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\(m_{CH_3COOH}=24\%.150=36\left(g\right)\\ \rightarrow n_{CH_3COOH}=\dfrac{36}{60}=0,6\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 ---> 2CH3COONa + CO2 + H2O
0,6 0,3 0,6 0,3
=> VCO2 = 0,3.22,4 = 6,72 (l)
\(m_{Na_2CO_3}=0,3.31,8\left(g\right)\)
=> \(m_{ddNa_2CO_3}=\dfrac{31,8}{21,2\%}=150\left(g\right)\)
mCO2 = 0,3.44 = 13,2 (g)
\(m_{dd}=150+150-13,2=286,8\left(g\right)\)
\(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{24,6}{286,8}=8,58\%\)
PT: \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(n_{CO_2}=\dfrac{1,2395}{24,79}=0,05\left(mol\right)\)
a, Theo PT: \(n_{Na_2CO_3}=n_{CO_2}=0,05\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,05.106=5,3\left(g\right)\)
b, \(n_{NaOH}=2n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,1}{0,1}=1\left(M\right)\)
Bài 2 :
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH :
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1 0,3
\(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
\(b,V_{ddH_2SO_4}=\dfrac{0,3}{2}=0,15\left(l\right)\)
\(c,C_{M\left(Fe_2\left(SO_4\right)_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}\left(M\right)\)
Bài 3 :
\(n_{Mg}=\dfrac{4.8}{24}=0,2\left(mol\right)\)
PTHH :
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2O\)
0,2 0,2 0,2 0,2
\(m_{MgSO_4}=0,2.120=24\left(g\right)\)
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(c,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
\(d,C_{M\left(MgSO_4\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 4 :
\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\)
PTHH :
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
0,3 0,45 0,15 0,45
\(V_{H_2}=0,45.24,79=11,1555\left(l\right)\)
\(m_{H_2SO_4}=0,45.98=44,1\left(g\right)\)
\(C\%_{H_2SO_4}=\dfrac{44,1}{300}.100\%=14,7\%\)
\(m_{Al_2\left(SO_4\right)_3}=0,15.342=51,3\left(g\right)\)
\(m_{dd}=8,1+300-\left(0,45.2\right)=307,2\left(g\right)\)
\(C\%_{Al_2\left(SO_4\right)_3}=\dfrac{51,3}{307,2}.100\%\approx16,7\%\)
Bài 5 :
\(n_{H_2}=\dfrac{4,958}{24,79}=0,2\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
\(C_{M\left(HCl\right)}=\dfrac{0,4}{0,2}=2\left(M\right)\)
\(C_{M\left(FeCl_2\right)}=\dfrac{0,2}{0,2}=1\left(M\right)\)
a) Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,0125<-----0,025------------>0,025------>0,0125
=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)
c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)
\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)
a, \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
b, \(n_{CO_2}=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{CO_2}=0,08\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,08}{0,2}=0,4\left(M\right)\)
c, \(n_{Na_2CO_3}=0,04\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Na_2CO_3}=\dfrac{0,04.106}{10}.100\%=42,4\%\\\%m_{NaCl}=57,6\%\end{matrix}\right.\)
\(a)Ba\left(OH\right)_2+Na_2CO_3\rightarrow2NaOH+BaCO_3\\ n_{Ba\left(OH\right)_2}=0,2.2=0,4mol\\ n_{BaCO_3}=n_{Na_2CO_3}=n_{Ba\left(OH\right)_2}=0,4mol\\ m_{BaCO_3}=0,4.171=68,4g\\ b)V_{Na_2CO_3}=\dfrac{0,4}{1}=0,4l\\ c)n_{NaOH}=2n_{Ba\left(OH\right)_2}=0,8mol\\ C_{M\left(NaOH\right)}=\dfrac{0,8}{0,2+0,4}=\dfrac{4}{3}M\)
\(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(Na_2CO_3+H_2SO_4\rightarrow Na_2SO_4+CO_2+H_2O\)
\(0.5..............0.5...............0.5\)
\(m_{Na_2CO_3}=0.5\cdot106=53\left(g\right)\)
\(C_{M_{Na_2SO_4}}=\dfrac{0.5}{0.25}=2\left(M\right)\)
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