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a.\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(n_{C_2H_2Br_4}=\dfrac{6,72}{22,4}=0,3mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,3 0,3 ( mol )
\(\%C_2H_2=\dfrac{0,3}{0,6}.100=50\%\)
\(\%CH_4=100\%-50\%=50\%\)
b.
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,3 0,6 ( mol )
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)
0,3 0,75 ( mol )
\(V_{O_2}=\left(0,6+0,75\right).22,4=1,35.22,4=30,24l\)
Theo gt ta có: $n_{hh}=0,08(mol);n_{Br_2}=0,08(mol)$
$C_2H_2+2Br_2\rightarrow C_2H_2Br_4$
Suy ra $n_{C_2H_2}=0,04(mol)=n_{CH_4}$
a, $\Rightarrow \%V_{C_2H_2}=\%V_{C_2H_4}=50\%$
b, $CH_4+2O_2\rightarrow CO_2+2H_2O$
$2C_2H_2+5O_2\rightarrow 4CO_2+2H_2O$
Ta có: $n_{O_2}=0,04.2+0,04.5=0,28(mol)\Rightarrow m_{O_2}=8,96(g)$
\(a)C_2H_2 +2Br_2 \to C_2H_2Br_2\\ n_{C_2H_2} = \dfrac{1}{2}n_{Br_2} = \dfrac{0,4.0,2}{2} = 0,04(mol)\\ \Rightarrow V_{C_2H_2} = 0,04.22,4 = 0,896(lít)\\ \%V_{C_2H_2} =\dfrac{0,896}{1,792}.100\% = 50\%\\ \Rightarrow \%V_{CH_4} = 100\% -50\% = 50\%\\ b)\\V_{CH_4} = V_{C_2H_2} = 0,896(lít)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_2 + \dfrac{5}{2}O_2 \xrightarrow{t^o} 2CO_2 + H_2O\\ \)
\(V_{O_2} = 2V_{CH_4} + \dfrac{5}{2}V_{C_2H_2} = 4,032(lít)\\ \Rightarrow m_{O_2} = \dfrac{4,032}{22,4}.32 = 5,76(gam)\)
a) Khi cho metan và axetilen qua dung dịch brom thì metan không phản ứng với brom nên thoát ra khỏi bình còn axetilen phản ứng với dung dịch brom.
=> 20,16 lít khí thoát là metan CH4
=> V axetilen = 40,32 - 20,16 = 20,16 lít
<=> %V CH4 = %V C2H2 = 50%
b)
nCH4 = nC2H2 = \(\dfrac{20,16}{22,4}\)= 0,9 lít
CH4 + 2O2 → CO2 + 2H2O
C2H2 + \(\dfrac{5}{2}\)O2 → 2CO2 + H2O
Theo tỉ lệ phản ứng cháy => nO2 cần để đốt cháy hết hỗn hợp khí = 2nCH4+\(\dfrac{5}{2}\)nC2H2= 4,05 mol.
=> V O2 cần dùng = 4,05.22,4 = 90,72 lít
CH4+2O2-to>CO2+2H2O
x-----------------------------2x
C2H2+\(\dfrac{5}{2}\)O2-to>2CO2+H2O
y-----------------------------------y
=>\(\left\{{}\begin{matrix}x+y=\dfrac{3,36}{22,4}\\2x+y=\dfrac{4,5}{18}\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,1\\y=0,05\end{matrix}\right.\)
=>%VCH4=\(\dfrac{0,1.22,4}{3,36}\).100=66,67%
=>%VC2H2=100-66,67%=33,33%
b)
C2H2+2Br2->C2H2Br4
0,05-----0,1 mol
=>m Br2=0,1.160=16g
\(CH_2=CH_2+Br_2\rightarrow CH_2Br-CH_2Br\)
\(n_{hh}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
\(V_{CH_4}=2.24\left(l\right)\)
\(n_{CH_4}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(\Rightarrow n_{C_2H_4}=0.15-0.1=0.05\left(mol\right)\)
\(\%CH_4=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%C_2H_4=33.33\%\)
\(CH_4+2O_2\underrightarrow{^{t^0}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^0}}2CO_2+2H_2O\)
\(n_{O_2}=0.1\cdot2+0.05\cdot3=0.35\left(mol\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.35\cdot22.4=39.2\left(l\right)\)
a, Ta có \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)
PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)
b, \(m_{CH_4}=0,05.16=0,8\left(g\right)\)
c, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,1}{1}=0,1\left(l\right)\)
\(m_{C_2H_4}=0,1.28=2,8\left(g\right)\)
Khí thoát ra là metan
\(\%V_{CH_4} = \dfrac{5,6}{13,44}.100\% =41,67\%\\ \%V_{C_2H_4} = 100\% - 41,67\% = 58,33\%\\ b) V_{C_2H_2} = 13,44 -5,6 = 7,84(lít)\\ n_{C_2H_2} = \dfrac{7,84}{22,4} = 0,35(mol)\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ n_{Br_2} = 2n_{C_2H_2} = 0,7(mol)\\ \Rightarrow C_{M_{Br_2}} = \dfrac{0,7}{0,25} = 2,8M\\ c)\)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ V_{O_2} = 2V_{CH_4} + 3V_{C_2H_4} = 5,6.2 + 7,84.3 = 34,72(lít)\)
thank bạn nhìu :3