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a. PTHH:
Cu + H2SO4 ---x--->
Mg + H2SO4 ---> MgSO4 + H2
b. Ta có: \(n_{H_2SO_4}=2.\dfrac{100}{1000}=0,2\left(mol\right)\)
Theo PT: \(n_{Mg}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,2.24=4,8\left(g\right)\)
\(\Rightarrow\%_{m_{Mg}}=\dfrac{4,8}{6}.100\%=80\%\)
\(\%_{m_{Cu}}=100\%-80\%=20\%\)
c. Theo PT: \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(lít\right)\)
d. PTHH: \(Cu+2H_2SO_{4_đ}\overset{t^o}{--->}CuSO_4+SO_2+2H_2O\)
a, Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
2C2H5OH + 2Na ---> 2C2H5ONa + H2
a---------------------------------------->0,5a
2CH3COOH + 2Na ---> 2CH3COONa + H2
b------------------------------------------------>0,5b
=> hệ pt \(\left\{{}\begin{matrix}46a+60b=48,8\\0,5a+0,5b=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,8\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,8.46=36,8\left(g\right)\\m_{CH_3COOH}=0,2.60=12\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100\%=75,41\%\\\%m_{CH_3COOH}=100\%-75,41\%=24,59\%\end{matrix}\right.\)
b, PTHH:
\(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_4đặc}CH_3COOC_2H_5+H_2O\)
LTL: 0,8 > 0,2 => Rượu dư
\(n_{CH_3COOC_2H_5\left(tt\right)}=0,2.85\%=0,17\left(mol\right)\\ m_{este}=0,17.88=14,96\left(g\right)\)
a.Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=x\\n_{CH_3COOH}=y\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
x 1/2 x ( mol )
\(2CH_3COOH+Na\rightarrow2CH_3COONa+H_2\)
y 1/2 y ( mol )
Ta có:
\(\left\{{}\begin{matrix}46x+60y=48,8\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,2\end{matrix}\right.\)
\(\rightarrow m_{C_2H_5OH}=0,8.46=36,8g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100=75,4\%\\\%m_{CH_3COOH}=100\%-75,4\%=24,6\%\end{matrix}\right.\)
b.\(C_2H_5OH+CH_3COOH\rightarrow\left(H_2SO_4\left(đ\right),t^o\right)CH_3COOC_2H_5+H_2O\)
0,8 < 0,2 ( mol )
0,2 0,2 ( mol )
\(m_{CH_3COOC_2H_5}=0,2.88.85\%=14,96g\)
a. PTHH:
\(Zn+H_2SO_4--->ZnSO_4+H_2\)
\(Cu+H_2SO_4--\times-->\)
b. Theo PT: \(n_{Zn}=n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow m_{_{ }Zn}=0,1.65=6,5\left(g\right)\)
\(\Rightarrow\%_{m_{Zn}}=\dfrac{6,5}{10,5}.100\%=61,9\%\)
\(\%_{m_{Cu}}=100\%-61,9\%=31,8\%\)
\(Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2\)
Cu không phản ứng H2SO4 loãng nhé
\(n_{H_2}= \dfrac{2,24}{22,4}= 0,1 mol\)
Theo PTHH:
\(n_{Zn}=n_{H_2}= 0,1 mol\)
\(\Rightarrow m_{Zn}= 0,1 . 65= 6,5 g\)
\(\Rightarrow\)%mZn=\(\dfrac{6,5}{10,5} . 100\)%~ 61,9%
\(\Rightarrow\)%mCu= 100% - 61,9%=38,1 %
\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ b.n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ n_{Zn}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Zn}=\dfrac{0,1.65}{10,5}.100=61,9\%\\ \%m_{Cu}=100-61,9=38,1\%\)
- Cu không tác dụng được với dd H2SO4 loãng.
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{Zn}=n_{H_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Zn}=\dfrac{0,1.65}{10,5}.100\approx61,905\%\\ \Rightarrow\%m_{Cu}\approx38,095\%\)
anh giúp em bài này với https://hoc24.vn/cau-hoi/giup-minh-voi-trong-tam-giai-thich-ki-cai-de-nha-cam-on.2017646398420
a) Gọi số mol CH3COOH, C2H5OH là a, b (mol)
=> 60a + 46b = 25,8 (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2Na + 2CH3COOH --> 2CH3COONa + H2
a------------------------->0,5a
2Na + 2C2H5OH --> 2C2H5ONa + H2
b--------------------->0,5b
=> 0,5a + 0,5b = 0,25 (2)
(1)(2) => a = 0,2 (mol); b = 0,3 (mol)
=> \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,2.60}{25,8}.100\%=46,51\%\\\%m_{C_2H_5OH}=\dfrac{0,3.46}{25,8}.100\%=53,49\%\end{matrix}\right.\)
b)
\(n_{CH_3COOC_2H_5}=\dfrac{13,2}{88}=0,15\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
0,15<---------------------------------0,15
=> \(H=\dfrac{0,15}{0,2}.100\%=75\%\)
a,\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: x x
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}65x+56y=30,7\\x+y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,3.65.100\%}{30,7}=63,52\%;\%m_{Fe}=100\%-63,52\%=36,48\%\)
b,
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,6
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,2 0,4
nHCl = 0,6+0,4 = 1 (mol)
\(V_{ddHCl}=\dfrac{1}{2}=0,5\left(l\right)=500\left(ml\right)\)
a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Cu+HCl\rightarrow\)(không phản ứng)
2Al + 6HCl => 2AlCl3 + 3H2
0,3/3*2 (6,72/22,4)
=> mAl = 0,2 *27 =5,4g; mCu = 11,8 - 5,4 = 6,4g
a, \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
b, \(n_{CH_3COOH}=0,1.2=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c, Theo PT: \(n_{Zn}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,1.65}{9,5}.100\%\approx68,42\%\\\%m_{Cu}\approx31,58\%\end{matrix}\right.\)