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a)
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,1--------->0,2------------->0,2------------>0,1
=> mCH3COOH = 0,2.60 = 12 (g)
\(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,2}{0,4}=0,5M\)
b) \(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{0,2.80}{100}=0,16\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4,to--> CH3COOC2H5 + H2O
0,16------------------------------------->0,16
=> \(m_{CH_3COOC_2H_5}=0,16.88=14,08\left(g\right)\)
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
a) 2NaOH + H2SO4 -- Na2SO4 + 2H2O
b) \(n_{NaOH}=\dfrac{100.20}{100.40}=0,5\left(mol\right)\)
PTHH: 2NaOH + H2SO4 -- Na2SO4 + 2H2O
______0,5----->0,25------>0,25
=> mH2SO4 = 0,25.98 = 24,5 (g)
=> \(m_{ddH_2SO_4}=\dfrac{24,5.100}{19,6}=125\left(g\right)\)
c) mNa2SO4 = 0,25.142 = 35,5 (g)
mdd sau pư = 100 + 125 = 225 (g)
=> \(C\%\left(Na_2SO_4\right)=\dfrac{35,5}{225}.100\%=15,778\%\)
PTHH: \(CH_3COOH+KHCO_3\rightarrow CH_3COOK+H_2O+CO_2\uparrow\)
a) Ta có: \(n_{CH_3COOH}=\dfrac{200\cdot24\%}{60}=0,8\left(mol\right)=n_{KHCO_3}\)
\(\Rightarrow m_{ddKHCO_3}=\dfrac{0,8\cdot100}{16,8\%}\approx476.2\left(g\right)\)
b) Theo PTHH: \(n_{CH_3COOK}=0,8\left(mol\right)=n_{CO_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CH_3COOK}=0,8\cdot98=78,4\left(g\right)\\m_{CO_2}=0,8\cdot44=35,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddCH_3COOH}+m_{ddKHCO_3}-m_{CO_2}=641\left(g\right)\)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{78,4}{641}\cdot100\%\approx12,23\%\)
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
nFe = 11.2/56 = 0.2 (mol)
Fe + H2SO4 => FeSO4 + H2
0.2____0.2_______0.2___0.2
mH2SO4 = 0.2*98 = 19.6 (g)
mdd H2SO4 = 19.6*100/10 = 196 (g)
m dd sau phản ứng = 11.2 + 196 - 0.4 = 206.8 (g)
mFeSO4 = 0.2*152 = 30.4 (g)
C% FeSO4 = 30.4/206.8 * 100% = 14.7%
Vdd H2SO4 = mdd H2SO4 / D = 196 / 1.14 = 171.9 (ml)
CM FeSO4 = 0.2 / 0.1719 = 1.16 M
\(a.n_{Mg\left(OH\right)_2}=\dfrac{17,4}{58}=0,3\left(mol\right)\\ Mg\left(OH\right)_2+2HCl\rightarrow MgCl_2+2H_2O\\ n_{HCl}=2n_{Mg\left(OH\right)_2}=0,6\left(mol\right)\\ CM_{HCl}=\dfrac{0,6}{0,2}=3M\\b. n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,3\left(mol\right)\\ m_{MgCl_2}=0,3.85=25,5\left(g\right)\\c.CM_{MgCl_2}=\dfrac{0,3}{0,2}=1,5M \)
Ta có: \(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
a. PTHH: Fe3O4 + 4H2SO4 ---> FeSO4 + Fe2(SO4)3 + 4H2O
Theo PT: \(n_{H_2SO_4}=4.n_{Fe_3O_4}=4.0,01=0,04\left(mol\right)\)
=> \(m_{H_2SO_4}=0,04.98=3,92\left(g\right)\)
Theo đề, ta có: \(C_{\%_{H_2SO_4}}=\dfrac{3,92}{m_{dd_{H_2SO_4}}}.100\%=20\%\)
=> \(m_{dd_{H_2SO_4}}=19,6\left(g\right)\)
b. Ta có: \(m_{dd_{SauPỨ}}=2,32+19,6=21,92\left(g\right)\)
Theo PT: \(n_{FeSO_4}=n_{Fe_2\left(SO_4\right)_3}=n_{Fe_3O_4}=0,01\left(mol\right)\)
=> \(m_{FeSO_4}=0,01.152=1,52\left(g\right)\)
\(m_{Fe_2\left(SO_4\right)_3}=0,01.400=4\left(g\right)\)
=> \(m_{SauPỨ}=1,52+4=5,52\left(g\right)\)
=> \(C_{\%_{SauPỨ}}=\dfrac{5,52}{21,92}.100\%=25,18\%\)