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a)
\(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
PTHH: Zn + H2SO4 --> ZnSO4 + H2
0,25-->0,25------------->0,25
=> VH2 = 0,25.22,4 = 5,6 (l)
b) \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,25}{0,3}=\dfrac{5}{6}M\)
c) \(n_{Fe_2O_3}=\dfrac{32}{160}=0,2\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,25}{3}\) => Fe2O3 dư, H2 hết
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
\(\dfrac{0,25}{3}\) <--0,25----->\(\dfrac{0,5}{3}\)
=> \(m=32-\dfrac{0,25}{3}.160+\dfrac{0,5}{3}.56=28\left(g\right)\)
PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
đb: 0,25
a) số mol của Zn là: \(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
Theo PTHH, ta có: \(n_{H_2}=\dfrac{0,25\cdot1}{1}=0,25\left(mol\right)\)
Thể tích của H2 ở đktc là: \(V_{H_2\left(đktc\right)}=n_{H_2}\cdot22,4=0,25\cdot22,4=5,6\left(l\right)\)
2 câu còn lại mk chịu
`Zn + H_2 SO_4 -> ZnSO_4 + H_2`
`0,25` `0,25` `0,25` `(mol)`
`n_[Zn]=[16,25]/65=0,25(mol)`
`a)V_[H_2]=0,25.22,4=5,6(l)`
`b)C_[M_[H_2 SO_4]]=[0,25]/[0,3]~~0,8(M)`
`c)`
`H_2 + 3Fe_2 O_3` $\xrightarrow{t^o}$ `2Fe_3 O_4 + H_2 O`
`1/15` `0,2` `2/15` `(mol)`
`n_[Fe_2 O_3]=32/160=0,2(mol)`
Ta có:`[0,25]/1 > [0,2]/3`
`=>H_2` dư
`=>m_[Fe_3 O_4]=2/15 . 232~~30,93(g)`
2H2+O2-to>2H2O
0,1----0,05----0,1mol
n H2=\(\dfrac{2,24}{22,4}=0,1mol\)
=>m H2O=0,1.18=1,8g
2Na+2H2O->2NaOH+H2
0,1----0,1-------0,1------0,05
n Na=\(\dfrac{3,45}{23}\)=0,15 mol
=>Na dư
=>VH2=0,05.22,4=1,12l
\(2H_2+O_2\underrightarrow{t^o}2H_2O\)
\(nH_2=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(mH_2O=0,1.18=1,8\left(g\right)\)
\(H_2O+2Na\rightarrow Na_2O+H_2\uparrow\)
\(nNa=\dfrac{3,45}{23}=0,15\left(mol\right)\)
\(\dfrac{0,1}{1}>\dfrac{0,15}{2}\)
=> Na dư , H2O đủ
\(mH_2=0,1.22,4=2,24\left(l\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ m_{HCl}=200.27,375\%=54,75\left(g\right)\\ n_{HCl}=\dfrac{54,75}{36,5}=1,5\left(mol\right)\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
a ----> 2a --------> a -----> a
Fe + 2HCl ---> FeCl2 + H2
b ---> 2b -------> b ------> b
Hệ pt \(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=0,5.65=32,5\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
\(m_{dd}=43,7+200-0,7.2=242,3\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,5.136}{242,3}=28,06\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{242,3}=10,48\%\\C\%_{HCl\left(dư\right)}=\dfrac{\left(1,5-0,5.2-0,2.2\right).36,5}{242,3}=1,51\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\
pthh:\left\{{}\begin{matrix}Zn+H_2SO_4->ZnSO_4+H_2\\Fe+H_2SO_4->FeSO_{\text{ 4 }}+H_2\end{matrix}\right.\)
gọi số mol Zn là x , số mol Fe là y
=> 65x+56y=43,7
=> a+b=0,7
=>a=0,5 , b =0,2
=> \(m_{Zn}=0,5.65=32,5\\ m_{Fe}=43,7-32,5=11,2\left(G\right)\)
2Na+2H2O->2NaOH+H2
x-------------------x----------0,5x mol
Ba+2H2O->Ba(OH)2+H2
y---------------------y----------y mol
