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a.\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3 ( mol )
\(m_{AlCl_3}=0,2.133,5=26,7g\)
\(V_{H_2}=0,3.22,4=6,72l\)
b.\(n_{CuO}=\dfrac{56}{80}=0,7mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,7 < 0,3 ( mol )
0,3 0,3 0,3 ( mol )
\(m_X=m_{CuO\left(dư\right)}+m_{Cu}=\left[\left(0,7-0,3\right).80\right]+\left(0,3.64\right)=51,2g\)
nFe = 5,6 : 56 = 0,1(mol)
pthh : Fe + 2 HCl -->FeCl2 + H2
0,1---------------> 0,1-----> 0,1 (mol)
=> m = mFeCl2 = 0,1 .127 = 12,7 (g)
=> V = VH2 (dktc ) = 0,1 . 22,4 = 2,24 (l)
nCuO = 4 : 80 0,05 (mol)
pthh CuO + H2 -t--> Cu + H2O
LTL : 0,05/ 1 < 0,1 /1 => H2 du
nH2(pu) = nCuO = 0,05 (mol)
=> nH2 (du) = nH2 (ban dau ) - nH2 (pu )
= 0,1 - 0,05 = 0,05 (mol)
mH2(du) = 0,05 . 2 = 0,1 (g)
Fe + 2HCl ---> FeCl2 + H2
0,1 -> 0,2 -> 0,1 -> 0,1 (mol)
nFe = \(\dfrac{5,6}{56}\)= 0,1 (mol)
mFeCl2 = 0,1 . (56 + 35,5 . 2) = 12,7 (g)
VH2 = 0,1 . 22,4 = 2,24 (l)
b) H2 + CuO --> Cu + H2O
0,05 <- 0,05 -> 0,05 -> 0,05 (mol)
nCuO = \(\dfrac{4}{80}\)= 0,05(mol)
Tỉ lệ : \(\dfrac{0,1}{1}\) > \(\dfrac{0,05}{1}\). Vậy H2 dư, tính theo CuO.
nH2(dư) = nH2( ban đầu) - nH2(phản ứng) = 0,1 - 0,05 = 0,05 (mol)
Vui lòng kiểm tra lại, nếu có sai sót gì thì sorry.
\(\left\{{}\begin{matrix}m_{Mg}=\dfrac{40.9}{100}=3,6\left(g\right)\\m_{Al}=9-3,6=5,4\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\\n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\end{matrix}\right.\)
PTHH:
Mg + 2HCl ---> MgCl2 + H2
0,15 ------------------------> 0,15
2Al + 6HCl ---> 2AlCl3 + 3H2
0,2 ---------------------------> 0,3
\(\rightarrow V_{H_2}=\left(0,15+0,3\right).22,4=10,08\left(l\right)\)
\(n_{H_2O}=\dfrac{6,48}{18}=0,36\left(mol\right)\)
PTHH: FexOy + yH2 --to--> xFe + yH2O
Theo pthh: \(n_{O\left(oxit\right)}=n_{H_2\left(pư\right)}=n_{H_2O}=0,36\left(mol\right)\)
\(\rightarrow m_{oxit}=15,12+16.0,36=20,88\left(g\right)\)
\(n_{Fe}=\dfrac{15,12}{56}=0,27\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,27 : 0,36 = 3 : 4
=> CTHH: Fe3O4 (oxit sắt từ)
mMg = 40%x9 = 3,6(g) =>nMg=3,6:24 = 0,15 (mol)
=> mAl = 9-3,6 = 5,4(g) => nAl = 5,4:27 = 0,2 (mol)
pthh : 2Al+6HCl -> 2AlCl3+3H2
0,2 0,3
Mg+2HCl -> MgCl2 +H2
0,15 0,15
=> nH2 = 0,15 + 0,3 = 0,45 (mol)
=> VH2 = 0,45.22,4 = 10,08 (L)
mH2 = 0,45 . 2 = 0,9 (mol)
áp dụng BLBTKL ta có :
mH2 + moxit sắt = mFe + mH2O
=> moxit sắt = 20,7 (g)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 6HCl ---> 2AlCl3 + 3H2
0,1 0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
\(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: \(0,4>0,15\rightarrow\) CuO dư
