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a: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
0,2 0,4 0,2 0,2
\(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
=>\(n_{H_2}=0.2\left(mol\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(lít\right)\)
b:
\(n_{MgCl_2}=n_{Mg}=0.2\left(mol\right)\)
\(m_{MgCl_2}=0.2\left(24+35.5\cdot2\right)=19\left(g\right)\)
c: \(C\%\left(HCl\right)=\dfrac{0.4\cdot36.5}{100}=14.6\%\)
\(a,PTHH:Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\uparrow\\ b,n_{Na_2CO_3}=\dfrac{15,9}{106}=0,15\left(mol\right)\\ \Rightarrow n_{HCl}=0,3\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,3\cdot36,5=10,95\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{10,95}{200}\cdot100\%=5,475\%\\ c,n_{CO_2}=0,15\left(mol\right)\\ \Rightarrow V_{CO_2\left(đkc\right)}=0,15\cdot24,79=3,7185\left(l\right)\\ d,m_{CO_2}=0,15\cdot44=6,6\left(g\right)\\ n_{NaCl}=0,3\left(mol\right);n_{H_2O}=0,15\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}m_{CT_{NaCl}}=0,3\cdot58,5=17,55\left(g\right)\\m_{H_2O}=0,15\cdot18=2,7\left(g\right)\end{matrix}\right.\\ m_{dd_{NaCl}}=15,9+200-2,7-6,6=206,6\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{17,55}{206,6}\cdot100\%\approx8,49\%\)
\(CaCO_3+2HCl->CaCl_2+CO_2+H_2O\\ a.V_{CO_2}=\dfrac{30}{100}\cdot22,4=6,72L\\ b.C\%_{HCl}=\dfrac{0,6\cdot36,5}{150}=14,6\%\\ c.C\%_{CaCl_2}=\dfrac{111\cdot0,3}{180-44\cdot0,3}=19,96\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ b,n_{HCl}=0,4(mol)\\ \Rightarrow C\%_{HCl}=\dfrac{0,4.36,5}{100}.100\%=14,6\%\\ c,n_{ZnCl_2}=n_{H_2}=0,2(mol)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2(g)\\ \Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{13+100-0,2.2}.100\%\approx 24,16\%\)
PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
Ta có: \(n_{Na_2SO_4}=n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}\cdot\dfrac{10}{40}=0,125\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddH_2SO_4}=\dfrac{0,125\cdot98}{10\%}=122,5\left(g\right)\\m_{Na_2SO_4}=0,125\cdot142=17,75\left(g\right)\end{matrix}\right.\)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{17,75}{10+122,5}\cdot100\%\approx13,4\%\)
Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
a. PTHH: Zn + H2SO4 ---> ZnSO4 + H2
b. Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
=> \(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
Ta có: \(C_{M_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=25\%\)
=> \(m_{dd_{H_2SO_4}}=39,2\left(g\right)\)
Ta có: \(m_{H_2}=0,1.2=0,2\left(g\right)\)
=> \(m_{dd_{ZnSO_4}}=6,5+39,2-0,2=45,5\left(g\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
=> \(C_{\%_{ZnSO_4}}=\dfrac{16,1}{45,5}.100\%=35,4\%\)
a. PTHH: Zn + H2SO4 ---> ZnSO4 + H2↑
b. Ta có: \(C_{M_{H_2SO_4}}=\dfrac{n_{H_2SO_4}}{200:1000}=1,5M\)
=> \(n_{H_2SO_4}=0,3\left(mol\right)\)
Ta lại có: \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
Ta thấy: \(\dfrac{0,3}{1}>\dfrac{0,25}{1}\)
Vậy H2SO4 dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)
=> \(V_{H_2}=0,25.22,4=5,6\left(lít\right)\)
c. Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,25\left(mol\right)\)
=> \(m_{ZnSO_4}=0,25.161=40,25\left(g\right)\)
d. Ta có: \(V_{dd_{ZnSO_4}}=0,2\left(lít\right)\)
=> \(C_{M_{ZnSO_4}}=\dfrac{0,25}{0,2}=1,25M\)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4 0,2 0,2
\(V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\)
\(m_{ZnCl_2}=0,2\cdot136=27,2\left(g\right)\)
\(m_{H_2}=0,2\cdot2=0,4\left(g\right)\)
\(m_{ddsau}=13+200-0,4=212,6\left(g\right)\)
\(\Rightarrow C\%=\dfrac{27,2}{212,6}\cdot100\%=12,8\%\)