aTa có :)\(\left\{{}\begin{matrix}23x+137y=2,06\\0,5x+y=0,025\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,03\\y=0,01\end{matrix}\right.\)
=>mbazo=0,03.40+0,01.171=2,91g
=>m Na=0,03.23=0,69g
=>m Ba=0,01.137=1,27g
\(1.\\ n_A=\dfrac{16,8}{A}mol\\ n_{H_2}=\dfrac{7,437}{24,79}=0,3mol\\ A+2HCl\rightarrow ACl_2+H_2\\ \Rightarrow\dfrac{16,8}{A}=0,3\\ \Rightarrow A=56g/mol\\ \Rightarrow A.là.Fe\\ \Rightarrow Chọn.A\\ 2.\\ n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,1mol\\ V_{H_2}=0,1.24,79=2,479l\\ \Rightarrow Chọn.B\\ 3.\\ Axit:H_2SO_4;HCl\\ \Rightarrow Chọn.B\\ 4.\\ 3,719l\Rightarrow3,7185\\ CTHH:R\\ n_R=\dfrac{3,6}{R}mol\\ n_{H_2}=\dfrac{3,7185}{24,79}=0,15mol\\ R+2HCl\rightarrow RCl_2+H_2\\ \Rightarrow\dfrac{3,6}{R}=0,15\\ \Rightarrow R=24g/mol,Mg\\ \Rightarrow Chọn.B\)
\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(m_{ct}=\dfrac{14,6.50}{100}=7,3\left(g\right)\)
\(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,05 0,2 0,05 0,05
a) Lập tỉ số so sánh : \(\dfrac{0,05}{1}< \dfrac{0,2}{2}\)
⇒ Zn phản ứng hết , HCl dư
⇒ Tính toán dựa vào số mol của Zn
\(n_{H2}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
b) \(n_{ZnCl2}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,05.136=6,8\left(g\right)\)
\(n_{HCl\left(dư\right)}=0,2-\left(0,5.2\right)=0,1\left(mol\right)\)
⇒ \(m_{HCl\left(dư\right)}=01,.36,5=3,65\left(g\right)\)
c) \(m_{ddspu}=3,25+50-\left(0,05.2\right)=53,15\left(g\right)\)
\(C_{ZnCl2}=\dfrac{6,8.100}{53,15}=12,8\)0/0
\(C_{HCl\left(dư\right)}=\dfrac{3,65.100}{53,15}=6,88\)0/0
Chúc bạn học tốt
a)
$n_{Zn} = \dfraac{3,25}{65} = 0,05(mol) ; n_{HCl} = \dfrac{50.14,6\%}{36,5} = 0,2(mol)$
$Zn +2 HCl \to ZnCl_2 + H_2$
$n_{Zn} : 1 < n_{HCl} : 2$ nên HCl dư
$n_{H_2} = n_{Zn} = 0,05(mol)$
$V_{H_2} = 0,05.22,4 = 1,12(lít)$
b)
$n_{ZnCl_2} = n_{Zn} = 0,05 \Rightarrow m_{ZnCl_2} = 0,05.136 = 6,8(gam_$
$n_{HCl\ pư} = 2n_{Zn} = 0,1(mol) \Rightarrow m_{HCl\ dư} = (0,2 - 0,1).36,5 = 3,65(gam)$
c)
$m_{dd\ sau\ pư} = 3,25 + 50 - 0,05.2 = 53,15(gam)$
d)
$C\%_{ZnCl_2} = \dfrac{6,8}{53,15}.100\%= 12,8\%$
$C\%_{HCl} = \dfrac{3,65}{53,15}.100\% = 6,87\%$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\); \(n_{A\left(OH\right)_2}=\dfrac{34,2}{M_A+34}\left(mol\right)\)
\(A+2H_2O\rightarrow A\left(OH\right)_2+H_2\)
\(\dfrac{34,2}{M_A+34}\) --> \(\dfrac{34,2}{M_A+34}\) ( mol )
\(\rightarrow n_{H_2}=\dfrac{34,2}{M_A+34}=0,2\left(mol\right)\)
\(\Leftrightarrow34,2=0,2M_A+6,8\)
\(\Leftrightarrow0,2M_A=27,4\)
\(\Leftrightarrow M_A=137\) ( g/mol )
--> A là Bari ( Ba )
\(A+H_2O\rightarrow A\left(OH\right)_2+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ TheoPT:n_{H_2}=n_{A\left(OH\right)_2}=0,2\left(mol\right)\\ \Rightarrow M_{A\left(OH\right)_2}=A+17.2=\dfrac{34,2}{0,2}=171\\ \Rightarrow A=137\left(Ba\right)\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Fe}=0,5\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,25.36,5=18,25\left(g\right)\)
c, Theo PT: \(n_{H_2}=n_{Fe}=0,25\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
