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Đầu tiên bạn tính n H2 = cách bảo toàn e =» n hcl pư =» m dd hcl pư
Bạn bảo toàn ntố Fe để tím n FeCl2 =» m FeCl2 (dd B)
C% dd B = m FeCl 2 / (m Fe + m dd HCl)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}\cdot0,11\cdot1,5=0,0825\left(mol\right)\)
\(\Rightarrow m_{Mg}=0,0825\cdot24=1,98\left(g\right)\)
\(n_{BaCl_2}=\dfrac{200.20,8\%}{208}=0,2\left(mol\right)\\ PTHH:BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ n_{BaSO_4}=n_{H_2SO_4}=n_{BaCl_2}=0,2\left(mol\right)\\ a,m_{kt}=m_{BaSO_4}=233.0,2=46,6\left(g\right)\\ b,C\%_{ddH_2SO_4}=\dfrac{0,2.98}{200}.100\%=9,8\%\)
Oxit kim loại : R2On
\(\%R = \dfrac{2R}{2R + 16n}.100\% = 60\%\\ \Rightarrow R = 12n\)
Với n = 2 thì R = 24(Magie)
Vậy oxit là MgO
\(MgO+ H_2SO_4 \to MgSO_4 + H_2O\\ n_{MgSO_4} = n_{H_2SO_4} = n_{MgO} = \dfrac{20}{40} = 0,5(mol)\\ \Rightarrow m_{dd\ H_2SO_4} =\dfrac{0,5.98}{10\%} = 490(gam)\\ m_{dd\ sau\ pư} = 20 + 490 = 510(gam)\\ \Rightarrow C\%_{MgSO_4} = \dfrac{0,5.120}{510}.100\% = 11,76\%\)
\(a,m_{BaCl_2}=\dfrac{200.20,8\%}{100\%}=41,6g\\ n_{BaCl_2}=\dfrac{41,6}{208}=0,2mol\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ n_{BaSO_4}=n_{H_2SO_4}=n_{BaCl_2}=0,2mol\\ m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6g\\ b,m_{H_2SO_4}=0,2.98=19,6g\\ C_{\%H_2SO_4}=\dfrac{19,6}{200}\cdot100\%=9,8\%\)
Bài 1:
\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)
Bài 2:
\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)
2Al + 3H2SO4 \(\rightarrow\)Al2(SO4)3 + 3H2
nAl=\(\dfrac{5,4}{27}=0,2\left(mol\right)\)
Theo PTHH ta có:
\(\dfrac{1}{2}\)nAl=nAl2(SO4)3=0,1(mol)
nH2=\(\dfrac{3}{2}\)nAl=0,3(mol)
nH2SO4=nH2=0,3(mol)
mH2SO4=98.0,3=29,4(g)
mdd H2SO4=\(29,4:\dfrac{19,6}{100}=150\left(g\right)\)
mAl2(SO4)3=0,1.342=34,2(g)
C% Al2(SO4)3 =\(\dfrac{34,2}{5,4+150-0,3.2}.100\%=22,09\%\)