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\(n_{NaOH}=\dfrac{16.10\%}{40}=0,04\left(mol\right)\\ 2NaOH+SO_2\rightarrow Na_2SO_3+H_2O\\ NaOH+SO_2\rightarrow NaHSO_3\\ Đặt:n_{NaHSO_3}=a\left(mol\right);n_{Na_2SO_3}=1,5a\left(mol\right)\\ \Rightarrow n_{NaOH\left(tổng\right)}=3a+a=4a=0,04\left(mol\right)\\ \Leftrightarrow a=0,01\left(mol\right)\\ n_{SO_2\left(tổng\right)}=n_{Na_2SO_3}+n_{NaHSO_3}=2,5a=0,025\left(mol\right)\\ V_{SO_2\left(đktc\right)}=0,025.22,4=0,56\left(lít\right)\)
a)
$KOH + SO_2 \to KHSO_3$
Theo PTHH : $n_{KOH} = n_{KHSO_3} = n_{SO_2} = 0,4.0,5 = 0,2(mol)$
$V_{SO_2} = 0,2.22,4 = 4,48(lít)$
$C_{M_{KHSO_3}} = \dfrac{0,2}{0,4} = 0,5M$
b)
$2KOH + SO_2 \to K_2SO_3 + H_2O$
$n_{K_2SO_3} = n_{SO_2} = \dfrac{1}{2}n_{KOH} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$
$C_{M_{K_2SO_3}} = \dfrac{0,1}{0,4} = 0,25M$
a) nAl=2,7/27=0,1(mol)
nHCl=14,6/36,5= 0,4(mol)
PTHH: 2Al +6 HCl -> 2 AlCl3 +3 H2
Ta có: 0,1/2 < 0,6/4
=> HCl dư, Al hết, tính theo nAl
=> nAlCl3=nAl=0,1(mol)
=> mAlCl3=0,1.133,5=13,35(g)
b) nH2= 3/2. nAl=3/2. 0,1=0,15(mol)
=>V(H2,đktc)=0,15.22,4=3,36(l)
c) mFe2O3(nguyên chất)= 80%. 38,4=30,72(g)
=>nFe2O3= 30,72/160=0,192(mol)
PTHH: Fe2O3 + 3 H2 -to->2 Fe +3 H2O
Ta có: 0,192/1 > 0,15/3
=> H2 hết, Fe2O3 dư, tính theo nH2
=> nFe= 2/3. nH2= 2/3. 0,15=0,1(mol)
=>mFe=0,1.56=5,6(g)
a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right);n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: 0,1 0,1 0,15
Tỉ lệ:\(\dfrac{0,1}{2}< \dfrac{0,4}{6}\) ⇒ Al pứ hết,HCl dư
\(\Rightarrow m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
b,\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
c,\(m_{Fe_2O_3\left(tinhkhiét\right)}=38,4.\left(100\%-20\%\right)=30,72\left(g\right)\)
⇒\(n_{Fe_2O_3}=\dfrac{30,72}{160}=0,192\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol : 0,15 0,1
Tỉ lệ:\(\dfrac{0,192}{1}>\dfrac{0,15}{3}\)⇒ Fe2O3 dư,H2 hết
=> mFe = 0,1.56 =5,6 (g)
nNaOH=0,2mol
a) PTHH: 2NaOH+H2SO4=> Na2SO4+2H2O
0,2=>0,1
=> V H2SO4=0,1:0,5=0,2l=200ml
b) 2NaOH+SO2=>Na2SO3+H2O
2/15=>1/15
NaOH+SO2=>NaHSO3
1/15=>1/15
=> VSO2=2.1/15.22,4=2,98l
Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)\)
a. PTHH: Na2SO3 + 2HCl ---> 2NaCl + SO2 + H2O
Theo PT: \(n_{SO_2}=n_{Na_2CO_3}=0,1\left(mol\right)\)
=> \(V_{SO_2}=0,1.22,4=2,24\left(lít\right)\)
b. Theo PT: \(n_{HCl}=2.n_{SO_2}=2.0,1=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
=> \(C_{\%_{HCl}}=\dfrac{7,3}{150}.100\%=4,87\%\)
c. Ta có: \(m_{dd_{NaCl}}=n_{Na_2SO_{3_{PỨ}}}=50\left(g\right)\)
Theo PT: \(n_{NaCl}=n_{HCl}=0,2\left(mol\right)\)
=> \(m_{NaCl}=0,2.58,5=11,7\left(g\right)\)
=> \(C_{\%_{NaCl}}=\dfrac{11,7}{50}.100\%=23,4\%\)
a) \(n_{Na_2CO_3}=\dfrac{26,5}{106}=0,25\left(mol\right)\)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
_____0,25------>0,5--------->0,5---->0,25
VCO2 = 0,25.22,4 = 5,6(l)
b) mHCl = 0,5.36,5 = 18,25(g)
=> a = \(\dfrac{18,25.100}{20}=91,25\left(g\right)\)
c) mNaCl = 0,5.58,5 = 29,25 (g)
d) PTHH: NaOH + HCl --> NaCl + H2O
_________0,4---->0,4
=> Không trung hòa đc hết lượng axit