Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
a)
$Fe_2(SO_4)_3 + 6KOH \to 2Fe(OH)_3 + 3K_2SO_4$
b)
$n_{Fe_2(SO_4)_3} = 0,3.1 = 0,3(mol)$
$n_{KOH} = \dfrac{16,8}{56} =0,3(mol)$
Ta thấy :
$n_{KOH} : 3 < n_{Fe_2(SO_4)_3} : 1$ nên $Fe_2(SO_4)_3$ dư
$n_{Fe(OH)_3} = \dfrac{1}{3}n_{KOH} = 0,1(mol)$
$n_{Fe_2O_3} = \dfrac{1}{2}n_{Fe(OH)_3} = 0,05(mol)$
$m_{Fe_2O_3} = 0,05.160 = 8(gam)$
\(\begin{cases} m_{NaOH}=\dfrac{150.20\%}{100\%}=30(g)\\ m_{MgCl_2}=\dfrac{80.59,375\%}{100\%}=47,5(g) \end{cases} \Rightarrow \begin{cases} n_{NaOH}=\dfrac{30}{40}=0,75(mol)\\ n_{MgCl_2}=\dfrac{47,5}{95}=0,5(mol) \end{cases}\\ PTHH:2NaOH+MgCl_2\to Mg(OH)_2\downarrow+2NaCl\\ \text {Vì }\dfrac{n_{NaOH}}{2}<\dfrac{n_{MgCl_2}}{1} \text {nên }MgCl_2 \text { dư}\\ a,n_{Mg(OH)_2}=\dfrac{1}{2}n_{NaOH}=0,375(mol)\\ \Rightarrow m_{Mg(OH)_2}=0,375.58=21,75(g)\\ b,n_{NaCl}=m_{NaOH}=0,75(mol)\\ \Rightarrow m_{CT_{NaCl}}=0,75.58,5=43,875(g)\\ m_{dd_{NaCl}}=150+80-21,75=208,25(g)\\ \Rightarrow C\%_{NaCl}=\dfrac{43,875}{208,25}.100\%\approx 21,07\%\)
a) FeCl2+2NaOH---->Fe(OH)2+2NaCl(1)
4Fe(OH)2+O2---->2Fe2O3+4H2O(2)
Ta có
m FeCl2=317,50.10/100=31,75(g)
n FeCl2=31,75/127=0,25(mol)
n NaOH=0,1.1=0,1(mol)
--->FeCl2 dư..dd Y gồm FeCl2 và NaCl
NaCl+AgNO3---->AgCl+NaNO3(3)
FeCl2+ 2AgNO3---->2AgCl+Fe(NO3)2(4)
b) Theo pthh1
n FeCl2 =2n NaOH=0,2
---->n FeCl2 dư=0,05(mol)(*)
n Fe(OH)2=2n NaOH=0,2(mol)
Theo pthh2
n Fe2O3=1/2n Fe(OH)2=0,1(mol)
m=m Fe2O3=0,1.160=16(g)
Theo phh3
n AgCl=2nFeCl2 dư =0,1(mol)(từ * suy ra)
Theo pthh1
n NaCl=n NaOH=0,1(mol)
Tổng n AgCl=0,2(mol)
a=m AgCl=0,2.143,5=28,7(g)
\(n_{FeCl_3}=0.2\cdot0.4=0.08\left(mol\right)\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(0.08...........0.24..............0.08\)
\(2Fe\left(OH\right)_3\underrightarrow{^{^{t^0}}}Fe_2O_3+3H_2O\)
\(0.08...........0.04\)
\(m_{Fe_2O_3}=0.04\cdot160=6.4\left(g\right)\)
\(V_{dd_{NaOH}}=\dfrac{0.24}{0.5}=0.48\left(l\right)\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\) (1)
\(2Fe\left(OH\right)_3\rightarrow Fe_2O_3+3H_2O\) (2)
\(n_{FeCl_3}=0,2.0,4=0,08\left(mol\right)\)
Bảo toàn nguyên tố Fe : \(n_{FeCl_3}=2n_{Fe_2O_3}=0,08\left(mol\right)\)
=> \(n_{Fe_2O_3}=0,04\left(mol\right)\)
=> \(m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\)
Theo PT (1) : \(n_{NaOH}=3n_{FeCl_3}=0,08.3=0,24\left(mol\right)\)
=> \(V_{NaOH}=\dfrac{0,24}{0,5}=0,48\left(l\right)\)
a)
\(FeSO_4 + 2NaOH \to Fe(OH)_2 + Na_2SO_4\)
b)
\(n_{FeSO_4} = 0,4.0,5 = 0,2(mol) ; n_{NaOH} = 0,5.0,5 = 0,25(mol)\)
Ta thấy : \(2n_{FeSO_4} = 0,4 > n_{NaOH} = 0,25\) nên FeSO4 dư.
Theo PTHH :
\(n_{Fe(OH)_2} = 0,5n_{NaOH} = 0,125(mol)\\ \Rightarrow m_{Fe(OH)_2} = 0,125.90 = 11,25(gam)\)
c)
\(4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O\)
Theo PTHH :
\(n_{Fe_2O_3} = 0,5n_{Fe(OH)_2} = 0,0625(mol)\\ \Rightarrow m_{Fe_2O_3} = 0,0625.160 = 10(gam)\)
\(n_{MgCl_2}=0,15.1=0,15\left(mol\right);n_{NaOH}=\dfrac{80.20\%}{40}=0,4\left(mol\right)\)
PTHH: \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2\downarrow+2NaCl\)
Ban đầu: 0,15 0,4
Pư: 0,15------->0,3
Sau pư: 0 0,1 0,15
\(Mg\left(OH\right)_2\xrightarrow[]{t^o}MgO+H_2O\)
0,15--------->0,15
=> \(m=m_{MgO}=0,15.40=6\left(g\right)\)