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Theo đề gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=3x\left(mol\right)\\n_{CuO}=2x\left(mol\right)\end{matrix}\right.\)
Có: \(m_{hh}=m_{Fe_2O_3}+m_{CuO}=160.3x+80.2x=32\)
\(\Rightarrow x=0,05\\ \Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=0,05.3=0,15\left(mol\right)\\n_{CuO}=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,15 ---->0,45-->0,3
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,1 --->0,1-->0,1
a. \(m_{kim.loại}=m_{Fe}+m_{Cu}=0,3.56+0,1.64=23,2\left(g\right)\)
b. \(V_{H_2}=\left(0,45+0,1\right).22,4=12,32\left(l\right)\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{Fe}=n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Coi hh X gồm: Fe, Cu và O.
Ta có: nFe = 0,3 (mol)
Quá trình khử oxit: \(H_2+O_{\left(trongoxit\right)}\rightarrow H_2O\)
\(\Rightarrow n_{O\left(trongoxit\right)}=n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
⇒ mCu = 39,2 - mFe - mO (trong oxit) = 39,2 - 0,3.56 - 0,6.16 = 12,8 (g)
BTNT Cu, có: \(n_{CuO}=n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,2.80}{39,2}.100\%\approx40,82\%\\\%m_{Fe_xO_y}\approx100-40,82\approx59,18\%\end{matrix}\right.\)
b, Ta có: \(m_{Fe_xO_y}=39,2-m_{CuO}=23,2\left(g\right)\)
⇒ mO (trong FexOy) = 23,2 - mFe = 6,4 (g) \(\Rightarrow n_O=\dfrac{6,4}{16}=0,4\left(mol\right)\)
⇒ x:y = 0,3:0,4 = 3:4
Vậy: CTHH cần tìm là Fe3O4.
a, \(CuO+H_2\underrightarrow{^{t^o}}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{^{t^o}}2Fe+3H_2O\)
Gọi: \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\) ⇒ 80x + 160y = 40 (1)
Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=x+3y=\dfrac{13,44}{22,4}=0,6\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,3.80=24\left(g\right)\\m_{Fe_2O_3}=0,1.160=16\left(g\right)\end{matrix}\right.\)
b, \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{24}{40}.100\%=60\%\\\%m_{Fe_2O_3}=40\%\end{matrix}\right.\)
\(n_{Fe}=\dfrac{2,8}{56}=0,05mol\)
\(\Rightarrow m_{Cu}=6-2,8=3,2g\)\(\Rightarrow n_{Cu}=0,05mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,05 0,05
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
0,075 0,05
\(\Rightarrow\Sigma n_{H_2}=0,075+0,05=0,125mol\)
\(\Rightarrow V=0,125\cdot22,4=2,8l\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,3 0,3 ( mol )
\(m_{CuO}=0,3.80=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\)
\(\%m_{CuO}=\dfrac{24}{40}.100=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,3
\(\Rightarrow n_{CuO}=0,3\Rightarrow m_{CuO}=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\Rightarrow n_{Fe_2O_3}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\%m_{CuO}=\dfrac{24}{40}\cdot100\%=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(m_{CuO}=50.20\%=10\left(g\right)\)
\(n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
\(m_{Fe_2O_3}=50-10=40\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0,25\left(mol\right)\)
PTHH :
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,125 0,125 0,125
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,25 0,75 0,5
\(a,V_{H_2}=\left(0,75+0,125\right).22,4=19,6\left(l\right)\)
\(b,m_{Cu}=0,125.64=8\left(g\right)\)
\(m_{Fe}=0,5.56=28\left(g\right)\)