Theo pthh: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,15.64}{0,15.64+\left(0,4-0,15\right).80}=32,43\%\\\%m_{CuO}=100\%-32,43\%=67,57\%\end{matrix}\right.\)
a. \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\)
b. \(n_{Al}=\frac{m}{M}=\frac{2,7}{27}=0,1mol\)
Theo phương trình `(1)` \(n_{H_2}=\frac{3}{2}.n_{Al}=\frac{3}{2}.0,1=0,15mol\)
\(\rightarrow V_{H_2\left(ĐKTC\right)}=n.22,4=0,15.22,4=3,36l\)
c. \(CuO+H_2\rightarrow^{t^o}Cu+H_2O\left(2\right)\)
\(n_{CuO}=\frac{m}{M}=\frac{32}{80}=0,4mol\)
Tỷ lệ \(\frac{0,4}{1}>\frac{0,15}{1}\)
`->CuO` dư
Theo phương trình `(2)` \(n_{Cu}=n_{H_2}=0,15mol\)
\(n_{CuO\left(pứ\right)}=n_{H_2}=0,15mol\)
\(\rightarrow n_{CuO\left(dư\right)}=0,4-0,15=0,25mol\)
\(m\left(g\right)\text{ chất rắn }\hept{\begin{cases}CuO_{dư}=0,25mol\\Cu=0,15mol\end{cases}}\)
\(\rightarrow m=0,15.64+0,25.80=29,6g\)
\(\%m_{CuO\left(dư\right)}=\frac{0,25.80.100}{29,6}\approx67,6\%\)
\(\%m_{Cu}=100\%-67,6\%=32,4\%\)
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,1_____0,2______0,1_____0,1 (mol)
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,2}{0,1}=1\left(M\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\)
⇒ m chất rắn = mCuO (dư) + mCu = 0,05.80 + 0,1.64 = 10,4 (g)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
______0,2_________________0,2 (mol)
b, VH2 = 0,2.22,4 = 4,48 (l)
c, Ta có: \(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
PT: \(FeO+H_2\underrightarrow{t^o}Fe+H_2O\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,2}{1}\), ta được H2 dư.
Theo PT: \(n_{Fe}=n_{FeO}=0,1\left(mol\right)\)
⇒ mFe = 0,1.56 = 5,6 (g)
Bạn tham khảo nhé!
a) Zn + 2HCl \(\rightarrow\)ZnCl2 + H2
b) mZn = \(\dfrac{13}{65}\)=0,2 (mol)
Zn + 2HCl \(\rightarrow\)ZnCl2 + H2
(mol) 0,2 ----------------------> 0,2
\(V_{H_2}\)= 0,2 . 22,4 = 4,48(lít)
c)\(n_{FeO}\)=\(\dfrac{7,2}{72}\)=0,1 (mol)
H2 + FeO \(\underrightarrow{t^o}\)Fe + H2O
(mol) 0,1----->0,1
mFe = 0,1 . 56 = 5,6(g)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2--------------------->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
c) \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,2<--0,2-------->0,2
=> nCuO(dư) = 0,3 - 0,2 = 0,1 (mol)
mCu = 0,2.64 = 12,8 (g)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,2 0,2
\(V=V_{H_2}=0,2.22,4=4,48\left(l\right)\)
\(pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,2 0,2
=> \(m_{Cu}=0,2.64=12,8\left(g\right)\)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
_____0,2__________________0,2 (mol)
b, \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
___________0,2__0,2 (mol)
\(\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
Bạn tham khảo nhé!