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\(n_{HCl}=\dfrac{25}{36,5}=\dfrac{50}{73}mol\)
2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
\(\Rightarrow n_{Al}=\dfrac{\dfrac{50}{73}.2}{6}=\dfrac{50}{219}mol\\ m_{Al}=\dfrac{50}{219}.27=\dfrac{450}{73}g\)
\(n_{H_2}=\dfrac{\dfrac{50}{73}.3}{6}=\dfrac{25}{73}mol\\ V_{H_2}=\dfrac{25}{73}.22,4=\dfrac{560}{73}l\)
a: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b: \(n_{HCl}=\dfrac{25}{36.5}=\dfrac{50}{73}\left(mol\right)\)
\(\Leftrightarrow n_{AlCl_3}=\dfrac{150}{73}\left(mol\right)=n_{Al}\)
\(m_{Al}=\dfrac{150}{73}\cdot27=\dfrac{4050}{73}\left(g\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,3 0,6 0,3 0,3
\(FeCl_2+2AgNO_3\rightarrow Fe\left(NO_3\right)_3+2AgCl\)
0,3 0,6
\(\rightarrow\left\{{}\begin{matrix}a=0,3.56=16,8\left(g\right)\\b=0,6.143,5=86,1\left(g\right)\end{matrix}\right.\)
\(m_{ddHCl}=150.1,2=180\left(g\right)\\ m_{HCl}=0,6.36,5=21,9\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{21,9}{180}=12,17\%\\C_{M\left(HCl\right)}=\dfrac{0,6}{0,15}=4M\end{matrix}\right.\)
a. PTHH:
Al+H2SO4-->AlSO4+H2
b.Theo ĐLBTKL, ta có:
mAl+mH2SO4=mAl2SO4+mH2
=>mH2SO4=mAl2SO4+mH2-mAl
=171+3-27=147 (g)
$a\big)2Al+6HCl\to 2AlCl_3+3H_2$
$b\big)$
$n_{Al}=\dfrac{5,4}{27}=0,2(mol)$
Theo PT: $n_{H_2}=\dfrac{3}{2}n_{Al}=0,3(mol)$
$\to V_{H_2(đktc)}=0,3.22,4=6,72(l)$
$c\big)$
Theo PT: $n_{AlCl_3}=n_{Al}=0,2(mol)$
$\to m_{AlCl_3}=0,2.133,5=26,7(g)$
n hh khí = 0.5 mol
nCO: x mol
nCO2: y mol
=> x + y = 0.5
28x + 44y = 17.2 g
=> x = 0.3 mol
y = 0.2 mol
Khối lượng oxi tham gia pứ oxh khử oxit KL: 0.2 * 16 = 3.2g => m KL = 11.6 - 3.2 = 8.4g
TH: KL hóa trị I => nKL = 2*nH2 = 0.3 mol => KL: 28!!
KL hóa trị III => nKL = 2/3 *nH2 = 0.1 mol => KL: 84!!
KL hóa trị II => nKL = nH2 = 0.15 mol => KL: 56 => Fe.
nFe / Oxit = 0.15 mol
nO/Oxit = 0.2 mol
=> nFe/nO = 3/4 => Fe3O4
Fe3O4 + 4CO = 3Fe + 4CO2
Fe + H2SO4 = FeSO4 + H2
0.15.....0.15.......0.15.....0.15
=> mH2SO4 pứ = 14.7 g => mdd = 147 g
m dd sau khi cho KL vào = m KL + m dd - mH2 thoát ra = 0.15 * 56 + 147 - 0.15*2 = 155.1g
=> C% FeSO4 = 14.7%
tham khảo: https://hoidapvietjack.com/q/648/cho-83-g-hon-hop-a-gom-3-kim-loai-dong-nhom-va-magie-tac-d
Sửa đề : 200ml thành 200g
a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\) (1)
\(3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O\) (2)
b) 1/2 lượng khí B: \(n_{H_2\left(2\right)}=3n_{Fe_2O_3}=3.\dfrac{38,4}{160}=0,72\left(mol\right)\)
=> \(n_{H_2\left(1\right)}=0,72.2=1,44\left(mol\right)\)
\(n_{H_2SO_4}=n_{H_2\left(2\right)}=1,44\left(mol\right)\)
=> \(C\%H_2SO_4=\dfrac{1,44.98}{200}.100=70,56\%\)
\(n_{Al}=\dfrac{2}{3}n_{H_2\left(2\right)}=0,96\left(mol\right)\)
=> \(m_{Al}=0,96.27=25,92\left(g\right)\)
\(n_{Al}=\dfrac{6.75}{27}=0.25\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0.25....................0.25......0.375\)
\(m_{AlCl_3}=0.25\cdot133.5=33.375\left(g\right)\)
\(V_{H_2}=0.375\cdot22.4=8.4\left(l\right)\)