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Pt : \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O|\)
1 1 1 1
a 1a 0,05
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O|\)
1 3 1 3
b 3b 0,05
Gọi a là số mol của MgO
b là số mol của Fe2O3
\(m_{MgO}+m_{Fe2O3}=10\left(g\right)\)
⇒ \(n_{MgO}.M_{MgO}+n_{Fe2O3}.M_{Fe2O3}=10g\)
⇒ 40a + 160b = 10g (1)
\(m_{ct}=\dfrac{5,6.350}{100}=19,6\left(g\right)\)
\(n_{H2SO4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)
⇒ 1a + 6b = 0,2(2)
Từ(1),(2) , ta có hệ phương trình :
40a + 160b = 10
1a + 6b = 0,2
⇒ \(\left\{{}\begin{matrix}a=0,05\\b=0,05\end{matrix}\right.\)
\(m_{MgO}=0,05.40=2\left(g\right)\)
\(m_{Fe2O3}=0,05.160=8\left(g\right)\)
0/0MgO = \(\dfrac{2.100}{10}=20\)0/0
0/0Fe2O3 = \(\dfrac{8.100}{10}=80\)0/0
b) Có : \(n_{MgO}=0,05\left(mol\right)\Rightarrow n_{MgSO4}=0,05\left(mol\right)\)
\(n_{Fe2O3}=0,05\left(mol\right)\Rightarrow n_{Fe2\left(SO4\right)3}=0,05\left(mol\right)\)
\(m_{MgSO4}=0,05.161=8,05\left(g\right)\)
\(m_{Fe2\left(SO4\right)3}=0,05.400=20\left(g\right)\)
Chúc bạn học tốt
Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
a. PTHH:
Zn + H2SO4 ---> ZnSO4 + H2 (1)
MgO + H2SO4 ---> MgSO4 + H2O (2)
b. Theo PT(1): \(n_{Zn}=n_{H_2}=0,5\left(mol\right)\)
=> \(m_{Zn}=0,5.65=32,5\left(g\right)\)
(Sai đề nhé.)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
0,5 0,5
b)\(m_{Zn}=0,5\cdot65=32,5\left(g\right)\)
\(m_{ZnO}=\) ko tính đc do lỗi đề
\(n_{MgO}=a\left(mol\right),n_{Fe_2O_3}=b\left(mol\right)\)
\(m=40a+160b=12\left(g\right)\left(1\right)\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(m_{Muối}=120a+400y=32\left(g\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
\(\%MgO=\dfrac{0.1\cdot40}{12}\cdot100\%=33.33\%\)
\(\%Fe_2O_3=66.67\%\)
\(m_{dd}=12+200=212\left(g\right)\)
\(C\%_{MgSO_4}=\dfrac{0.1\cdot120}{212}\cdot100\%=5.66\%\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.05\cdot400}{212}\cdot100\%=9.42\%\)
a) \(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Đặt \(n_{Fe_2O_3}=a\left(mol\right);n_{CuO}=b\left(mol\right)\)
Ta có:
\(\left\{{}\begin{matrix}160a+80b=24\\3a+b=0,4\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\%m_{Fe_2O_3}=\dfrac{160.0,1}{24}.100\%=66,67\%\\ \%m_{CuO}=100\%-66,67\%=33,33\%\)
b) \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(n_{HCl}=6.0,1+2.0,1=0,9\left(mol\right)\)
\(m_{HCl}=0,9.36,5=32,85\left(g\right)\)
\(m_{ddHCl}=\dfrac{32,85.100}{14,7}=223,47\left(g\right)\)
\(a)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(\dfrac{1}{6}\) \(0,5\) \(\dfrac{1}{6}\) \(0,25\)
\(\%m_{Al}=\dfrac{1:6.27}{25}\cdot100=18\%\\ \%m_{Al_2O_3}=100-18=82\%\\ b)n_{Al_2O_3}=\dfrac{25-1:6.27}{102}=\dfrac{41}{204}mol\\ Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(\dfrac{41}{204}\) \(\dfrac{41}{36}\) \(\dfrac{41}{102}\)
\(m_{ddHCl}=\dfrac{\left(0,5+41:36\right)36,5}{20}\cdot100=299,1g\\ V_{ddHCl}=\dfrac{299,1}{1,1}=271,9ml\)
\(m_{dd}=299,1+25-0,25.2=323,6g\)
\(m_{AlCl_3}=\left(\dfrac{1}{6}+\dfrac{41}{102}\right)\cdot133,5=75,9g\\ C_{\%AlCl_3}=\dfrac{75,9}{323,6}\cdot100=23,45\%\)
Dung` DL BTKL: moxit + mH2SO4 = mmuoi' + mH2O
voi' nH2O = nH2SO4 = 0.5*0.1 = 0.05
--> mmuoi' = 2.81 + 0.05*98 - 0.05*18 = 6.81g
Cach' #: (Fe2O3, MgO, ZnO) ----> (Fe2(SO4)3; MgSO4, ZnSO4)
--> nO = nSO4(2-) = nH2SO4 = 0.05
--> m(Fe, Mg, Zn) = 2.81 - mO = 2.81 - 0.05*16 = 2.01g
mmuoi' = mKL + mSO4(2-) = 2.01 + 0.05*96 = 6.81g
bảo toàn khối lượng
Ta có nH2SO4=0,05 mol =>n H+=0,1 mol
2H+ + O2- ---> H2O
==>2,81+98.0,05=m+0.05.18 ==> m=6,81(gam)
\(n_{MgO}=a\left(mol\right),n_{Fe_2O_3}=b\left(mol\right)\)
\(m_{hh}=40a+160b=24\left(g\right)\left(1\right)\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(n_{HCl}=2a+6b=1\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.2,b=0.1\)
\(m_{MgO}=0.2\cdot40=8\left(g\right)\)
\(m_{Fe_2O_3}=16\left(g\right)\)