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\(n_{HCl}=0,3.2=0,6\left(mol\right)\\a, 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b,n_{H_2}=\dfrac{3}{6}.0,6=0,3\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,n_{Al}=n_{AlCl_3}=\dfrac{2}{6}.0,6=0,2\left(mol\right)\\ m_{Al}=0,2.27=5,4\left(g\right)\\ d,V_{ddAlCl_3}=V_{ddHCl}=0,3\left(l\right)\\ C_{MddHCl}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\left(M\right)\)
\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ n_{H_2SO_4}=0,16.5=0,8\left(mol\right)\)
PTHH: 2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
LTL: \(\dfrac{0,2}{2}< \dfrac{0,8}{3}\rightarrow\)H2SO4 dư
Theo pt: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,2=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,2=0,1\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Al_2\left(SO_4\right)_3}=0,1.342=34,2\left(g\right)\\V_{H_2}=0,3.22,4=6,72\left(l\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{5}=0,04M\\C_{M\left(H_2SO_4.dư\right)}=\dfrac{0,8-0,3}{5}=0,1M\end{matrix}\right.\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{FeCl_2}=n_{H_2}=n_{Fe}=0,15\left(mol\right)\\ n_{HCl}=0,15.2=0,3\left(mol\right)\\ a,m_{FeCl_2}=127.0,15=19,05\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,02}=15\left(M\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\end{matrix}\right.\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\ a,m_{AlCl_3}=133,5.0,1=13,35\left(g\right)\\ n_{H_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,n_{HCl}=\dfrac{6}{2}.0,1=0,3\left(mol\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{Zn}=n_{H_2}=0,15\left(mol\right);n_{HCl}=2.0,15=0,3\left(mol\right)\\ a,m=m_{Zn}=0,15.65=9,75\left(g\right)\\ b,C_{MddHCl}=\dfrac{0,3}{0,15}=0,2\left(l\right)\\ c,m_{ZnCl_2}=0,15.136=20,4\left(g\right)\)
n Zn= 19,5/65=0,3 (mol).
PTPƯ: Zn(0.3) + HCl(0.6) ----> ZnCl2(0.3) + H2(0,3)
mHCl=0,6.36.5=21.9(g)
a) C%HCl= 21.9/300.100%=7,3%
b) VH2=0,3.22,4=6,72(lít)
c) mH2=0,3.2=0,6(g)
mZnCl2=0,3.136=40,8(g)
mddZnCl2 =(19,5+300)-0,6=318,9(g)
C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%
nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)