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\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a,PTHH:Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\\ n_{H_2}=n_{\left(CH_3COO\right)_2Mg}=n_{Mg}=0,2\left(mol\right);n_{CH_3COOH}=2.0,2=0,4\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Mg}=142.0,2=28,4\left(g\right)\\ d,m_{ddCH_3COOH}=\dfrac{0,4.60.100}{12}=200\left(g\right)\)
\(n_{HCl}=\dfrac{18.25}{36.5}=0.5\left(mol\right)\)
\(a.Mg+2HCl\rightarrow MgCl_2+H_2\)
\(b.\)
\(n_{Mg}=n_{H_2}=\dfrac{1}{2}\cdot n_{HCl}=\dfrac{1}{2}\cdot0.5=0.25\left(mol\right)\)
\(m_{Mg}=0.25\cdot24=6\left(g\right)\)
\(V_{H_2}=0.25\cdot22.4=5.6\left(l\right)\)
\(c.\)
\(V_{H_2\left(tt\right)}=5.6\cdot90\%=5.04\left(l\right)\)
\(Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2\)
b)
\(n_{H_2}= \dfrac{2,24}{22,4}= 0,1 mol\)
\(\)Theo PTHH:
\(n_{ZnSO_4}= n_{H_2}= 0,1 mol\)
\(m_{ZnSO_4}= 0,1 . 161=16,1g\)
c)
Theo PTHH:
\(n_{H_2SO_4}= n_{H_2}= 0,1 mol\)
\(\Rightarrow m_{H_2SO_4}= 0,1 . 98= 9,8g\)
\(\Rightarrow m_{dd H_2SO_4}= \dfrac{9,8 . 100}{20}=49g\)
a) PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)=n_{MgCl_2}\)
\(\Rightarrow m_{MgCl_2}=0,15\cdot95=14,25\left(g\right)\)
c) Theo PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(p.ứ\right)}=0,3\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{HCl\left(p.ứ\right)}=0,3\cdot36,5=10,95\left(g\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Mg}+m_{ddHCl}-m_{H_2}=53,3\left(g\right)\)
\(\Rightarrow m_{ddHCl}=50\left(g\right)\) \(\Rightarrow C\%_{HCl\left(p.ứ\right)}=\dfrac{10,95}{50}\cdot100\%=21,9\%\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,3.65=19,5\left(g\right)\)
c, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,1}=6\left(M\right)\)
a, \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
b,\(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Na_2CO_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
c, \(n_{CO_2}=n_{Na_2CO_3}=0,2\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{BaCO_3}=\dfrac{19,7}{197}=0,1\left(mol\right)\\ a,PTHH:BaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ba+CO_2+H_2O\\ n_{CO_2}=n_{\left(CH_3COO\right)_2Ba}=n_{BaCO_3}=0,1\left(mol\right)\\ b,V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Ba}=255.0,1=25,5\left(g\right)\\ d,C_2H_5OH+O_2\rightarrow\left(men.giấm\right)CH_3COOH+H_2O\\ n_{CH_3COOH}=0,1.2=0,2\left(mol\right);n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,2\left(mol\right)\\ n_{C_2H_5OH\left(TT\right)}=0,2.75\%=0,15\left(mol\right)\\ m_{C_2H_5OH\left(TT\right)}=0,15.46=6,9\left(g\right)\)
\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=2\cdot0,15=0,3\left(mol\right)\)
Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên sau p/ứ Zn dư
\(\Rightarrow n_{Zn}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\\ \Rightarrow m_{Zn}=0,15\cdot65=9,75\\ \Rightarrow m_{Zn\left(dư\right)}=13-9,75=3,25\left(g\right)\\ c,n_{H_2}=n_{Zn}=0,15\left(mol\right)\\ \Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ a,PTHH:Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ b,n_{H_2}=n_{\left(CH_3COO\right)_2Zn}=n_{Zn}=0,3\left(mol\right);n_{CH_3COOH}=2.0,3=0,6\left(mol\right)\\ b,V_{H_2\left(đkc\right)}=24,79.0,3=7,437\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Zn}=0,3.183=54,9\left(g\right)\\ d,C_2H_5OH+CH_3COOH\rightarrow CH_3COOC_2H_5+H_2O\\ n_{Este\left(LT\right)}=n_{CH_3COOH}=0,6\left(mol\right)\\ n_{este\left(TT\right)}=80\%.0,6=0,48\left(mol\right)\\ m=m_{este\left(TT\right)}=88.0,48=42,24\left(g\right)\)