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\(n_{KHSO_3}=\dfrac{1.2}{120}=0.01\left(mol\right)\)
\(n_{K_2SO_3}=\dfrac{1.58}{158}=0.01\left(mol\right)\)
\(n_{KOH}=n_{KHSO_3}+2n_{K_2SO_3}=0.01+2\cdot0.01=0.03\left(mol\right)\)
\(C_{M_{KOH}}=\dfrac{0.03}{0.1}=0.3\left(M\right)\)
\(n_{SO_2}=n_{KHSO_3}+n_{K_2SO_3}=0.01+0.01=0.02\left(mol\right)\)
\(V_{SO_2}=0.02\cdot22.4=0.448\left(l\right)\)
a, \(MnO_2+4HCl\rightarrow MnCl_2+Cl_2+2H_2O\)
Ta có:
\(n_{MnO2}=\frac{4,35}{87}=0,05\left(mol\right)\)
\(n_{HCl}=0,3.1=0,3\left(mol\right)\)
\(n_{Cl2}=n_{MnO2}=0,05\left(mol\right)\)
\(\Rightarrow V_{Cl2}=0,05.22,4=1,12\left(l\right)\)
b,\(MnCl_2+2AgNO_3\rightarrow2AgCl+Mn\left(NO_3\right)_2\)
\(HCl+AgNO_3\rightarrow AgCl+HNO_3\)
\(n_{MnCl2}=n_{MnO2}=0,05\left(mol\right)\)
\(n_{HCl.trong.X}=0,3-0,2=0,1\left(mol\right)\)
\(n_{AgCl}=0,05.2+0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{AgCl}=0,2.143,5=28,7\left(g\right)\)
\(n_{Mg}=0,3\left(mol\right)\)
\(n_{HCl}=0,3\left(mol\right)\)
\(PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\)
...............0,15......0,3..........0,15.....0,15......
- Thấy sau phản ứng HCl phản ứng hết, Mg còn dư ( dư 0,15 mol )
\(\Rightarrow\left\{{}\begin{matrix}m_M=m_{MgCl_2}=14,25\left(g\right)\\V=V_{H_2}=3,36\left(l\right)\end{matrix}\right.\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Ta có: \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
\(n_{HCl}=0,2.1,5=0,3\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,3}{2}\), ta được Mg dư.
Theo PT: \(n_{MgCl_2}=n_{H_2}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,15.95=14,25\left(g\right)\\V_{H_2}=0,15.22,4=3,36\left(l\right)\end{matrix}\right.\)
Bạn tham khảo nhé!
Sửa đề: đktc → đkc
a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: 24nMg + 56nFe = 13,2 (1)
\(n_{H_2}=\dfrac{8,6765}{24,79}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}+n_{Fe}=0,35\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,2\left(mol\right)\\n_{Fe}=0,15\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,2.24}{13,2}.100\%\approx36,36\%\\\%m_{Fe}\approx63,64\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\n_{FeCl_2}=n_{Fe}=0,15\left(mol\right)\end{matrix}\right.\)
⇒ m muối khan = 0,2.95 + 0,15.127 = 38,05 (g)
\(n_K=\dfrac{5,85}{39}=0,15\left(mol\right)\)
PTHH: 2K + 2H2O --> 2KOH + H2
_____0,15------------->0,15-->0,075
=> VH2 = 0,075.22,4 =1,68(l)
mdd = 5,85 + 100 - 0,075.2 = 105,7(g)
=> \(C\%=\dfrac{0,15.56}{105,7}.100\%=7,95\%\)
\(n_{H_2SO_4}=0,2.2=0,4mol\\ Zn+H_2SO_4->ZnSO_4+H_2\\ m=65.0,4=26g\\ V=22,4.0,4=8,96L\)
nH2= 0,35(mol)
a) PTHH: Mg + 2 HCl -> MgCl2 + H2
x_________2x_______x______x(mol)
PTHH: Fe + 2 HCl -> FeCl2 + H2
y________2y________y_____y(mol)
Ta có hpt: \(\left\{{}\begin{matrix}24x+56y=13,2\\x+y=0,35\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,15\end{matrix}\right.\)
b) m=m(muối khan)= mMgCl2 + mFeCl2= 95.x+127y=95.0,2+127.0,15= 38,05(g)
a)
Gọi
\(n_{Fe} = a(mol) ; n_{Mg} = b(mol)\\ \Rightarrow 56a + 24b = 13,2(1)\)
\(Mg + 2HCl \to MgCl_2 + H_2\\ Fe + 2HCl \to FeCl_2 + H_2\)
Theo PTHH : \(n_{H_2} = a + b = 0,35(mol)\)(2)
Từ (1)(2) suy ra a = 0,15 ;b = 0,2
Vậy :
\(\%m_{Fe} = \dfrac{0,15.56}{13,2}.100\% = 63,64\%\\ \Rightarrow m_{Mg} = 100\% - 63,64\% = 36,36\%\)
b)
Ta có :\(n_{HCl} = 2n_{H_2} = 0,7(mol)\)
Bảo toàn khối lượng :
\(m_{muối} = m_{kim\ loại} + m_{HCl} - m_{H_2} = 13,2 + 0,7.36,5 - 0,35.2=38,05(gam)\)
