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Gọi \(n_{Zn}=a\left(mol\right)\rightarrow n_{Fe}=1,6a\left(mol\right)\)
Theo đề bài: \(65a+1,6a.56=7,73\rightarrow a=0,05\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}n_{Zn}=0,05\left(mol\right)\\n_{Fe}=0,05.1,6=0,08\left(mol\right)\end{matrix}\right.\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
0,05 0,1 0,05 0,05
Fe + 2HCl ---> FeCl2 + H2
0,08 0,16 0,08 0,08
\(\rightarrow V_{H_2}=\left(0,05+0,08\right).22,4=2,912\left(l\right)\)
Gọi mE = a (g)
=> \(\left\{{}\begin{matrix}m_{Fe_2O_3}=48\%.a=0,48a\left(g\right)\\m_{CuO}=32\%.a=0,32a\left(g\right)\end{matrix}\right.\rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{0,48a}{160}=0,003a\left(mol\right)\\n_{CuO}=\dfrac{0,32a}{80}=0,004a\left(mol\right)\end{matrix}\right.\)
PTHH:
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,003a->0,009a
CuO + H2 --to--> Cu + H2O
0,004a->0,004a
\(\rightarrow0,13=0,004a+0,009a\\ \Leftrightarrow a=100\left(g\right)\)
\(n_{H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\)
\(PTHH:Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\uparrow\)
0,025 0,025
\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)
\(\rightarrow m_{Ba}=0,025.137=3,425\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{3,425}{6,486}=52,81\%\\\%m_{BaO}=100\%-52,81\%=47,19\%\end{matrix}\right.\)
a, Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH:
Fe + 2HCl ---> FeCl2 + H2
a--->2a------------------>a
2Al + 6HCl ---> 2AlCl3 + 3H2
b---->3b-------------------->1,5b
=> \(\left\{{}\begin{matrix}56a+27b=16,6\\a+1,5b=0,5\end{matrix}\right.\Leftrightarrow a=b=0,2\left(mol\right)\)
=> \(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)
b) \(C\%_{HCl}=\dfrac{\left(0,2.2+0,2.3\right).36,5}{300}.100\%=12,167\%\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
gọi nFe : a , nAl: b (a,b>0) => 56a + 27b = 16,6 (g)
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a a
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b \(\dfrac{3b}{2}\)
=> \(a+\dfrac{3b}{2}=0,5\)
ta có hệ pt
\(\left\{{}\begin{matrix}56a+27b=16,6\\a+\dfrac{3b}{2}=0,5\end{matrix}\right.\)
=> a= 0,2 , b = 0,2
\(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=16,6-11,2=5,4\left(g\right)\end{matrix}\right.\)
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 0,4
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,6
=> \(m_{HCl}=\left(0,4+0,6\right).36,5=36,5\left(g\right)\)
=> \(C\%=\dfrac{36,5}{200}.100\%=18,25\%\)
2H2 + O2 --to--> 2H2O
Xét \(\dfrac{0,2}{2}>\dfrac{0,08}{1}\) => H2 dư, O2 hết
=> Hiệu suất phản ứng tính theo O2
\(n_{O_2\left(pư\right)}=\dfrac{0,08.75}{100}=0,06\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
____0,12<-0,06------>0,12
=> \(Y\left\{{}\begin{matrix}m_{O_2}=\left(0,08-0,06\right).32=0,64\left(g\right)\\m_{H_2}=\left(0,2-0,12\right).2=0,16\left(g\right)\\m_{H_2O}=0,12.18=2,16\left(g\right)\end{matrix}\right.\)
nH2=0,35(mol)
Đặt: nFe2O3= x(mol); nCuO=y(mol) (x,y>0)
PTHH: Fe2O3 + 3 H2 -to-> 2 Fe + 3 H2O
x___________3x_________2x(mol)
CuO + H2 -to-> Cu + H2O
y_____y____y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}160x+80y=20\\3x+y=0,35\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
=>mFe2O3= 160.0,1=16(g)
=>%mFe2O3=(16/20).100=80%
=>%mCuO=20%
nO2 = \(\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Pt: 2Cu + O2 \(\rightarrow\) 2CuO
x 0,5x x
3Fe + 2O2 \(\rightarrow\) Fe3O4
y 2/3y 1/3y
Theo bài ta có hpt:
\(\left\{{}\begin{matrix}64x+56y=23,2\\0,5x+\dfrac{2}{3}y=0,25\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}x=0,1\\y=0,3\end{matrix}\right.\)
mCuO = 0,1.80 = 8 g
mFe3O4 = 0,3.232 = 69,6g
=> %mCuO = \(\dfrac{8}{8+69,6}.100\%=10,3\%\)
%mFe3O4 = 100 - 10,3 = 89,7%
a) Zn+2HCl--->ZnCl2+H2
b) Ta có
n H2=4,48/22,4=0,2(mol)
Theo pthh
n Zn=n H2=0,2(mol)
m Zn=0,2.65=13(g)
%m Zn=13/21,2.100%=61,6%
%m ZnO=100-61,6=38,4%