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\(\left\{{}\begin{matrix}CuO:a\\Fe2O3:2a\end{matrix}\right.\)
a.\(80a+320a=24\Leftrightarrow a=0.06\)
\(\Rightarrow\left\{{}\begin{matrix}CuO=0.06\\Fe2O3=0.12\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}CuO=4.8g\\Fe2O3=19.2g\end{matrix}\right.\)
b.\(CuO+H2\rightarrow Cu+H2O\)
a a a
\(Fe2O3+3H2\rightarrow2Fe+3H2O\)
2a 6a 4a
\(\Rightarrow V_{H2}=\left(a+6a\right)\times22.4=9.408l\)
c.nHCl = 0.2 mol
\(Fe+2HCl\rightarrow FeCl2+H2\)
0.1 0.2
m chất rắn còn lại = mCu + m Fe ban đầu - m Fe bị hòa tan
= \(a\times64+4a\times56-0.1\times56=11.68g\)
a, -Gọi số mol của CuO và Fe2O3 lần lượt là x, y ( mol )
PTKL : \(80x+160y=40\left(I\right)\)
\(CuO+H_2\rightarrow Cu+H_2O\)
..x.........x............
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
...y............3y......
=> \(n_{H_2}=x+3y=\dfrac{V}{22,4}=0,6\left(mol\right)\left(II\right)\)
- Giair I và II ta được : x = 0,3 , y = 0,1 ( mol )
=> \(\left\{{}\begin{matrix}mCuO=n.M=24\left(g\right)\\mFe2O3=mhh-mCuO=16\left(g\right)\end{matrix}\right.\)
b, \(\%CuO=\dfrac{m}{mhh}.100\%=60\%\)
=> %Fe2O3 =100% - %CuO = 40% .
Vậy ...
a.b.
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=40.80\%=32g\\m_{CuO}=40-32=8g\end{matrix}\right.\)
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\n_{CuO}=\dfrac{8}{80}=0,1mol\end{matrix}\right.\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,2 0,6 0,4 ( mol )
\(V_{H_2}=\left(0,1+0,6\right).22,4=15,68l\)
\(\left\{{}\begin{matrix}m_{Cu}=0,1.64=6,4g\\m_{Fe}=0,4.56=22,4g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{6,4}{6,4+22,4}.100=22,22\%\\\%m_{Fe}=100\%-22,22\%=77,78\%\end{matrix}\right.\)
c.
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) ( Cu không phản ứng với H2SO4 loãng )
0,4 0,4 ( mol )
\(V_{H_2}=0,4.22,4=8,96l\)
Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
\(m_{CuO}+m_{Fe_2O_3}=40\\ \Rightarrow80x+160y=40\left(1\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ \left(mol\right)......x\rightarrow.x\\ PTHH:Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\\ \left(mol\right).....y\rightarrow....3y\\ V_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ \Rightarrow x+3y=0,6\left(2\right)\)
\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}80x+160y=40\\x+3y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,1\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}m_{CuO}=80.0,3=24\left(g\right)\\m_{Fe_2O_3}=40-24=16\left(g\right)\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=100\%-60\%=40\%\end{matrix}\right.\)
a)
CuO + H2 --to--> Cu + H2O
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
b) \(n_{Fe_2O_3}=\dfrac{32.20\%}{160}=0,04\left(mol\right)\)
\(n_{CuO}=\dfrac{32-0,04.160}{80}=0,32\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,32-->0,32---->0,32
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,04-->0,12-------->0,08
=> VH2 = (0,32 + 0,12).22,4 = 9,856 (l)
c)
mCu = 0,32.64 = 20,48 (g)
mFe = 0,08.56 = 4,48 (g)
a)
\(m_{CuO}=\dfrac{32.40}{100}=12,8\left(g\right)\) => \(n_{CuO}=\dfrac{12,8}{80}=0,16\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{32-12,8}{160}=0,12\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,16->0,16---->0,16
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,12-->0,36----->0,24
=> \(V_{H_2}=\left(0,16+0,36\right).22,4=11,648\left(l\right)\)
b)
mCu = 0,16.64 =10,24 (g)
mFe = 0,24.56 = 13,44 (g)
c)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,24}{1}< \dfrac{0,5}{2}\) => HCl dư, Fe hết
PTHH: Fe + 2HCl --> FeCl2 + H2
0,24------------------->0,24
=> \(V_{H_2}=0,24.22,4=5,376\left(l\right)\)
\(a) CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\\ b) n_{CuO} = \dfrac{32.25\%}{80} = 0,1(mol)\\ n_{Fe_2O_3} = \dfrac{32-0,1.80}{160} = 0,15(mol)\\ n_{Cu} = n_{CuO} = 0,1(mol) \Rightarrow m_{Cu} = 0,1.64 = 6,4(gam)\\ n_{Fe} = 2n_{Fe_2O_3} = 0,3(mol) \Rightarrow m_{Fe} = 0,3.56 = 16,8(gam)\)
Câu 1:
a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Giả sử: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
⇒ 80x + 160y = 40 (1)
Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PT: \(\Sigma n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=x+3y\left(mol\right)\)
⇒ x + 3y = 0,6 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,3.80=24\left(g\right)\\m_{Fe_2O_3}=0,1.160=16\left(g\right)\end{matrix}\right.\)
b, Ta có: \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=40\%\end{matrix}\right.\)
Câu 4:
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
Ta có: \(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\)
\(n_{H_2O}=\dfrac{150}{18}=\dfrac{25}{3}\left(mol\right)\)
Xét tỉ lệ ta được H2O dư.
Theo PT: \(n_{NaOH}=n_{Na}=0,3\left(mol\right)\) \(\Rightarrow m_{NaOH}=0,3.40=12\left(g\right)\)
\(n_{H_2}=\dfrac{1}{2}n_{Na}=0,15\left(mol\right)\)
Ta có: m dd sau pư = mNa + mH2O - mH2 = 6,9 + 150 - 0,15.2 = 156,6 (g)
\(\Rightarrow C\%_{NaOH}=\dfrac{12}{156,6}.100\%\approx7,66\%\)
Bạn tham khảo nhé!
PTHH: 2Na +2H2O →2NaOH+ H2 ↑
\(+n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\)
Theo PTHH ta có:
\(+n_{NaOH}=n_{Na}=0,3\left(mol\right)\)
\(+n_{H_2}=\dfrac{1}{2}n_{Na}=0,15\left(mol\right)\)
\(+m_{NaOH}=0,3.40=12\left(gam\right)\)
\(+C\%_{NaOH}=\dfrac{12}{150+6,9-0,15.2}.100\%\approx7,66\%\)
Đáp án:
8,96 l
Giải thích các bước giải:
a)
Fe2O3+3H2->2Fe+3H2O
CuO+H2->Cu+H2O
gọi a là số mol Fe2O3 b là số mol CuO
Ta có
160a=2x80b=>a=b
ta có
112a+64b=17,6
a=b
=>a=0,1 b=0,1
nH2=0,1x3+0,1=0,4(mol)
VH2=0,4x22,4=8,96 l