Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
Quy hỗn hợp X về : \(\left\{{}\begin{matrix}Na:x\left(mol\right)\\Ba:y\left(mol\right)\\O:z\left(mol\right)\end{matrix}\right.\)
BTe ta được : \(x+2y=2z+0,05.2\left(1\right)\)
BTKL : \(23x+137y+16z=21,9\left(2\right)\)
\(y=\dfrac{20,52}{171}=0,12\left(mol\right)\)
\(\Leftrightarrow\left\{{}\begin{matrix}x=0,14\\z=0,14\end{matrix}\right.\)
\(n_{NaOH}=0,14\Leftrightarrow a=0,14.40=5.6\left(g\right)\)
Gọi số mol NaOH là a (mol)
\(n_{Ba\left(OH\right)_2}=\dfrac{20,52}{171}=0,12\left(mol\right)\); \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Ta có sơ đồ:
\(21,9\left(g\right)X\left\{{}\begin{matrix}Na\\Ba\\Na_2O\\BaO\end{matrix}\right.+H_2O\rightarrow\left\{{}\begin{matrix}Ba\left(OH\right)_2:0,12\left(mol\right)\\NaOH:a\left(mol\right)\end{matrix}\right.+H_2:0,05\left(mol\right)\)
Bảo toàn H: \(n_{H_2O}=\dfrac{0,12.2+a+0,05.2}{2}=0,17+0,5a\left(mol\right)\)
Bảo toàn khối lượng:
\(m_X+m_{H_2O}=m_{Ba\left(OH\right)_2}+m_{NaOH}+m_{H_2O}\)
=> \(21,9+18\left(0,17+0,5a\right)=20,52+40a+0,05.2\)
=> a = 0,14 (mol)
=> m = 0,14.40 = 5,6 (g)
2Na+2H2O->2NaOH+H2
x-------------------x---------0,5x
2K+2H2O->2KOH+H2
y-----------------y-----------0,5y
nH2O=2n H2
=>mH2O=\(\dfrac{4,48}{22,4}2.18\)=7,2g
Ta có :\(\left\{{}\begin{matrix}23x+39y=11,6\\0,5x+0,5y=0,2\end{matrix}\right.\)
=>x=0,25 mol, y=0,15 mol
=>m bazo=0,25.40+0,15.56=18,4g
d) m Na=0,25.23=5,75g
=>m K=0,15.39=5,85g
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
gọi nNa :a , nk :b (a,b>0)
=> 23a+39b=11,6(g)
\(2Na+2H_2O\rightarrow2NaOH+H_2\)
a \(\dfrac{1}{2}a\)
\(2K+2H_2O\rightarrow2KOH+H_2\)
b \(\dfrac{1}{2}b\)
=> \(\left\{{}\begin{matrix}23a+39b=11,6\\\dfrac{1}{2}a+\dfrac{1}{2}b=0,2\end{matrix}\right.\)
=> a= 0,25 , b = 0,15(mol)
theo pt nH2O = 0,4+0,4=0,8(mol)
=> mH2O = 0,8.18=14,4(g)
theo pthh : nKOH = 0,15 , nNaOH = 0,25
=> \(\left\{{}\begin{matrix}m_{KOH}=0,15.56=8,4\left(g\right)\\m_{NaOH}=0,25.40=10\left(g\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}m_K=0,15.39=5,85\left(g\right)\\m_{Na}=0,25.23=5,75\left(g\right)\end{matrix}\right.\)
$n_{Ba} = n_{Ba(OH)_2} = 0,12(mol)$
$n_{H_2} = \dfrac{1,12}{22,4} = 0,05(mol)$
Gọi $n_{Na} = a ; n_O = b$
Ta có :
$23a + 16b + 0,12.137 = 21,1$
Bảo toàn electron : $a + 0,12.2 = 2b + 0,05.2$
Suy ra $a = \dfrac{177}{1550} ; b = \dfrac{197}{1550}$
Suy ra $m_{NaOH} = \dfrac{177}{1550}.40 = 4,57(gam)$
a)Quy \(\left\{{}\begin{matrix}Na:x\left(mol\right)\\Ba:y\left(môl\right)\\O:z\left(mol\right)\end{matrix}\right.\underrightarrow{+H_2O}\left\{{}\begin{matrix}NaOH:x\left(mol\right)\\Ba\left(OH\right)_2:y\left(mol\right)\\O^{2-}:z\left(mol\right)\end{matrix}\right.+H_2\)
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05mol\)
\(n_{Ba\left(OH\right)_2}=\dfrac{20,52}{171}=0,12mol\Rightarrow y=0,12mol\)
Ta có hệ: \(\left\{{}\begin{matrix}BTKL:23x+137y+16z=21,9\\y=0,12\\BTe:x+2y=2z+2n_{H_2}\Rightarrow x-2z=-0,14\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,14\\y=0,12\\z=0,14\end{matrix}\right.\)
\(n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,14+2\cdot0,12=0,38mol\)
\(n_{CO _2}=\dfrac{6,72}{22,4}=0,3mol\Rightarrow n_{CO_3^{2-}}=0,38-0,3=0,08mol\)
\(\Rightarrow m_{CO_3^{2-}\downarrow}=0,08\cdot197=15,76g\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
=> \(n_{H_2SO_4}=0,2\left(mol\right)\)
mmuối = mkim loại + mSO4 = 12 + 0,2.96 = 31,2 (g)
a)
\(n_{H_2}=\dfrac{0,336}{22,4}=0,015\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2
0,03<------------0,03<----0,015
=> \(\%m_{Na}=\dfrac{0,03.23}{1,31}.100\%=52,67\%\)
=> \(\%m_{Na_2O}=100\%-52,67\%=47,33\%\)
b)
\(n_{Na_2O}=\dfrac{1,31.47,33\%}{62}=0,01\left(mol\right)\)
PTHH: Na2O + H2O --> 2NaOH
0,01----------->0,02
=> nNaOH = 0,03 + 0,02 = 0,05 (mol)
mdd sau pư = 1,31 + 18,72 - 0,015.2 = 20 (g)
=> \(C\%_{dd.NaOH}=\dfrac{0,05.40}{20}.100\%=10\%\)
\(V_{dd.NaOH}=\dfrac{20}{1,2}=\dfrac{50}{3}\left(ml\right)=\dfrac{1}{60}\left(l\right)\)
\(C_{M\left(dd.NaOH\right)}=\dfrac{0,05}{\dfrac{1}{60}}=3M\)