Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{NO}=a;n_{N_2O}=b\\ BTe:\dfrac{3m}{27}=3a+b\\ a+b=\dfrac{0,896}{22,4}=0,04mol\\ 30a+44b=0,04.20,25.2=1,62\\ \Rightarrow a=0,01;b=0,03\\ m=0,54\)
a) Gọi $n_{CO_2} = a(mol) ; n_{SO_2} = b(mol)$
Ta có :
$a + b = \dfrac{8,96}{22,4} = 0,4(mol)$
$\dfrac{44a + 64b}{a + b} = 27.2$
Suy ra : a = b = 0,2$
$V_{CO_2} = V_{SO_2} = 0,2.22,4 = 4,48(lít)$
b) Theo PTHH : $n_{K_2SO_3} = n_{SO_2} = 0,2(mol)$
$\Rightarrow m_{K_2SO_3} = 0,2.158 = 31,6(gam)$
Gọi $n_{K_2CO_3} = x(mol) ; n_{Na_2CO_3} = y(mol)$
$\Rightarrow 138x + 106y + 31,6 = 56(1)$
$n_{CO_2} = x + y = 0,2(2)$
Từ (1)(2) suy ra : x = y = 0,1
$m_{K_2CO_3} = 0,1.138 = 13,8(gam) ; m_{Na_2CO_3} = 0,1.106 = 10,6(gam)$
Gọi số mol N2O, N2 là a, b (mol)
Có: \(\overline{M}_A=\dfrac{44a+28b}{a+b}=18,45.2=36,9\left(g/mol\right)\)
=> 7,1a = 8,9b (1)
PTHH: 8Fe + 30HNO3 --> 8Fe(NO3)3 + 3N2O + 15H2O
\(\dfrac{8}{3}a\)<-------------------------------a
10Fe + 36HNO3 --> 10Fe(NO3)3 + 3N2 + 18H2O
\(\dfrac{10}{3}b\)<------------------------------b
=> \(\dfrac{8}{3}a+\dfrac{10}{3}b=\dfrac{4,48}{22,4}=0,2\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{89}{2370}\left(mol\right)\\b=\dfrac{71}{2370}\left(mol\right)\end{matrix}\right.\) => \(V=\left(\dfrac{89}{2370}+\dfrac{71}{2370}\right).22,4=\dfrac{1792}{1185}\left(l\right)\)
Gọi: \(\left\{{}\begin{matrix}n_{H_2}=x\left(mol\right)\\n_{CO_2}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1\right)\)
Mà: dY/H2 = 6,25
\(\Rightarrow2x+44y=6,25.2.0,4\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)=n_{H_2}\\y=0,1\left(mol\right)=n_{CO_2}\end{matrix}\right.\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,2\left(mol\right)\)
\(n_{Na_2CO_3}=n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow m=m_{Al}+m_{Na_2CO_3}=0,2.27+0,1.106=16\left(g\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
Fe + 2HCl ---> FeCl2 + H2
2Al + 6HCl ---> 2AlCl3 + 3H2
Zn + 2HCl ---> ZnCl2 + H2
Theo các pthh trên: \(n_{HCl}=2n_{H_2}=2.0,2=0,4\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}m_{H_2}=0,2.2=0,4\left(g\right)\\m_{HCl}=0,4.36,5=14,6\left(g\right)\end{matrix}\right.\)
Áp dụng ĐLBTKL:
mKim loại + mHCl = mmuối khan + mH2
=> mMuối khan = 12 + 14,6 - 0,4 = 26,2 (g)
pthh fe + 2hcl -> fecl2 + h2
2al2 + 6hcl -> 2l2cl3 + 3h2
zn + 2hcl -> zncl2 + h2
\(n_{Mg}=a;n_{Fe}=0,5a;n_{Zn}=b\\ a\left(24+28\right)+65b=52a+65b=44,2\\ 1,5a+b=\dfrac{24,64}{22,4}1,1\\ a=0,6;b=0,2\\ \%m_{Mg}=\dfrac{24a}{44,2}=32,58\%\\ \%m_{Fe}=\dfrac{28a}{44,2}=38\%\\ \%m_{Zn}=29,42\%\\ m_{ddacid}=\dfrac{98\left(1,5a+b\right)}{0,08}=1347,5g\\ m_{ddsau}=1389,5g\\ C\%_{MgCl_2}=\dfrac{95a}{1389,5}=4,10\%\\ C\%_{FeCl_2}=\dfrac{127.0,5a}{1389,5}=2,74\%\\ C\%_{ZnCl_2}=\dfrac{136b}{1389,5}=1,96\%\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
=> \(n_{H_2SO_4}=0,2\left(mol\right)\)
mmuối = mkim loại + mSO4 = 12 + 0,2.96 = 31,2 (g)
Câu 2 :
\(n_{Cu}=a\left(mol\right),n_{Al}=b\left(mol\right)\)
\(m=64a+27b=11.8\left(g\right)\left(1\right)\)
\(BTKL:m_{O_2}=18.2-11.8=6.4\left(g\right)\)
\(n_{O_2}=\dfrac{6.4}{32}=0.2\left(mol\right)\)
\(2Cu+O_2\underrightarrow{^{^{t^0}}}2CuO\)
\(4Al+3O_2\underrightarrow{^{^{t^0}}}2Al_2O_3\)
\(n_{O_2}=0.5a+0.75b=0.2\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.2\)
\(\%Cu=\dfrac{0.1\cdot64}{11.8}\cdot100\%=54.23\%\)
Do HNO3 nóng dư nên Fe, Cu pứ hết --> Fe3+ & Cu2+
M(B) = 36 --> nNO : nNO2 = 5:3
Khi cho đ sau pứ tác dụng vs NH3 dư thì --> Fe(OH)3 ko tan, Cu(NH3)4(OH)2 tan
--> Chất rắn sau nung: Fe2O3: n = 0,05 --> nFe = 0,1 -->mFe = 5,6, mCu = 6,4g
Từ nFe, nCu, bảo toàn electron --> nNO, nNO2 --> V
c, Dung dịch kiềm> Vì trong dd D có NH4NHO3, nên cho kiềm vào sẽ sinh ra NH3.
\(n_{Zn}=\frac{13}{65}=0,2mol\)
\(M_{\text{khí}}=18,5.2=37g/mol\)
Đặt \(\hept{\begin{cases}x\left(mol\right)=n_{N_2}\\y\left(mol\right)=n_{N_2O}\end{cases}}\)
\(\rightarrow\frac{28x+44y}{x+y}=37\)
\(\rightarrow\frac{x}{y}=\frac{7}{9}\)
\(\rightarrow y=\frac{9x}{7}\)
Bảo toàn e:
\(\rightarrow2n_{Zn}=10n_{N_2}+8n_{N_2O}\)
\(\rightarrow0,4=10x+8.\frac{9x}{7}\)
\(\rightarrow x=\frac{7}{355}mol\)
\(\rightarrow y=\frac{9}{355}mol\)
\(V_{\text{khí}}=\frac{7}{355}.22,4+\frac{9}{355}.22,4=1l\)