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\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 0,1
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\\
V_{H_2}=0,1.22,4=2,24l\\
m_{\text{dd}}=6,5+200-\left(0,1.2\right)=206,3g\)
bài 2 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(m_{HCl}=0,4.36,5=14,6g\\
V_{H_2}=0,2.22,4=4,48l\\
m\text{dd}=4,8+200-0,4=204,4g\\
C\%=\dfrac{0,2.136}{204,4}.100\%=13,3\%\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\
pthh:Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
0,1 0,1 0,1
\(m_{MgSO_4}=120.0,1=12\left(g\right)\\
n_{CuO}=\dfrac{48}{80}=0,6\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(LTL:\dfrac{0,6}{1}>\dfrac{0,1}{1}\)
=> CuO dư
\(n_{CuO\left(P\text{Ư}\right)}=n_{H_2}=0,1\left(mol\right)\\
m_{CuO\left(d\right)}=\left(0,6-0,1\right).80=40\left(g\right)\)
nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2nMg=2,424=0,1(mol)pthh:Mg+H2SO4→MgSO4+H2
0,1 0,1 0,1
mMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2OmMgSO4=120.0,1=12(g)nCuO=4880=0,6(mol)pthh:CuO+H2to→Cu+H2O
a) PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
b) Ta có: \(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,2\cdot95=19\left(g\right)\\C\%_{HCl}=\dfrac{0,4\cdot36,5}{200}\cdot100\%=7,3\%\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{MgO}+m_{ddHCl}=208\left(g\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{19}{208}\cdot100\%\approx9,13\%\)
c) PTHH: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_2\downarrow\)
Ta có: \(\left\{{}\begin{matrix}n_{MgCl_2}=0,2\left(mol\right)\\n_{NaOH}=\dfrac{200\cdot4\%}{40}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,2}{2}\) \(\Rightarrow\) NaOH p/ứ hết, MgCl2 còn dư
\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,2\left(mol\right)\\n_{Mg\left(OH\right)_2}=0,1\left(mol\right)=n_{MgCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaCl}=0,2\cdot58,5=11,7\left(g\right)\\m_{MgCl_2\left(dư\right)}=9,5\left(g\right)\\m_{Mg\left(OH\right)_2}=0,1\cdot58=5,8\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{ddA}+m_{ddNaOH}-m_{Mg\left(OH\right)_2}=402,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{NaCl}=\dfrac{11,7}{402,2}\cdot100\%\approx2,91\%\\C\%_{MgCl_2\left(dư\right)}=\dfrac{9,5}{402,2}\cdot100\%\approx2,36\%\end{matrix}\right.\)
Theo gt ta có: $n_{MgO}=0,2(mol)$
a, $MgO+2HCl\rightarrow MgCl_2+H_2O$
b, Ta có: $n_{HCl}=0,4(mol)\Rightarrow x=7,3$
Bảo toàn khối lượng ta có: $m_{ddA}=208(g)$
$\Rightarrow \%C_{MgCl_2}=9,13\%$
c, Ta có: $n_{NaOH}=0,2(mol)$
$\Rightarrow n_{Mg(OH)_2}=0,1(mol)$
Bảo toàn khối lượng ta có: $m_{ddB}=208+200-0,1.58=402,2(g)$
$\Rightarrow \%C_{MgCl_2}=2,36\%$
Bài 1:
\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)
Bài 2:
\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)
Những bài dạng này em viết 1 PTHH duy nhất là PTHH trung hòa axit và bazo tạo muối và nước thôi sau đó so sánh số mol tìm chất dư chất hết là được.
\(HCl+NaOH\rightarrow NaCl+H_2O\\ n_{HCl}=n_{NaCl}=n_{NaOH}=1,5.0,1=0,15\left(mol\right)\\ a,m_{HCl}=0,15.36,5=5,475\left(g\right)\\ b,m_{NaCl}=58,5.0,15=8,775\left(g\right)\)
\(n_{HCl}=\dfrac{200\cdot7.3\%}{36.5}=0.4\left(mol\right)\)
\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
\(0.2..................0.4\)
\(m_{Ba\left(OH\right)_2}=0.2\cdot171=34.2\left(g\right)\)
Bạn ơi cho mình hỏi sao nHCl=mdd.C%/M vậy bạn? Cái này là làm gộp đúng không ạ? Nếu làm chậm thì bước đấy làm thế nào vậy ạ?
m MgSO4=4,8g=>nMgSO4=4,8\120=0,04 mol
mNaOh=24g =>nNaOh=24\40=0,6 mol
2NaOH+MgSO4->Mg(OH)2+Na2SO4
=> lập tỉ lệ :NaOH dư
=>mMg(OH)2=0,04.58=2,32g