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a) \(n_{CH_3COOH}=0,1.0,3=0,03\left(mol\right)\)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,03---->0,03--------->0,03
=> \(V_{dd.NaOH}=\dfrac{0,03}{1,5}=0,02\left(l\right)\)
b) mCH3COONa = 0,03.82 = 2,46 (g)
c) \(C_{M\left(CH_3COONa\right)}=\dfrac{0,03}{0,1+0,02}=0,25M\)
a)PTHH:
HCl + NaOH → NaCl + H2O
nHCl = 0,04 (mol) = nNaOH = nNaCl
=>VddNaOH = 0,04/0,1 = 0,4 (l) = 400 (ml)
Vdd = VddNaOH + VddHCl = 0,6 (l)
=>C(M) ≈ 0,067 (M)
b) 2HCl + Ca(OH)2 → CaCl2 + 2H2O
nCa(OH)2 = nCaCl2 = (1/2)nHCl = 0,02 (mol)
(Nồng độ phần trăm = 25% ????)
mCa(OH)2 = 1,48 (g)
=>mdd(Ca(OH)2) = 5,92 (g)
mddHCl = 220 (g)
=>mdd = 225,92 (g)
mCaCl2 = 2,22 (g)
=>%mCaCl2 ≈ 0,98%
a) \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: CO2 + 2NaOH → Na2CO3 + H2O
Mol: 0,15 0,3 0,15
\(C_{M_{ddNaOH}}=\dfrac{0,3}{0,2}=1,5M\)
b) Na2CO3: natri cacbonat
\(m_{Na_2CO_3}=0,15.106=15,9\left(g\right)\)
c)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,15 0,075
\(V_{ddH_2SO_4}=\dfrac{0,075}{1}=0,075\left(l\right)=75\left(ml\right)\)
\(n_{SO_2}= \dfrac{7,84}{22,4}=0,35 mol\)
\(n_{Ca(OH)_2}= 0,2 . 1,4=0,28mol\)
Ta có:
\(T=\dfrac{n_{nhóm OH}}{n_{SO_2}}\)\(=\dfrac{2. 0,28}{0,35}= 1,6\)
Có: 1<T<2
Nên Phản ứng tạo hỗn hợp 2 muối trung hòa và axit
\(Ca(OH)_2 + SO_2 \rightarrow CaSO_3 + H_2O\) (1)
\(CaSO_3 + SO_2 + H_2O \rightarrow Ca(HSO_3)_2\) (2)
Theo PTHH (1):
\(n_{SO_2(1)}\)\(n_{CaSO_3} = n_{Ca(OH)_2}= 0,28mol\)
\(\Rightarrow n_{SO_2(2)}=0,35 - 0,28= 0,07 mol\)
Theo PTHH (2):
\(n_{CaSO_3bị hòa tan}\)\(=\)\(n_{Ca(HSO_3)_2}= n_{SO_2(2)}= 0,07 mol\)
Suy ra: \(n_{CaSO_3 sau pư}= 0,28 - 0,07= 0,21 mol\)
\(m_{muối}= m_{CaSO_3} + m_{Ca(HSO_3)_2}= 0,21 .120 + 0,07 . 202= 39,34g\)
b)
\(C_{M Ca(HSO_3)_2}= \dfrac{0,07}{0,2}= 0,35M\)
Đổi 300ml = 0,3 lít
Ta có: \(n_{H_2SO_4}=0,3.0,5=0,15\left(mol\right)\)
PTHH: H2SO4 + 2KOH ---> K2SO4 + 2H2O
a. Theo PT: \(n_{KOH}=2.n_{H_2SO_4}=2.0,15=0,3\left(mol\right)\)
\(\Rightarrow V_{dd_{KOH}}=\dfrac{0,3}{0,2}=1,5\left(lít\right)\)
b. Theo PT: \(n_{K_2SO_4}=n_{H_2SO_4}=0,15\left(mol\right)\)
\(\Rightarrow m_{K_2SO_4}=0,15.174=26,1\left(g\right)\)
c. Ta có: \(V_{dd_{K_2SO_4}}=V_{dd_{H_2SO_4}}=0,3\left(lít\right)\)
\(\Rightarrow C_{M_{K_2SO_4}}=\dfrac{0,15}{0,3}=0,5M\)
\(a.n_{CO_2}=\dfrac{0,672}{22,4}=0,03mol\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
\(n_{CO_2}=n_{Ca\left(OH\right)_2}=n_{CaCO_3}=0,03mol\\ m_{CaCO_3}=0,03.100=3g\\ b.V_{ddCa\left(OH\right)_2}=\dfrac{0,03}{1,5}=0,02l\)
300ml = 0,3l
\(n_{HNO3}=1.0,3=0,3\left(mol\right)\)
Pt : \(NaOH+HNO_3\rightarrow NaNO_3+H_2O|\)
1 1 1 1
0,3 0,3 0,3
\(n_{NaOH}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
200ml = 0,2l
\(C_{M_{NaOH}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
\(n_{NaNO3}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
⇒ \(m_{NaNO3}=0,3.85=25,5\left(g\right)\)
Sau phản ứng :
\(V_{dd}=0,2+0,3=0,5\left(l\right)\)
\(C_{M_{NaNO3}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\)
Chúc bạn học tốt
\(n_{HNO_3}=0,3\left(mol\right)\)
\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)
Theo PT: \(n_{NaOH}=n_{NaNO_3}=n_{HNO_3}=0,3\left(mol\right)\)
\(\Rightarrow CM_{NaOH}=\dfrac{0,3}{0,2}=1,5M\)
\(m_{NaNO_3}=0,3.85=25,5\left(g\right)\)
\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)
a)
$n_{HCl} = \dfrac{200.7,3\%}{36,5} = 0,4(mol)$
$Ca(OH)_2 + 2HCl \to CaCl_2 + 2H_2O$
$n_{Ca(OH)_2} = \dfrac{1}{2}n_{HCl} = 0,2(mol)$
$\Rightarrow m_{dd\ Ca(OH)_2} = \dfrac{0,2.74}{14,8\%} = 100(gam)$
b)
Sau phản ứng : $m_{dd} = 200 + 100 = 300(gam)$
$C\%_{CaCl_2} = \dfrac{0,2.111}{300}.100\% = 7,4\%$
a, \(m_{CH_3COOH}=20.3,75\%=0,75\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{0,75}{60}=0,0125\left(mol\right)\)
PT: \(2CH_3COOH+Ca\left(OH\right)_2\rightarrow\left(CH_3COO\right)_2Ca+2H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=\dfrac{1}{2}n_{CH_3COOH}=0,00625\left(mol\right)\)
\(\Rightarrow V_{ddCa\left(OH\right)_2}=\dfrac{0,00625}{0,2}=0,03125\left(l\right)=31,25\left(ml\right)\)
b, \(n_{\left(CH_3COO\right)_2Ca}=\dfrac{1}{2}n_{CH_3COOH}=0,00625\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Ca}=0,00625.158=0,9875\left(g\right)\)
Em cảm ơn