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\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ PTHH:CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3\downarrow+H_2O\\ \Rightarrow n_{Ba\left(OH\right)_2}=n_{BaCO_3}=0,1\left(mol\right)\\ \Rightarrow C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,1}{0,2}=0,5M\\ m_{BaCO_3}=0,1\cdot197=19,7\left(g\right)\)
_Cách 1: tự luận
nC02=6.72/22.4=0.3mol
nNaOH=2*0.2=0.4mol
=>nNaOH/nC02=0.4/0.3=1.33=>1<1.33<2
=>sinh ra 2 muối trung hòa và axit.
Gọi x,y là số mol của C02 ở (1)(2):
C02+2NaOH=>Na2C03+H20(1)
x----->2x---------->x(mol)
C02+NaOH=>NaHC03(2)
y------>y---------->y(mol)
Ta có:
2x+y=0.4
x+y=0.3
<=>x=0.1,y=0.2
=>nNa2C03=0.1mol
=>mNa2C03=0.1*106=10.6(g)
=>nNaHC03=0.2mol
=>mNaHC03=0.2*84=16.8(g)
_Cách 2:pp đường chéo.
Na2C03(n=2)...................1/3
.............................n=4/3
NaHC03(n=1)...................2/3
=>nNa2C03=nC02/3=0.3/3=0.1(mol)
=>nNaHC03=nC02*2/3=0.3*2/3=0.2(mol)
=>mNa2C03=0.1*106=10.6(g)
=>mNaHC03=0.2*84=16.8(g)
Cho 6,72 lít khí CO2 (đktc) vào 200 ml dung dịch NaOH 2M.Khối lượng muối thu được sau phản ứng là? | Yahoo Hỏi & Đáp
\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)
a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)
\(a,PTHH:CuCl_2+2KOH\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=2n_{CuCl_2}=0,4\left(mol\right)\\ \Rightarrow C\%_{KOH}=\dfrac{0,4}{0,2}=2M\\ b,PTHH:Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\\ \Rightarrow m_{CuO}=0,2\cdot80=16\left(g\right)\)
a. \(n_{CO_2}=0,02\left(mol\right);n_{Ca\left(OH\right)_2}=0,008\left(mol\right)\Rightarrow n_{OH^-}=0,016\\ Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,016}{0,02}=0,8\Rightarrow ChỉtạoCa\left(HCO_3\right)_2,CO_2dư\\ 2CO_2+Ca\left(OH\right)_2\rightarrow Ca\left(HCO_3\right)_2+H_2O\\ n_{Ca\left(HCO_3\right)_2}=n_{Ca\left(OH\right)_2}=0,016\left(mol\right)\\ \Rightarrow CM_{Ca\left(HCO_3\right)_2}=\dfrac{0,016}{0,4}=0,04M\)
\(b.n_{SO_2}=0,18\left(mol\right);n_{Ba\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow n_{OH^-}=0,4\left(mol\right)\\Tacó:\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,4}{0,18}=2,22\Rightarrow Ba\left(OH\right) _2dư\\ SO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\\ n_{Ba\left(OH\right)_2dư}=0,2-0,18=0,02\left(mol\right)\\ \Rightarrow CM_{Ba\left(OH\right)_2dư}=\dfrac{0,02}{0,2}=0,1M\)
a, \(n_{CO_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PT: \(MgO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2O\)
\(MgCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+CO_2+H_2O\)
Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,1.84}{10,4}.100\%\approx80,77\%\\\%m_{MgO}\approx19,23\%\end{matrix}\right.\)
b, \(n_{MgO}=\dfrac{10,4-0,1.84}{40}=0,05\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{MgO}+2n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
a) \(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
\(n_{NaOH}=0,5.2=1\left(mol\right)\)
PTHH: 2NaOH + SO2 --> Na2SO3 + H2O
1------->0,5------>0,5
Na2SO3 + SO2 + H2O --> 2NaHSO3
0,1<-----0,1--------------->0,2
=> Thu được muối Na2SO3, NaHSO3
\(\left\{{}\begin{matrix}m_{Na_2SO_3}=0,4.126=50,4\left(g\right)\\n_{NaHSO_3}=0,2.104=20,8\left(g\right)\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}C_{M\left(Na_2SO_3\right)}=\dfrac{0,4}{0,5}=0,8M\\C_{M\left(NaHSO_3\right)}=\dfrac{0,2}{0,5}=0,4M\end{matrix}\right.\)