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mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
PTHH : 2Cu + O2 ---> 2CuO (1)
2KMnO4 ---> K2MnO4 + MnO2 + O2 (2)
Từ gt => nCu =16:64 = 0,25 (mol)
Từ (1) và gt => nCu = nCuO = 2 nO2
=> nCuO = 0,25 mol
nO2 = 0,125 mol
=> mCuO = 0,25 x 80 = 20 (g)
VO2 = 0,125 x 22,4 = 2,8 (l)
Từ (2) => nKMnO4 = 2 nO2
=> nKMnO4 = 0,25
=> mKMnO4 = 0,25 x 158 = 39,5(g)
\(n_{H_2}=\dfrac{V}{24,79}=\dfrac{11,2}{24,79}\approx0,45\left(mol\right)\)
a) \(PTHH:2H_2+O_2\underrightarrow{t^o}2H_2O\)
2 1 2
0,45 0,225 0,45
b) \(m_{O_2}=n.M=0,225.\left(16.2\right)=7,2\left(g\right)\\ V_{O_2}=n.24,79=0,225.24,79=5,57775\left(l\right)\)
c) \(PTHH:2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)
2 1 1 1
0,45 0,225 0,225 0,225
\(m_{KMnO_4}=n.M=0,45.\left(39+55+16.4\right)=71,1\left(g\right).\)
a, \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,25\left(mol\right)\)
\(\Rightarrow m_{O_2}=0,25.32=8\left(g\right)\)
\(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,5\left(mol\right)\Rightarrow m_{KMnO_4}=0,5.158=79\left(g\right)\)
a, \(2Cu+O_2\underrightarrow{t^o}2CuO\)
b, \(n_{Cu}=\dfrac{16}{64}=0,25\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Cu}=0,125\left(mol\right)\Rightarrow V_{O_2}=0,125.22,4=2,8\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,25\left(mol\right)\Rightarrow m_{KMnO_4}=0,25.158=39,5\left(g\right)\)
a)
$2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2$
b) $n_{KMnO_4} = \dfrac{79}{158} = 0,5(mol)$
Theo PTHH : $n_{O_2} = \dfrac{1}{2}n_{KMnO_4} = 0,25(mol)$
$\Rightarrow V_{O_2} = 0,25.22,4 = 5,6(lít)$
c) $n_P = \dfrac{3,1}{31} = 0,1(mol)$
$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
Ta thấy : $n_P : 4 < n_{O_2} :5$ nên $O_2$ dư
$n_{P_2O_5} = \dfrac{1}{2}n_P = 0,05(mol)$
$m_{P_2O_5} = 0,05.142 = 7,1(gam)$
a.\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{31,6}{158}=0,2mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,2 0,1 ( mol )
\(V_{O_2}=n.22,4=0,1.22,4=2,24l\)
b.\(n_{O_2}=0,1.60\%=0,06mol\)
\(2R+\dfrac{1}{2}nO_2\rightarrow\left(t^o\right)R_2O_n\)
\(\dfrac{2,16}{M_R}\) \(\dfrac{2,16n}{M_R}\) ( mol )
\(\Rightarrow\dfrac{2,16n}{M_R}=0,06\)
\(\Rightarrow0,06M_R=2,16n\)
\(\Rightarrow M_R=36n\)
Biện luận:
-n=1 => Loại
-n=2 => Loại
-n=3 => \(M_R=108\) ( g/mol ) R là Bạc ( Ag )
Vậy R là Bạc (Ag)
4P+5O2-to>2P2O5
0,04----0,05----0,02
n P=0,04 mol
=>m P2O5=0,02.142=2,84g
=>VO2=0,05.22,4=1,12l
c)
2KMnO4-to>K2MnO4+MnO2+O2
0,1----------------------------------------0,05
H=10%
m KMnO4=0,1.158.110%=17,28g
\(n_P=\dfrac{1,24}{31}=0,04\left(mol\right)\\ pthh:4P+5O_2\underrightarrow{T^O}2P_2O_5\)
0,04 0,05 0,02
=> \(\left\{{}\begin{matrix}m_{P_2O_5}=0,02.142=2,84\left(g\right)\\V_{O_2}=0,05.22,4=1,12\left(l\right)\end{matrix}\right.\)
\(pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
=> \(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(m_{KMnO_4\left(d\text{ùng}\right)}=15,8.110\%=17,38\left(g\right)\)
nKMnO4=94,8:158=0,6(mol)
PTHH: 2KMnO4-t--> K2MnO4+MnO2+O2
0,6----------------------------------->0,3(mol)
=>V= VO2=0,3. 22,4= 6,72(l)
b ) 40%nO2 =40%.0,3=0,12(mol)
2R + O2 -t--->2RO
0,24(mol)<- 0,12
=> M(Khối lượng Mol ) R= m:n=5,76:0,24=24(G/MOL)
=> R là Mg
a)-\(n_{KMnO_4}=\dfrac{m}{M}=\dfrac{94,8}{158}=0,6\left(mol\right)\)
-PTHH: \(2KMnO_4\rightarrow^{t^0}K_2MnO_4+MnO_2+O_2\uparrow\)
2 1
0,6 0,3
\(\Rightarrow V_{O_2\left(đktc\right)}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b)-\(V_{O_2\left(cd\right)}=6,72.\dfrac{40}{100}=2,688\left(l\right)\)
\(\Rightarrow n_{O_2}=\dfrac{V}{22,4}=\dfrac{2,688}{22,4}=0,12\left(mol\right)\)
-PTHH: \(2R+O_2\rightarrow^{t^0}2RO\)
2 1
0,24 0,12
\(m_R=n.M=5,76\left(g\right)\)
\(\Rightarrow0,24.M_R=5,76\)
\(\Rightarrow M_R=24\) (g/mol)
-Vậy R là Crom
H=0%?