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a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=100.14,6\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{Zn}=0,2\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
Ta có: m dd sau pư = 6,5 + 100 - 0,1.2 = 106,3 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{106,3}.100\%\approx12,79\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,2.36,5}{106,3}.100\%\approx6,87\%\end{matrix}\right.\)
\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1........2\)
\(0.1......0.4\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)
\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)
\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)
\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)
\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)
Sửa đề: 8,4 gam Fe
\(a,n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ n_{HCl}=\dfrac{14,6.175}{36,5.100}=0,7\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
ban đầu 0,15 0,7
phản ứng 0,15 0,3
sau pư 0 0,4 0,15 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
\(b,m_{dd}=8,4+175-0,15.2=183,1\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15.127}{183,1}.100\%=10,4\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,4.36,5}{183,1}.100\%=7,97\%\end{matrix}\right.\)
a)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(m_{HCl}=\dfrac{175.14,6}{100}=25,55\left(g\right)\\ \rightarrow n_{HCl}=\dfrac{25,55}{35,5}=0,7\left(mol\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
bđ 0,3 0,7
pư 0,3 0,6
spư 0 0,1 0,3 0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b)
mdd = 16,8 + 175 - 0,3.2 = 191,2 (g)
=> \(\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,3.127}{191,2}.100\%=19,93\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{191,2}.100\%=1,91\%\end{matrix}\right.\)
\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ n_{HCl}=\dfrac{\dfrac{175.14,6}{100}}{36,5}=0,7\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(LTL:\dfrac{0,3}{1}< \dfrac{0,7}{2}\)
\(n_{H_2}=n_{Fe}=0,3\left(mol\right)\\
V_{H_2}=0,3.22,4=6,72\left(l\right)\\
m_{\text{dd}}=16,8+175-\left(0,3.2\right)=191,2\left(g\right)\\
n_{FeCl_2}=n_{Fe}=0,3\left(mol\right)\\
C\%_{FeCl_2}=\dfrac{0,3.127}{191,2}.100\%=19,92\%\)
=> HCl dư
\(n_{Zn}=\dfrac{6,5}{65}=0,1mol\)
\(m_{HCl}=\dfrac{200\cdot14,6\%}{100\%}=29,2g\Rightarrow n_{HCl}=0,8mol\)
a)\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,8 0 0
0,1 0,2 0,1 0,1
0 0,6 0,1 0,1
b)Chất HCl dư và dư \(m=0,6\cdot36,5=21,9g\)
c)\(V_{H_2}=0,1\cdot22,4=2,24l\)
d)\(m_{H_2}=0,1\cdot2=0,2g\)
\(m_{ZnCl_2}=0,1\cdot136=13,6g\)
\(m_{ddZnCl_2}=6,5+200-0,2=206,3g\)
\(C\%=\dfrac{13,6}{206,3}\cdot100\%=6,59\%\)
a, ta có pt sau : Zn + 2HCl >ZnCl2 + H2 (1)
