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\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 0,25.........0,5.........0,25.......0,25\left(mol\right)\\ a.V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b.m_{HCl}=0,5.36,5=18,25\left(g\right)\\ c.n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\ Fe_2O_3+3H_2\underrightarrow{^{to}}2Fe+3H_2O\\ Vì:\dfrac{0,25}{3}< \dfrac{0,1}{1}\\ \Rightarrow Fe_2O_3dư\\ n_{Fe}=\dfrac{2}{3}.0,25=\dfrac{1}{6}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{1}{6}.56\approx9,333\left(g\right)\)
a,\(n_{Mg}=\dfrac{6}{24}=0,25\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,25 0,5 0,25
\(\Rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
b,\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
c,\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,25 \(\dfrac{1}{6}\)
Ta có: \(\dfrac{0,1}{1}>\dfrac{0,25}{3}\)⇒ Fe2O3 dư, H2 hết
\(m_{Fe}=\dfrac{1}{6}.56=9,33\left(g\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{H_2}=n_{Mg}=0,2\left(mol\right)\\ n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\\ CuO+H_2\underrightarrow{^{to}}Cu+H_2O\\ Vì:\dfrac{0,25}{1}>\dfrac{0,2}{1}\\ \Rightarrow CuOdư\\ \Rightarrow n_{Cu}=n_{H_2}=0,2\left(mol\right)\\ m_{Cu}=0,2.64=12,8\left(g\right)\)
\(n_{Mg}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,2 0,2
\(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
Pt : \(H_2+CuO\rightarrow\left(t_o\right)Cu+H_2O|\)
1 1 1 1
0,2 0,25 0,2
Lập tỉ số so sánh : \(\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
⇒ H2 phản ứng hết , CuO dư
⇒ Tính toán dựa vào số mol của H2
\(n_{Cu}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{Cu}=0,2.64=12,8\left(g\right)\)
Chúc bạn học tốt
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
\(n_{Mg}=\dfrac{1,2}{24}=0,05(mol)\\ Mg+H_2SO_4\to MgSO_4+H_2\\ \Rightarrow n_{H_2}=0,05(mol)\\ \Rightarrow V_{H_2}=0,05.22,4=1,12(l)\)
a) Gọi số mol CH3COOH, C2H5OH là a, b (mol)
=> 60a + 46b = 25,8 (1)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: 2Na + 2CH3COOH --> 2CH3COONa + H2
a------------------------->0,5a
2Na + 2C2H5OH --> 2C2H5ONa + H2
b--------------------->0,5b
=> 0,5a + 0,5b = 0,25 (2)
(1)(2) => a = 0,2 (mol); b = 0,3 (mol)
=> \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,2.60}{25,8}.100\%=46,51\%\\\%m_{C_2H_5OH}=\dfrac{0,3.46}{25,8}.100\%=53,49\%\end{matrix}\right.\)
b)
\(n_{CH_3COOC_2H_5}=\dfrac{13,2}{88}=0,15\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
0,15<---------------------------------0,15
=> \(H=\dfrac{0,15}{0,2}.100\%=75\%\)
a, Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
2C2H5OH + 2Na ---> 2C2H5ONa + H2
a---------------------------------------->0,5a
2CH3COOH + 2Na ---> 2CH3COONa + H2
b------------------------------------------------>0,5b
=> hệ pt \(\left\{{}\begin{matrix}46a+60b=48,8\\0,5a+0,5b=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,8\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,8.46=36,8\left(g\right)\\m_{CH_3COOH}=0,2.60=12\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100\%=75,41\%\\\%m_{CH_3COOH}=100\%-75,41\%=24,59\%\end{matrix}\right.\)
b, PTHH:
\(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_4đặc}CH_3COOC_2H_5+H_2O\)
LTL: 0,8 > 0,2 => Rượu dư
\(n_{CH_3COOC_2H_5\left(tt\right)}=0,2.85\%=0,17\left(mol\right)\\ m_{este}=0,17.88=14,96\left(g\right)\)
a.Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=x\\n_{CH_3COOH}=y\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)
x 1/2 x ( mol )
\(2CH_3COOH+Na\rightarrow2CH_3COONa+H_2\)
y 1/2 y ( mol )
Ta có:
\(\left\{{}\begin{matrix}46x+60y=48,8\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,2\end{matrix}\right.\)
\(\rightarrow m_{C_2H_5OH}=0,8.46=36,8g\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100=75,4\%\\\%m_{CH_3COOH}=100\%-75,4\%=24,6\%\end{matrix}\right.\)
b.\(C_2H_5OH+CH_3COOH\rightarrow\left(H_2SO_4\left(đ\right),t^o\right)CH_3COOC_2H_5+H_2O\)
0,8 < 0,2 ( mol )
0,2 0,2 ( mol )
\(m_{CH_3COOC_2H_5}=0,2.88.85\%=14,96g\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
____0,2__________________0,2 (mol)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
Bạn tham khảo nhé!
nMg = \(\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + H2SO4 ---> MgSO4 + H2
Theo PT: \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\)
=> \(V_{H_2}=0,2.22,4=4,48\left(lít\right)\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,2 0,2
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)