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\(n_{HCl}=\dfrac{10\%.109,5}{36,5}=0,3\left(mol\right);n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ Vì:\dfrac{0,3}{2}>\dfrac{0,1}{1}\Rightarrow HCldư\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.0,1=0,2\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\\ V_{H_2\left(đkc\right)}=24,79.0,1=2,479\left(l\right)\\ b,ddA:HCl\left(dư\right),MgCl_2\\ m_{ddA}=2,4+109,5-0,1.2=111,7\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{111,7}.100\%\approx3,268\%;C\%_{ddMgCl_2}=\dfrac{0,1.95}{111,7}.100\%\approx8,505\%\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
\(m_{CuCl_2}=\dfrac{270\cdot10\%}{100\%}=27g\Rightarrow n_{CuCl_2}=0,2mol\)
\(Fe+CuCl_2\rightarrow FeCl_2+Cu\)
0,15 0,2 0,15 0,15
\(a=m_{Cu}=0,15\cdot64=9,6g\)
\(m_{FeCl_2}=0,15\cdot127=19,05g\)
\(m_{ddFeCl_2}=8,4+270-0,15\cdot64=268,8g\)
\(C\%=\dfrac{19,05}{268,8}\cdot100\%=7,09\%\)
a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(m_{CuCl_2}=270.10\%=27\left(g\right)\Rightarrow n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\)
Ta có: \(\dfrac{0,15}{1}< \dfrac{0,2}{1}\) ⇒ Fe hết, CuCl2 dư
PTHH: Fe + CuCl2 ---> FeCl2 + Cu
Mol: 0,15 0,15 0,15 0,15
\(a=m_{Cu}=0,15.64=9,6\left(g\right)\)
b, \(m_{dd.sau.pứ}=8,4+270-9,6=268,8\left(g\right)\)
\(m_{CuCl_2dư}=\left(0,2-0,15\right).135=6,75\left(g\right)\)
\(\left\{{}\begin{matrix}C\%_{CuCl_2dư}=\dfrac{6,75.100\%}{268,8}=2,51\%\\C\%_{FeCl_2}=\dfrac{0,15.127.100\%}{268,8}=7,09\%\end{matrix}\right.\)
c, \(V_{ddCuCl_2}=\dfrac{270}{1,35}=200\left(ml\right)=0,2\left(l\right)\)
\(\left\{{}\begin{matrix}C_{M_{CuCl_2dư}}=\dfrac{0,2-0,15}{0,2}=0,25M\\C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75M\end{matrix}\right.\)
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
n H2 = n Fe = 11,2/56 = 0,2(mol)
V H2 = 0,2.22,4 = 4,48(lít)
b)
n HCl = 2n Fe = 0,2.2 = 0,4(mol)
=> CM HCl = 0,4/0,4 = 1M
c)
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
Ta thấy :
n CuO = 64/80 = 0,8 > n H2 = 0,2 nên CuO dư
Theo PTHH :
n CuO pư = n Cu = n H2 = 0,2(mol)
n Cu dư = 0,8 - 0,2 = 0,6(mol)
Vậy :
%m Cu = 0,2.64/(0,2.64 + 0,6.80) .100% = 21,05%
%m CuO = 100% -21,05% = 78,95%
1 ) CAO +H2O => CA(OH)2 (1)
2K + 2H2O => 2KOH + H2(2)
n (H2) =1,12/22,4 =0,05
theo ptpư 2 : n(K) = 2n (h2) =2.0.05=0,1(mol)
=> m (K) =39.0,1=3,9 (g)
% K= 3,9/9,5 .100% =41,05%
%ca =100%-41,05%=58,95%
xo + 2hcl =>xcl2 +h2o
10,4/X+16 15,9/x+71
=> giải ra tìm đc X bằng bao nhiêu thì ra
\(n_{Fe}=\dfrac{36,4}{56}=0,65\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,65->1,3----->0,65--->0,65
=> \(\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{1,3}{0,5}=2,6\left(l\right)\\b,V_{H_2}=0,65.22,4=14,56\left(l\right)\end{matrix}\right.\)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,65}{2,6}=0,25M\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ m_{HCl}=\dfrac{109,5\cdot10\%}{100\%}=10,95\left(g\right)\\ \Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ \text{Vì }\dfrac{n_{Mg}}{1}< \dfrac{n_{HCl}}{2}\text{ nên sau p/ứ }HCl\text{ dư}\\ \Rightarrow n_{H_2}=0,1\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,1\cdot22,4=2,24\left(l\right)\)
\(b,n_{MgCl_2}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{MgCl_2}}=0,1\cdot95=9,5\left(g\right)\\ m_{H_2}=0,1\cdot2=0,2\left(mol\right)\\ m_{dd_{MgCl_2}}=2,4+109,5-0,2=111,7\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{111,7}\cdot100\%\approx8,5\%\)
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