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\(2Na+2C_2H_5OH\rightarrow2C_2H_5ONa+H_2\\ n_{C_2H_5OH}=\dfrac{4,6}{46}=0,1\left(mol\right)\\ n_{Na}=n_{C_2H_5OH}=0,1\left(mol\right)\\ n_{H_2}=\dfrac{0,1}{2}=0,05\left(mol\right)\\ a=m_{Na}=0,1.23=2,3\left(g\right)\\ V=V_{H_2\left(đktc\right)}=0,05.22,4=1,12\left(l\right)\)
Câu 2:
V(C2H5OH)= 2 x 30/100= 0,6(l)
=> V(H2O)=V(H2O,C2H5OH) - V(C2H5OH)=2-0,6=1,4(l)
=> Cách pha: Rót thêm 1,4 lít nước vào 0,6 lít C2H5OH ta sẽ được 2 lít rượu etylic 30o
Câu 1 :
\(n_{CH_3COOH}=\dfrac{200\cdot12\%}{60}=0.4\left(mol\right)\)
\(2CH_3COOH+CaCO_3\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\)
\(0.4........................0.2................0.2..................0.2\)
\(m_{CaCO_3}=0.2\cdot100=20\left(g\right)\)
\(V_{CO_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{\left(CH_3COO\right)_2Ca}=0.2\cdot158=31.6\left(g\right)\)
\(a,PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ b,n_{H_2}=\dfrac{16,8}{22,4}=0,74(mol)\\ \Rightarrow n_{Fe}=0,75(mol)\\ \Rightarrow m_{Fe}=0,75.56=42(g)\\ c,n_{H_2SO_4}=\dfrac{245.10\%}{100\%.98}=0,25(mol)\)
Vì \(\dfrac{n_{Fe}}{1}>\dfrac{n_{H_2SO_4}}{1}\) nên \(Fe\) dư
\(n_{Fe(dư)}=0,75-0,25=0,5(mol)\\ \Rightarrow m_{Fe(dư)}=0,5.56=28(g)\)
a) Fe + H2SO4 → FeSO4 + H2
b) Ta có : nH2 = \(\dfrac{16,8}{22,4}\) = 0,75 (mol)
⇒ nFe= 0,75.56 = 42(gam)
\(n_{HCl}=\dfrac{18.25}{36.5}=0.5\left(mol\right)\)
\(a.Mg+2HCl\rightarrow MgCl_2+H_2\)
\(b.\)
\(n_{Mg}=n_{H_2}=\dfrac{1}{2}\cdot n_{HCl}=\dfrac{1}{2}\cdot0.5=0.25\left(mol\right)\)
\(m_{Mg}=0.25\cdot24=6\left(g\right)\)
\(V_{H_2}=0.25\cdot22.4=5.6\left(l\right)\)
\(c.\)
\(V_{H_2\left(tt\right)}=5.6\cdot90\%=5.04\left(l\right)\)
\(n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\a, PTHH:C_2H_5OH+3O_2\rightarrow\left(t^o\right)2CO_2+3H_2O\\ b,n_{O_2}=3.0,5=1,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=22,4.1,5=33,6\left(l\right)\\ c,V_{C_2H_5OH}=46\%.100=46\left(ml\right)\\ C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\\ n_{C_2H_5OH}=\dfrac{0,8.46}{46}=0,8\left(mol\right)\\ n_{H_2}=\dfrac{0,8}{2}=0,4\left(mol\right)\Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\)
a, \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
b, \(n_{CH_3COOH}=\dfrac{3,6}{60}=0,06\left(mol\right)\)
Theo PT: \(n_{\left(CH_3COO\right)_2Mg}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,03\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Mg}=0,03.142=4,26\left(g\right)\)
\(V_{H_2}=0,06.22,4=1,344\left(l\right)\)
