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Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)\)
a. PTHH: Na2SO3 + 2HCl ---> 2NaCl + SO2 + H2O
Theo PT: \(n_{SO_2}=n_{Na_2CO_3}=0,1\left(mol\right)\)
=> \(V_{SO_2}=0,1.22,4=2,24\left(lít\right)\)
b. Theo PT: \(n_{HCl}=2.n_{SO_2}=2.0,1=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
=> \(C_{\%_{HCl}}=\dfrac{7,3}{150}.100\%=4,87\%\)
c. Ta có: \(m_{dd_{NaCl}}=n_{Na_2SO_{3_{PỨ}}}=50\left(g\right)\)
Theo PT: \(n_{NaCl}=n_{HCl}=0,2\left(mol\right)\)
=> \(m_{NaCl}=0,2.58,5=11,7\left(g\right)\)
=> \(C_{\%_{NaCl}}=\dfrac{11,7}{50}.100\%=23,4\%\)
a) $CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
Theo PTHH :
$n_{CO_2} = n_{CaCO_3} = \dfrac{10}{100} = 0,1(mol)$
$V_{CO_2} = 0,1.22,4 = 2,24(lít)$
b) $n_{HCl} = 2n_{CaCO_3} = 0,2(mol)$
$C_{M_{HCl}} = \dfrac{0,2}{0,25} = 0,8M$
c) $CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$
$n_{CaCO_3} = n_{CO_2} = 0,1(mol)$
$m_{CaCO_3} = 0,1.100 = 10(gam)$
a, \(Na_2SO_3+H_2SO_4\rightarrow Na_2SO_4+SO_2+H_2O\)
\(K_2SO_3+H_2SO_4\rightarrow K_2SO_4+SO_2+H_2O\)
Ta có: \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{SO_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3.98}{20\%}=147\left(g\right)\)
b, Ta có: 126nNa2SO3 + 158nK2SO3 = 44,2 (1)
Theo PT: \(n_{SO_2}=n_{Na_2SO_3}+n_{K_2SO_3}=0,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Na_2SO_3}=0,1\left(mol\right)\\n_{K_2SO_3}=0,2\left(mol\right)\end{matrix}\right.\)
Có: m dd sau pư = 44,2 + 147 - 0,3.64 = 172 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Na_2SO_3}=\dfrac{0,1.126}{172}.100\%\approx7,33\%\\C\%_{K_2SO_3}=\dfrac{0,2.158}{172}.100\%\approx18,37\%\end{matrix}\right.\)
c, \(n_{Ba\left(OH\right)_2}=0,5.1=0,5\left(mol\right)\)
\(\Rightarrow\dfrac{n_{SO_2}}{n_{Ba\left(OH\right)_2}}=0,6< 1\) → Pư tạo BaSO3.
PT: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
\(n_{BaSO_3}=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_{BaSO_3}=0,3.217=65,1\left(g\right)\)
Câu 15 :
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Pt : \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,4----->1,2------->0,4------>0,6
\(m_{HCl}=1,2.36,5=43,8\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{43.8.100\%}{25\%}=175,2\left(g\right)\)
\(m_{ddspu}=10,8+175,2-0,6.2=184,8\left(g\right)\)
\(C\%_{AlCl3}=\dfrac{0,4.133,5}{184,8}.100\%=28,9\%\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
a+b+c) Ta có: \(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
\(\Rightarrow n_{H_2}=0,25\left(mol\right)=n_{MgCl_2}\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,25\cdot95=23,75\left(g\right)\\V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\end{matrix}\right.\)
d) PTHH: \(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Theo PTHH: \(n_{Cu}=n_{H_2}=0,25\left(mol\right)\) \(\Rightarrow m_{Cu}=0,25\cdot64=16\left(g\right)\)
1: \(n_{Zn}=\dfrac{3.25}{65}=0.05\left(mol\right)\)
a: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,05 0,1 0,05 0,05
\(m_{dd\left(HCl\right)}=0.1\cdot36.5=3.65\left(g\right)\)
b: \(V_{H_2}=0.05\cdot22.4=1.12\left(lít\right)\)
2)
H3PO4 (axit yếu) : axit photphoric
Zn3(PO4)2 (muối) : kẽm photphat
Fe2(SO4)3 (muối) : sắt (III) sunfat
SO2 (oxit axit) : lưu huỳnh đioxit
SO3 (oxit axit) : lưu huỳnh trioxit
P2O5 (oxit axit) : đi photpho pentaoxit
HCl(axit mạnh) : axit clohidric
Ca(HCO3)2 (muối axit) : canxi hidrocacbonat
Ca(H2PO4)2 (muối aixt) : canxi đihidrophotphat
Fe2O3 (oxit bazơ) : sắt (III) oxit
Cu(OH)2 (bazơ) : đống(II) hidroxit
NaH2PO4 (muối axit) : natri đihidrophotphat
Chúc bạn học tốt
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
1)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
____0,1----->0,15
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%=\dfrac{14,7}{250}.100\%=5,88\%\)
2)
\(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
_______0,2------------------------------>0,2
=> VCO2 = 0,2.22,4 = 4,48(l)
3)
\(n_A=\dfrac{18,4}{M_A}\left(mol\right)\)
PTHH: 2A + Cl2 --to--> 2ACl
____\(\dfrac{18,4}{M_A}\)---------->\(\dfrac{18,4}{M_A}\)
=> \(\dfrac{18,4}{M_A}\left(M_A+35,5\right)=46,8=>M_A=23\left(Na\right)\)
4)
nHCl = 0,2.3 = 0,6(mol)
PTHH: M + 2HCl --> MCl2 + H2
____0,3<-----0,6
=> \(M_M=\dfrac{7,2}{0,3}=24\left(Mg\right)\)