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a) NaOH + HCl --> NaCl + H2O
KOH + HCl --> KCl + H2O
b) Gọi số mol của NaOH, KOH là a, b (mol)
=> 40a + 56b = 3,04
Có nNaOH = nNaCl = a (mol)
=> mNaCl = 58,5a (g)
nKOH = nKCl = b (mol)
=> mKCl = 74,5b (g)
=> 58,5a + 74,5b = 4,15
=> a = 0,02; b = 0,04
\(\left\{{}\begin{matrix}m_{NaOH}=0,02.40=0,8\left(g\right)\\m_{KOH}=0,04.56=2,24\left(g\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}m_{NaCl}=0,02.58,5=1,17\left(g\right)\\m_{KCl}=0,04.74,5=2,98\left(g\right)\end{matrix}\right.\)
c)
PTHH: NaCl + AgNO3 --> NaNO3 + AgCl
0,02------------------------>0,02
KCl + AgNO3 --> KNO3 + AgCl
0,04--------------------->0,04
=> \(m_{AgCl}=\left(0,02+0,04\right).143,5=8,61\left(g\right)\)
\(a,NaOH+HCl\rightarrow NaCl+H_2O\\ KOH+HCl\rightarrow KCl+H_2O\\ b,Đặt:n_{NaOH}=w\left(mol\right);n_{KOH}=e\left(mol\right)\left(w,e>0\right)\\ \Rightarrow\left\{{}\begin{matrix}40w+56e=3,04\\58,5w+74,5e=4,15\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}w=0,02\left(mol\right)\\e=0,04\left(mol\right)\end{matrix}\right.\\ \Rightarrow m_{NaOH}=40w=0,8\left(g\right);m_{KOH}=56e=2,24\left(g\right)\\ c,NaCl+AgNO_3\rightarrow NaNO_3+AgCl\downarrow\\ KCl+AgNO_3\rightarrow KNO_3+AgCl\downarrow\\ n_{AgCl\downarrow}=n_{NaCl}+n_{KCl}=w+e=0,06\left(mol\right)\\ \Rightarrow m_{\downarrow}=m_{AgCl}=143,5.0,06=8,61\left(g\right)\)
Gọi M là kim loại cần tìm
Mỗi phần có \(\dfrac{49,6}{2}=24,8(g)\) hỗn hợp
\(\Rightarrow (2M_M+60)a+(2M_M+96)b=24,8(1)\)
Đặt \(n_{M_2SO_4}=x(mol);n_{M_2CO_3}=y(mol)\)
P1: \(M_2CO_3+H_2SO_4\to M_2SO_4+H_2O+CO_2\uparrow\)
\(\Rightarrow a=n_{CO_2}=\dfrac{2,24}{22,4}=0,1(mol)(2)\)
P2:
\(M_2CO_3+BaCl_2\to 2MCl+BaCO_3\downarrow\\ M_2SO_4+BaCl_2\to 2MCl+BaSO_4\downarrow\)
\(\Rightarrow 197a+233b=m_{\downarrow}=43(2)\\ (2)(3)\Rightarrow a=b=0,1(mol)\)
Thay vào \((1)\Rightarrow M_M=23(g/mol)(Na)\)
\(\Rightarrow CTHH:Na_2CO_3;Na_2SO_4\\ b,n_{Na_2CO_3}=2a=0,2(mol);n_{Na_2SO_4}=2b=0,2(mol)\\ \Rightarrow \%_{Na_2CO_3}=\dfrac{0,2.106}{49.6}.100\%=42,74\%\\ \Rightarrow \%_{Na_2SO_4}=100\%-42,74\%=57,26\%\)
Đặt nK2O=a(mol); nK2O=b(mol) (a,b>0)
Ta có: nHCl=0,6(mol)
K2O + H2O -> 2 KOH
a____________2a(mol)
Na2O + H2O -> 2 NaOH
b___________2b(mol)
KOH + HCl -> KCl + H2O
2a____2a____2a(mol)
NaOH + HCl -> NaCl + H2O
2b___2b______2b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}94a+62b=25\\2a+2b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> mK2O=0,2.94=18,8(g)
=>%mK2O= (18,8/25).100=75,2%
=>%mNa2O=24,8%
b) m(muối)= mKCl+ mNaCl= 74,5.0,4+ 58,5.0,2=41,5(g)
\(n_{CaCO_3}=a\left(mol\right),n_{K_2SO_3}=b\left(mol\right)\)
\(m_{hh}=100a+158=70.3\left(g\right)\left(1\right)\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(K_2SO_3+2HCl\rightarrow2KCl+SO_2+H_2O\)
\(n_{khí}=a+b=0.5\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.15,b=0.35\)
\(m_{Muối}=0.15\cdot111+0.35\cdot2\cdot74.5=68.8\left(g\right)\)
mdd giảm = m↓ - mCO2 → mCO2 = 10 - 3,4 = 6,6 gam → nCO2 = 6,6 : 44 = 0,15 mol.
C6H12O6 enzim−−−−→30−35oC→30-35oCenzim2C2H5OH + 2CO2
Theo phương trình: nC6H12O6 = 0,15 : 2 = 0,075 mol.
Mà H = 90% → nC6H12O6 = 0,075 : 90% = 1/12 mol → m = 180 x 1/12 = 15 gam
Theo đlbtklg ta có:
mX=8,04-2,72=5,32(g)
nX=5,32/X(mol)
Theo đlbtntố ta có:
nAgX=nX=5,32/X(mol)
Ta có:
5,32/X(108+X)=21,525
X=35,5(g/mol)
X là Cl
K hiểu j cứ hỏi lại nha