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a, \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Theo PT: \(n_{Na}=2n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Na}=0,1.23=2,3\left(g\right)\)
\(\Rightarrow m_{Na_2O}=8,5-2,3=6,2\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
Theo PT: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=0,3\left(mol\right)\Rightarrow m_{NaOH}=0,3.40=12\left(g\right)\)
Số mol của 2,24 lít khí H2:
\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH:
\(2Na+2H_2O\rightarrow2NaOH+H_2\uparrow\left(1\right)\)
2 : 2 : 2 : 1
0,1-> 0,1 : 0,1 : 0,05(mol)
\(Na_2O+H_2O\rightarrow2NaOH\left(2\right)\)
Khối lượng của 0,2 mol Na:
\(m_{Na}=n.M=0,2.23=4,6\left(g\right)\)
Do hỗn hợp A gồm Na và H2O nên ta có:
\(m_{Hỗnhợp}=m_{Na}+m_{Na_2O}\\ \Rightarrow m_{Na_2O}=m_{Hỗnhợp}-m_{Na}\\ \Rightarrow m_{Na_2O}=12,4-4,6\\ \Rightarrow m_{Na_2O}=7,8\left(g\right)\)
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
a, \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Na}=2n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Na}=0,3.23=6,9\left(g\right)\)
\(\Rightarrow m_{Na_2O}=13,1-6,9=6,2\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
Theo PT: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=0,5\left(mol\right)\)
Ta có: m dd sau pư = 13,1 + 200 - 0,15.2 = 212,8 (g)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,5.40}{212,8}.100\%\approx9,4\%\)
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)
2Na + 2H2O ---> 2NaOH + H2 (1)
Na2O + H2O ---> 2NaOH (2)
a) nH2 = 0,3 (mol)
Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)
=> mNa = 0,6.23 = 13,8 (g)
=> mNa2O = 26,2 - 13,8 = 12,4 (g)
=> nNa2O = 0,2 (mol)
BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)
=> mNaOH = 1.40 = 40(g)
b) %mNa = 13,8.100%/26,2 = 52,67%
%mNa2O = 100% - 52,67% = 47,33%
2Na+2H2O->2NaOH+H2
0,5-----0,5-----------0,5----0,25
Na2O+H2O->2NaOH
0,1--------0,1-----------0,2
n H2=0,25 mol
=>m Na =0,5.23=11,5g
=>m Na2O=6,2g=>n Na2O=0,1 mol
=>m NaOH=0,7.40=28g
=>VH2O=0,6.22,4=13,44l
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