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a)
\(n_{H_2}=\dfrac{0,336}{22,4}=0,015\left(mol\right)\)
PTHH: 2Na + 2H2O --> 2NaOH + H2
0,03<------------0,03<----0,015
=> \(\%m_{Na}=\dfrac{0,03.23}{1,31}.100\%=52,67\%\)
=> \(\%m_{Na_2O}=100\%-52,67\%=47,33\%\)
b)
\(n_{Na_2O}=\dfrac{1,31.47,33\%}{62}=0,01\left(mol\right)\)
PTHH: Na2O + H2O --> 2NaOH
0,01----------->0,02
=> nNaOH = 0,03 + 0,02 = 0,05 (mol)
mdd sau pư = 1,31 + 18,72 - 0,015.2 = 20 (g)
=> \(C\%_{dd.NaOH}=\dfrac{0,05.40}{20}.100\%=10\%\)
\(V_{dd.NaOH}=\dfrac{20}{1,2}=\dfrac{50}{3}\left(ml\right)=\dfrac{1}{60}\left(l\right)\)
\(C_{M\left(dd.NaOH\right)}=\dfrac{0,05}{\dfrac{1}{60}}=3M\)
\(n_{P_2O_5}=\dfrac{99,4}{142}=0,7\left(mol\right)\)
\(P_2O_5+3H_2O\rightarrow2H_3PO_4\)
0,7 2,1 1,4
a, \(m_{H_3PO_4}=1,4.98=137,2\left(g\right)\)
\(m_{ddH_3PO_4}=99,4+500=599,4\left(g\right)\)
Kl nước trong dd A :
\(m_{H_2O}=599,4-137,2=462,2\left(g\right)\)
\(b,C\%_{H_3PO_4}=\dfrac{137,2}{599,4}.100\%\approx22,89\%\)
\(c,C_M=\dfrac{n}{V}=\dfrac{1,4}{0,5}=2,8M\)
a)
\(C\%_{dd.KOH}=\dfrac{7,5}{7,5+42,5}.100\%=15\%\)
b) \(n_{HNO_3}=\dfrac{1,26}{63}=0,02\left(mol\right)\Rightarrow C_{M\left(dd.HNO_3\right)}=\dfrac{0,02}{0,016}=1,25M\)
Sửa đề: 9,2 gam Na
\(a,n_{Na_2O}=\dfrac{9,2}{23}=0,4\left(mol\right)\)
PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
0,4------------------>0,8
\(\rightarrow C_{M\left(NaOH\right)}=\dfrac{0,8}{0,5}=1,6M\)
\(b,n_{K_2O}=\dfrac{37,6}{94}=0,4\left(mol\right)\)
PTHH: \(K_2O+H_2O\rightarrow2KOH\)
0,4----------------->0,8
\(\rightarrow C\%_{KOH}=\dfrac{0,8.56}{362,4+37,6}.100\%=11,2\%\)
\(n_{Na}=x\left(mol\right)\)
\(n_{K_2O}=y\left(mol\right)\)
\(m_{hhA}=23x+94y=18,7\left(I\right)\)
PTHH:
2Na + 2H2O \(\rightarrow\) 2NaOH + H2\(\uparrow\) (1)
(mol) x...........................x..............0,5x
K2O + H2O \(\rightarrow\) 2KOH (2)
(mol) y..........................y
\(m_{hhX}=m_{H_2O}+m_{hhA}-m_{H_2\uparrow}\)
\(200=181,5+18,7-m_{H_2\uparrow}\)
\(m_{H_2\uparrow}=0,2\left(g\right)\)
\(n_{H_2}=\dfrac{0,2}{2}=0,1\left(mol\right)\)
\(\left(1\right)\rightarrow n_{H_2}=0,5.x=0,1\)
\(\rightarrow x=0,2\left(mol\right)\)
\(\left(I\right)\rightarrow y=0,15\left(mol\right)\)
200(g) ddX có 2 chất tan: NaOH, KOH
\(\left(1\right)\rightarrow n_{NaOH}=x=0,2\left(mol\right)\)
\(\left(2\right)\rightarrow n_{KOH}=2y=0,3\left(mol\right)\)
\(C\%_{NaOH/_{ddX}}=\dfrac{40.0,2}{200}.100=4\%\)
\(C\%_{KOH/_{ddX}}=\dfrac{56.0,3}{200}.100=8,4\%.\)
Bài 13: nNa= 0,2 mol ; nK= 0,1 mol
2Na + 2H2O → 2NaOH + H2↑
0,2 mol 0,2 mol 0,1 mol
2K + 2H2O → 2KOH + H2↑
0,1 mol 0,1 mol 0,05 mol
a) tổng số mol khí H2 là: nH2= 0,1 + 0,05 = 0,15 mol
→VH2= 0,15 x 22,4 = 3,36 (l)
b) mNaOH= 0,2 x 40= 8 (g) ; mKOH= 0,1 x 56= 5,6 (g)
mdung dịch= mNa + mK + mH2O - mH2 = 4,6 + 3,9 + 91,5 - 0,15x2 = 99,7 (g)
→C%NaOH= 8/99,7 x100%= 8,02%
→C%KOH= 5,6/99,7 x100%= 5,62%
2Na + 2H2O \(\rightarrow\) 2NaOH + H2 (1)
K2O + H2O \(\rightarrow\) 2KOH (2)
Có : mdd B = mhh A + mH2O - mH2 = 19,85 + 180,4 - mH2 = 200
\(\Rightarrow\) mH2 = 0,25(g)
\(\Rightarrow\) nH2 = 0,25/2 = 0,125(mol)
Theo PT(1) \(\Rightarrow\)nNa = nNaOH = 2.nH2 = 2. 0,125 = 0,25(mol)
\(\Rightarrow\left\{{}\begin{matrix}m_{Na}=0,25.23=5,75\left(g\right)\\m_{NaOH}=0,25.40=10\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\) mK2O = 19,85 - 5,75= 14,1(g)
\(\Rightarrow\) nK2O = 14,1/94 = 0,15(mol)
Theo PT(2) \(\Rightarrow\) nKOH = 2 . nK2O = 2. 0,15 = 0,3(mol)
\(\Rightarrow\) mKOH = 0,3 . 56 = 16,8(g)
* C%KOH / ddB = 16,8/200 . 100% = 8,4%
C%NaOH / dd B = 10/200 . 100% = 5%
* m(KOH+ NaOH) = 16 ,8 + 10 =\ 26,8(g)
\(\Rightarrow\)mH2O / dd B = 200 - 26,8 = 173,2 (g)
\(\Rightarrow\) VH2O / dd B = m : D = 173,2 : 1 = 173,2 (ml) =0,1732(l)
mà Vdd B = VH2O / ddB
=> Vdd B =\ 0,1732(l)
Do đó :
CM của NaOH / dd B = 0,25/0,1732=1,44(M)
CM của KOH / dd B = 0,3/0,1732 = 1,73 (M)
P/s: Bạn Tài Nguyễn nhờ em xóa hộ.