b, nHCl=\(\dfrac{200\times14,6}{100}=29,2\left(g\right)\)\(\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
Ta có : nZn=\(\dfrac{6,5}{65}=0,1\left(mol\right)\)
Ta có tỉ lệ số mol là : \(\dfrac{n_{Zn}}{1}< \dfrac{n_{HCl}}{2}\left(\dfrac{0,1}{1}< \dfrac{0,8}{2}\right)\)
\(\Rightarrow\) HCl dư , Zn pứ hết
Theo pt : nHClpứ = 2.nZn=2.0,1=0,2(mol)
\(\Rightarrow\)nHCl dư = nHCl bđ - nHCl pứ = 0,8 - 0,2 = 0,6 (mol)
\(\Rightarrow\)mHCl dư=0,6.36,6=21,9 (g)
c,theo pt :nH2=nZn=0,1(mol)
\(\Rightarrow\)VH2=0,1.22,4=2,24(l)
d,Các chất có trong dung dịch sau pứ là: ZnCl2 , HCl dư
mk chịu câu này
a, Zn + 2HCl ----> ZnCl2 + H2↑
b, nZn= 6,5:65= 0,1 mol; nHCl= (100*14,6%)/36,5 = 0,4 mol
Zn + 2HCl ----> ZnCl2 + H2↑
trc pư: 0,1 0,4 (mol)
pư: 0,1 0,2 (mol)
sau pư:0 0,2 0,1 0,1 (mol)
VH2(dktc)= 0,1*22,4= 2,24 (L)
c, mZnCl2= 0,1* 136= 13,6 g
mHCl= 0,2* 36,5= 7,3 g
mdd = 6,5 +100 - 0,1*2 =106,3 g
C%ZnCl2= 13,6/106,3* 100%= 12,8%
C%HCl= 7,3/106,3*100%=6,8%
\(a)n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot0,4=0,6\left(mol\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\\ b)n_{HCl}=3n_{Al}=3.0,4=1,2\left(mol\right)\\ m_{HCl}=1,2.36,5=43,8\left(g\right)\\ m_{dd_{HCl}}=\dfrac{43,8}{10,95\%}\cdot100\%=400\left(g\right)\\ c)n_{AlCl_3}=n_{Al}=0,4mol\\ m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ m_{H_2}=0,6.2=1,2\left(g\right)\\ m_{dd_{AlCl_3}}=10,8+400-1,2=409,6\left(g\right)\\ C_{\%AlCl_3}=\dfrac{53,4}{409,6}\cdot100\%\approx13\%\)
`n_[Al]=[2,7]/27=0,1(mol)`
`2Al + 6HCl -> 2AlCl_3 + 3H_2 \uparrow`
`0,1` `0,3` `0,1` `0,15` `(mol)`
`a)V_[H_2]=0,15.22,4=3,36(l)`
`b)V_[dd HCl]=[0,3]/2=0,15(l)`
`=>C_[M_[AlCl_3]]=[0,1]/[0,15]~~0,67(M)`
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,3 0,1 0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\\ V_{HCl}=\dfrac{0,3}{2}=0,15\left(l\right)\\ C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}M\)
nZn=19,5/65=0,3(mol)
mHCl=18,25/36,5=0,5(mol)
pt: Zn+2HCl--->ZnCl2+H2
1______2
0,3_____0,5
Ta có: 0,3/1>0,5/2
=>Zn dư
mZn dư=0,05.65=3,25(mol)
Theo pt: nH2=1/2nHCl=1/2.0,5=0,25(mol)
=>VH2=0,25.22,4=5,6(l)
nZn = 0,3 mol
nHCl = 0,5 mol
Zn + 2HCl → ZnCl2 + H2
Đặt tỉ lệ ta có
0,3 < \(\dfrac{0,52}{2}\)
⇒ Zn dư và dư 3,25 gam
⇒ VH2 = 0,25.22,4 = 5,6 (l)
nZn = \(\dfrac{6,5}{65}=0,1\left(mol\right)\)
mHCl = \(\dfrac{14,6\times100}{100}=14,6\left(g\right)\)
=> nHCl = \(\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Pt: Zn + 2HCl --> ZnCl2 + H2
0,1 mol-> 0,2 mol->0,1 mol-> 0,1 mol
Xét tỉ lệ mol giữa Zn và HCl:
\(\dfrac{0,1}{1}< \dfrac{0,4}{2}\)
Vậy HCl dư
VH2 thoát ra = 0,1 . 22,4 = 2,24 (lít)
mZnCl2 = 0,1 . 136 = 13,6 (g)
mdd sau pứ = mZn + mdd HCl - mH2
...................= 6,5 + 100 - 0,1 . 2 = 106,3 (g)
C% dd ZnCl2 = \(\dfrac{13,6}{106,3}.100\%=12,8\%\)
C% dd HCl dư = \(\dfrac{\left(0,4-0,2\right).36,5}{106,3}.100\%=6,9\%\)