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\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{0,71}{142}=0,005\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,01<----------------------0,005---------->0,005
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,01}{0,025}=4M\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,005--------->0,005
\(V_{ddNaOH}=\dfrac{0,005}{0,75}=\dfrac{1}{150}M\\ V_{H_2}=0,005.22,4=0,0112\left(l\right)\)
a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)
\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,1 0,1 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)
\(V_{H_2}=0,1.22,4=2,24l\)
b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)
0,2 0,2 ( mol )
\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,2<---------------------------0,1---------->0,1
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2------------->0,2
=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<------------0,01----->0,01
=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,05}=0,4M\)
b) VH2 = 0,01.22,4 = 0,224 (l)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)
PTHH: Mg + 2CH3COOH --> (CH3COO)2Mg + H2
0,02<-----------0,01-------->0,01
=> VH2 = 0,01.22,4 = 0,224 (l)
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)
b)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,02------>0,02
=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{2,84}{142}=0,02\left(mol\right)\)
PTHH :
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,04 0,02 0,02
\(a,C_M=\dfrac{n}{V}=\dfrac{0,04}{0,1}=0,4M\)
\(b,V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(c,PTHH:\)
\(CH_3COOH+C_2H_5OH\underrightarrow{t^o,H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
0,04 0,04
\(m_{este}=0,04.90\%.88=3,168\left(g\right)\)
2CH3COOH + Mg => (CH3COO)2Mg + H2
mmuối = 0.71 (g) => nmuối = m/M = 0.71/142 = 0.005 (mol)
Theo pthh ==> nCH3COOH = 0.01 (mol)
CM = n/V = 0.01/0.05 = 0.2 M
CH3COOH + NaOH => CH3COONa + H2O
Trong 50 ml axit trên có 0.01 mol
Theo pt ===> nNaOH = 0.01 (mol)
Vdd NaOH = n/CM = 0.01/0.75 = 1/75 (l)
\(PTHH:2CH_3COOH+Ca\rightarrow\left(CH_3COO\right)_2Na+H_2\)
Ta có:
\(n_{\left(CH3COO\right)2Na}=\frac{4,47}{158}=0,03\left(mol\right)\)
\(\Rightarrow n_{CH3COOH}=0,03.2=0,06\left(mol\right)\)
\(\Rightarrow CM_{CH3COOH}=\frac{0,06}{0,2}=0,3M\)
\(n_{H2}=0,03\left(mol\right)\Rightarrow V_{H2}=0,03.22,4=6,72\left(l\right)\)
PTHH :
\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
_0,06________0,06_____________________
\(\Rightarrow V_{NaOH}=\frac{0,06}{0,5}=0,12\left(l\right)=120\left(ml\right)\)