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m dd sau pư = mFe + m dd HCl - mH2 thôi em nhé, Cu không phản ứng nên không cộng thêm vào.
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a) Theo Pt : \(n_{H2}=n_{Fe}=n_{FeCl2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
b) Theo Pt : \(n_{H2}=2n_{HCl}=2.0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}.100\%=100\left(g\right)\)
c) \(m_{ddspu}=10+100-0,1.2=109,8\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,1.127}{109,8}.100\%=11,57\%\)
Mong MN giúp mình nhanh với , mình đang rất gấp
Cảm ơn mọi người nhiều nhà 😘😘
a)
Gọi $n_{Fe} = a ; n_{FeO} = b; n_{FeCO_3} = c \Rightarrow 56a + 72b + 116c = 21,6(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$
$FeCO_3 + 2HCl \to FeCl_2 + CO_2 + H_2O$
\(\dfrac{2a+44c}{a+c}=15.2=30\left(2\right)\)
$n_{FeCl_2} = a + b + c= \dfrac{31,75}{127} = 0,25(3)$
Từ (1)(2)(3) suy ra a = 0,05 ; b = 0,1 ; c = 0,1
$n_{HCl} = 2a + 2b + 2c =0,5(mol)$
$m_{dd\ HCl} = \dfrac{0,5.36,5}{7,3\%} = 250(gam)$
$\%m_{Fe} = \dfrac{0,05.56}{21,6}.100\% = 12,96\%$
$\%m_{FeO} = \dfrac{0,1.72}{21,6}.100\% = 33,33\%$
$\%m_{FeCO_3} = 53,71\%$
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\) (2)
a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)
\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)
c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)
\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)
Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, Ta có: m dd tăng = mKL - mH2
⇒ mH2 = 16,6 - 15,6 = 1 (g) \(\Rightarrow n_{H_2}=\dfrac{1}{2}=0,5\left(mol\right)\)
Có: 27nAl + 56nFe = 16,6 (1)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=0,5\left(2\right)\)
Từ (1) và (2) ⇒ nAl = nFe = 0,2 (mol)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
c, Theo PT: \(n_{HCl}=2n_{H_2}=1\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{1.36,5}{40\%}=91,25\left(g\right)\)
⇒ m dd sau pư = 91,25 + 15,6 = 106,85 (g)
Theo PT: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{0,2.133,5}{106,85}.100\%\approx24,98\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{106,85}.100\%\approx23,77\%\end{matrix}\right.\)
\(2Al+6HCl->2AlCl_3+3H_2\\ Fe+2HCl->FeCl_2+H_2\\ n_{H_2}=\dfrac{16,6-15,6}{2}=0,5mol\\ n_{HCl}=1mol\\ n_{Al}=a;n_{Fe}=b\\ 27a+56b=16,6\\ 3a+2b=1\\ a=b=0,2\\ m_{Al}=0,2.27=5,4g\\ m_{Fe}=0,2.56=11,2g\\ m_{ddsau}=15,6+\dfrac{36,5}{0,4}=106,85g\\ C\%_{AlCl_3}=\dfrac{133,5.0,2}{106,85}.100\%=24,99\%\\ C\%_{FeCl_2}=\dfrac{127.0,2}{106,85}.100\%=23,77\%\)
a,\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,4 0,2
\(\Rightarrow\%m_{Zn}=\dfrac{0,2.65.100\%}{21,1}=61,61\%;\%m_{ZnO}=100-61,61=38,39\%\)
b,\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1\left(mol\right)\)
PTHH: ZnO + 2HCl → ZnCl2 + H2O
Mol: 0,1 0,2
\(m_{ddHCl}=\dfrac{\left(0,2+0,4\right).36,5.100\%}{7,3\%}=300\left(g\right)\)
c,
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,2 0,2
PTHH: ZnO + H2SO4 → ZnSO4 + H2O
Mol: 0,1 0,1
\(n_{H_2SO_4}=0,2+0,1=0,3\left(mol\right)\Rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
\(m_{ddH_2SO_4}=600.1,12=672\left(g\right)\)
Ta có: \(n_{HCl}=\dfrac{200.7,3\%}{100\%.36,5}=0,4\left(mol\right)\)
Khi cho hỗn hợp trên tác dụng với HCl thì chỉ có Fe phản ứng,nên ta có PT:
PT : Fe + 2HCl -> FeCl2 +H2
cứ:: 1...........2.............1............1 (mol)
vậy:0,2<----0,4------->0,2------>0,2(mol)
=> mFe=n.M=0,2.56=11,2(g)
=> mAg=mhh - mFe=20-11,2=8,8(g)
\(\%Fe=\dfrac{m_{Fe}.100\%}{m_{hh}}=\dfrac{11,2.100}{20}=56\left(\%\right)\)
\(\Rightarrow\%Ag=100\%-\%Fe=100\%-56\%=44\left(\%\right)\)
b) Dung dịch sau phản ứng chỉ có FeCl2
=> mFeCl2=n.M=0,2.127=25,4(g)
md d sauphanung=mhh +mHCl=20+200=220(g)
\(C\%_{ddsauphanung}=\dfrac{m_{FeCl_2}.100\%}{m_{ddsauphanung}}=\dfrac{25,4.100\%}{220}\approx11,55\left(\%\right)\)