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\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1 0,1 0,1
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(C_{M_{ddH_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
\(C_{M_{ddFeSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
____0,1______0,2_____0,1____0,1 (mol)
a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)
\(13,n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ .....0,3.....0,6......0,3......0,3\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,3\cdot22,4=6,72\left(l\right)\\ 14,n_{CaCO_3}=\dfrac{25}{40+12+16\cdot3}=0,25\left(mol\right)\\ PTHH:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\\ .....0,25.....0,5......0,25......0,25......0,25\left(mol\right)\\ V_{CO_2\left(đktc\right)}=0,25\cdot22,4=5,6\left(l\right)\)
a) $n_{Fe} = \dfrac{11,2}{56} = 0,2(mol) ; n_{HCl} = \dfrac{300.3,65\%}{36,5} = 0,3(mol)$
$Fe + 2HCl \to FeCl_2 + H_2$
Ta thấy :
$n_{Fe} :1 > n_{HCl} : 2$ nên Fe dư
$n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,15(mol)$
$V_{H_2} = 0,15.22,4 = 3,36(lít)$
b) $n_{FeCl_2} = \dfrac{1}{2}n_{HCl} = 0,15(mol)$
$FeCl_2 + 2NaOH \to Fe(OH)_2 + 2NaCl$
$4Fe(OH)_2 +O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O$
$n_{Fe_2O_3} = \dfrac{1}{2}n_{FeCl_2} = 0,075(mol)$
$m = 0,075.160 = 12(gam)$
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + H2SO4 → MgSO4 + H2
Mol: 0,2 0,2
\(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
⇒ Chọn C
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(0.2..................................0.2\)
1 (mol) khí chiếm thể tích 24.79 (l)
\(V_{H_2}=0.2\cdot24.79=4.958\left(l\right)\)