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a)Đổi \(V_{H_2SO_4}=100ml=0,1l\)
Số mol của 2,7 gam Al:
\(n_{Al}=\dfrac{m}{M}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)3+3H_2\)
Tỉ lệ 2 : 3 : 1 : 3
0,1 -> 0,15 : 0,05 : 0,15(mol)
Nồng độ mol của dung dịch H2SO4:
\(C_{M_{H_2SO_4}}=\dfrac{n_{H_2SO_4}}{V_{H_2SO_4}}=\dfrac{0,15}{0,1}=1,5\left(M\right)\)
b) thể tích của 0,15 mol H2:
\(V_{H_2}=n.22,4=0,15.22,4=3,36\left(l\right)\)
c) nồng độ mol của dd \(Al_2\left(SO_4\right)_3\) :
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{n}{V}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
\(a) n_{Fe_2O_3}= \dfrac{8}{160} = 0,05(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{FeCl_3} = 2n_{Fe_2O_3} = 0,1(mol)\\ m_{FeCl_3} = 0,1.162,5 = 16,25(gam)\\ b) n_{HCl} = 6n_{Fe_2O_3} = 0,05.6 = 0,3(mol)\\ V_{dd\ HCl} = \dfrac{0,3}{0,5} = 0,6(lít)\\ c) V_{dd\ sau\ pư} = V_{dd\ HCl} =0,6(lít)\\ C_{M_{FeCl_3}} = \dfrac{0,1}{0,6} = 0,167M\)
PTHH:\(Fe_2O_3+HCl\rightarrow FeCl_3+3H_2O\)
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
a, Bảo toàn nguyên tố Fe:
\(n_{FeCl_3}=n_{Fe}=2n_{Fe_2O_3}=2.0,05=0,1\left(mol\right)\)
\(\Rightarrow m_{FeCl_3}=162,5.0,1=16,25\left(g\right)\)
b, Bảo toàn nguyên tố Cl:
\(n_{Hcl}=n_{Cl}=3n_{FeCl_3}=3.0,1=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{n_{HCL}}{C_M}=\dfrac{0,3}{0,5}=0,6\left(l\right)\)
c,\(C_{M_{FeCl_3}}=\dfrac{n_{FeCl_3}}{V_{ddFeCl_3}}=\dfrac{0,1}{0,6}=0,17M\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\) (mol) (1)
Phương trình hóa học :
Fe + 2HCl ---> FeCl2 + H2 (2)
Từ (1) và (2) ta có \(n_{FeCl_2}=n_{H_2}=0,4\) (mol) ; \(n_{HCl}=0,8\left(mol\right)\)
b) => \(m_{\text{muối}}=0,4.\left(56+35,5.2\right)=50.8\left(g\right)\)
c) \(V_{\text{khí}}=0,4.22,4=8,96\left(l\right)\)
d) \(m_{HCl}=0,8.36.5=29,2\left(g\right)\)
\(\Rightarrow C\%=\dfrac{29,2}{200}.100\%=14,6\%\)
\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
a
PTPỨ:
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
0,1------>0,1------>0,1
b
\(m_{muối}=m_{CuSO_4}=0,1.160=16\left(g\right)\)
\(V_{dd.H_2SO_4.pứ}=\dfrac{0,1}{0,5}=0,2\left(l\right)\)
Sửa đề : 11.2 g sắt
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(0.2....0.2.................0.2\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(C_{M_{H_2SO_4}}=\dfrac{0.2}{0.05}=4\left(M\right)\)
\(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
\(n_{HCl}=2.0,2=0,4\left(mol\right)\)
PTHH :
\(CuO+2HCl\rightarrow CuCl_2+H_2\uparrow\)
trc p/ư: 0,15 0,4
p/ư : 0,15 0,3 0,15 0,15
sau p/ư : 0 0,1 0,15 0,15
--> sau p/ư : HCl dư
\(a,m_{CuCl_2}=0,15.135=20,25\left(g\right)\)
\(b,C_{M\left(CuCl_2\right)}=\dfrac{0,15}{0,2}=0,75\left(M\right)\)
\(a)n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ n_{HCl}=0,2.2=0,4\left(mol\right)\\ CuO+2HCl\xrightarrow[]{}CuCl_2+H_2\\ \dfrac{0,15}{1}< \dfrac{0,4}{2}\Rightarrow HCl.dư\\ n_{CuCl_2}=n_{CuO}=n_{H_2}=0,15mol\\ m_{CuCl_2}=0,15.135=20,25\left(g\right)\\ b)C_{MCuCl_2}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\ n_{HCl\left(pư\right)}=0,15.2=0,3\left(mol\right)\\ n_{HCl\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\\ C_{MHCl\left(dư\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
\(n_{HCl}=0,3.2=0,6\left(mol\right)\\a, 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ b,n_{H_2}=\dfrac{3}{6}.0,6=0,3\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,n_{Al}=n_{AlCl_3}=\dfrac{2}{6}.0,6=0,2\left(mol\right)\\ m_{Al}=0,2.27=5,4\left(g\right)\\ d,V_{ddAlCl_3}=V_{ddHCl}=0,3\left(l\right)\\ C_{MddHCl}=\dfrac{0,2}{0,3}=\dfrac{2}{3}\left(M\right)\)
\(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\\a, CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{H_2SO_4}=n_{CuO}=0,05\left(MOL\right)\\ b,m_{CuSO_4}=0,05.160=8\left(g\right)\\ c,V_{ddH_2SO_4}=\dfrac{0,05}{0,5}=0,1\left(l\right)\\ d,V_{ddCuSO_4}=V_{ddH_2SO_4}=0,1\left(l\right)\\ C_{MddCuSO_4}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)