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a) C2H4 + Br2 --> C2H4Br2
b) \(n_{Br_2}=\dfrac{24}{160}=0,15\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,15<--0,15----->0,15
=> \(\%V_{C_2H_4}=\dfrac{0,15.22,4}{7,84}.100\%=42,857\%\)
=> \(\%V_{CH_4}=\dfrac{7,84-0,15.22,4}{7,84}.100\%=57,143\%\)
c) mC2H4Br2 = 0,15.188 = 28,2 (g)
a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
a) C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> a + b = \(\dfrac{1,68}{22,4}=0,075\left(mol\right)\) (1)
\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
=> a + 2b = 0,1 (2)
(1)(2) => a = 0,05 (mol); b = 0,025 (mol)
=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,075}.100\%=66,67\%\\\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100\%=33,33\%\end{matrix}\right.\)
c)
PTHH: C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,025-->0,0625
=> VO2 = (0,15 + 0,0625).22,4 = 4,76 (l)
a.b.\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)
\(n_{hh}=\dfrac{1,68}{22,4}=0,075mol\)
Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
x 2x ( mol )
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\2x+y=0,1\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,05\end{matrix}\right.\)
\(\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100=33,33\%\)
\(\%V_{C_2H_4}=100\%-33,33\%=66,67\%\)
c.
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,025 0,0625 ( mol )
\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,15 ( mol )
\(V_{O_2}=\left(0,0625+0,15\right).22,4=4,76l\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Ta có: \(n_{C_2H_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=\dfrac{8}{160}=0,05\left(mol\right)\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{C_2H_4}=0,55\\n_{C_2H_2}=-0,25\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.
C2H4+Br2->C2H4Br2
0,05----0,05
n Br2=\(\dfrac{8}{160}\)=0,05 mol
=>%VC2H4=\(\dfrac{0,05.22,4}{5,6}.100=20\%\)
=>%VCH4=80%
c)CH4+2O2-to>CO2+2H2O
1.10-3----2.10-3 mol
C2H4+3O2-to>2CO2+2H2O
2,5.10-4-7,5.10-4 mol
n hh=\(\dfrac{0,028}{22,4}\)=1,25.10-3 mol
=>n C2H4=2,5.10-4 mol
=>n CH4=1.10-3 mol
=>VO2=(2.10-3+7,5.10-4).22,4=0,0616l
\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)
\(\Rightarrow n_{etilen}=n_{Br_2}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(\Rightarrow n_{metan}=n_{hh}-n_{etilen}=0,25-0,05=0,2mol\)
a)\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b)\(\%V_{metan}=\dfrac{0,2}{0,25}\cdot100\%=80\%\)
\(\%V_{etilen}=100\%-80\%=20\%\)
a) C2H4 + Br2 --> C2H4Br2
b) nBr2 = 0,2.0,2 = 0,04 (mol)
PTHH: C2H4 + Br2 --> C2H4Br2
0,04<--0,04
=> \(m_{C_2H_4}=0,04.28=1,12\left(g\right)\)
\(m_{CH_4}=n_{CH_4}.M_{CH_4}=\left(\dfrac{1,12}{22,4}-0,04\right).16=0,16\left(g\right)\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04.22,4}{1,12}.100\%=80\%\\\%V_{CH_4}=100\%-80\%=20\%\end{matrix}\right.\)