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Cho hỗn hợp qua dung dịch brom chỉ có etylen tác dụng.
\(n_{Br_2}=0,25\cdot1,5=0,375mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,375 0,375
\(V_{C_2H_4}=0,375\cdot22,4=8,4l\Rightarrow V_{CH_4}=11-8,4=2,6l\)
a.\(m_{Br_2}=m_{C_2H_4}=11,2g\)
\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(n_{C_2H_4}=\dfrac{11,2}{28}=0,4mol\)
\(\%V_{C_2H_4}=\dfrac{0,4}{0,6}.100=66,66\%\)
\(\%V_{CH_4}=100\%-66,66\%=33,34\%\)
\(m_{CH_4}=\left(0,6-0,4\right).16=3,2g\)
\(\%m_{C_2H_4}=\dfrac{11,2}{11,2+3,2}.100=77,77\%\)
\(\%m_{CH_4}=100\%-77,77\%=22,23\%\)
b.
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,2 0,4 ( mol )
\(C_2H_4+5O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,4 2 ( mol )
\(V_{kk}=\left(2+0,4\right).22,4.5=53,76.5=268,8l\)
a) \(n_{CH_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
=> \(\%V_{CH_4}=\dfrac{3,36}{11,2}.100\%=30\%\)
=> \(\%V_{C_2H_4}=100\%-30\%=70\%\)
b) \(n_{C_2H_4}=\dfrac{11,2.70\%}{22,4}=0,35\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,15-->0,3
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,35-->1,05
=> nO2 = 0,3 + 1,05 = 1,35 (mol)
=> VO2 = 1,35.22,4 = 30,24 (l)
a)
PTHH: C2H2+2Br2 --> C2H2Br4
b) \(n_{C_2H_2}=\dfrac{36}{26}=\dfrac{18}{13}\left(mol\right)\)
=> \(V_{C_2H_2}=\dfrac{18}{13}.22,4=\dfrac{2016}{65}\left(l\right)\)
\(n_{CH_4}=\dfrac{42-36}{16}=0,375\left(mol\right)\)
=> \(V_{CH_4}=0,375.22,4=8,4\left(l\right)\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_2}=\dfrac{\dfrac{2016}{65}}{\dfrac{2016}{65}+8,4}.100\%=78,69\%\\\%V_{CH_4}=\dfrac{8,4}{\dfrac{2016}{65}+8,4}.100\%=21,31\%\end{matrix}\right.\)
Ta có: \(V_{hhsaupư}=V_{CH_4}=\dfrac{44,8}{5,6}=8\left(l\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{8}{44,8}.100\%\approx17,86\%\\\%V_{C_2H_4}\approx82,14\%\end{matrix}\right.\)
\(m_{bìnhtăng}=m_{anken}=m_{etilen}=1,4g\)
\(\Rightarrow n_{C_2H_4}=\dfrac{1,4}{28}=0,05mol\)
\(n_{hh}=\dfrac{4,48}{22,4}=0,2mol\)
\(\Rightarrow n_{metan}=n_{hh}-n_{eilen}=0,2-0,05=0,15mol\)
\(\%V_{metan}=\dfrac{0,15}{0,2}\cdot100\%=75\%\)
\(\%V_{etilen}=100\%-75\%=25\%\)
a.\(m_{dd.Br_2\left(tăng\right)}=m_{C_2H_2}=2,6g\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(n_{C_2H_2}=\dfrac{2,6}{26}=0,1mol\)
\(\%V_{C_2H_2}=\dfrac{0,1}{0,25}.100=40\%\)
\(\%V_{CH_4}=100\%-40\%=60\%\)
b.\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,1 0,2 ( mol )
\(C_{M\left(dd.Br_2\right)}=\dfrac{0,2}{0,1}=2M\)
\(n_{hh}=\dfrac{11,2}{22,4}=0,5mol\)
\(m_{Br_2}=5,6g\Rightarrow n_{Br_2}=0,035mol\Rightarrow n_{C_2H_4}=0,035mol\)
\(\Rightarrow n_{C_2H_6}=0,5-0,035=0,465mol\)
a)\(\%V_{C_2H_6}=\dfrac{0,465}{0,5}\cdot100\%=93\%\)
\(\%V_{C_2H_4}=100\%-93\%=7\%\)
b)\(V_{Br_2}=\dfrac{0,035}{2}=0,0175l=17,5ml\)
a) mtăng = mC2H4
=> \(n_{C_2H_4}=\dfrac{5,6}{28}=0,2\left(mol\right)\)
=> \(n_{C_2H_6}=\dfrac{11,2}{22,4}-0,2=0,3\left(mol\right)\)
\(\left\{{}\begin{matrix}\%m_{C_2H_6}=\dfrac{0,3.30}{0,3.30+0,2.28}.100\%=61,644\%\\\%m_{C_2H_4}=\dfrac{0,2.28}{0,3.30+0,2.28}.100\%=38,356\%\end{matrix}\right.\)
b)
PTHH: C2H4 + Br2 --> C2H4Br2
0,2--->0,2
=> \(V_{dd.Br_2}=\dfrac{0,2}{2}=0,1\left(l\right)\)