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a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow m_{Zn}=0,1\cdot65=6,5\left(g\right)\)
\(\Rightarrow\%m_{Zn}=\dfrac{6,5}{10}\cdot100\%=65\%\) \(\Rightarrow\%m_{Cu}=35\%\)
c) Theo PTHH: \(n_{HCl}=2n_{Zn}=0,2mol\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2\cdot36,5}{5\%}=146\left(g\right)\)
Tóm tắt
\(V_{H_2\left(đktc\right)}=8,96l\\ C_{\%H_2SO_4}=19,6\%\\ a)m_{Zn}=?\\ m_{ddH_2SO_4}=?\\ b)C_{\%ZnSO_4}=?\)
\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,4 0,4 0,4 0,4
\(m_{Zn}=0,4.65=26g\\ m_{ddH_2SO_4}=\dfrac{0,4.98}{19,6}\cdot100=200g\\ b)C_{\%ZnSO_4}=\dfrac{0,4.161}{26+200-0,4.2}\cdot100=28,6\%\)
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)
b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)
a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
____0,15<--0,3<--------------0,15
=> mFe = 0,15.56 = 8,4 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{21,2}.100\%=39,62\%\\\%Cu=\dfrac{21,2-8,4}{21,2}.100\%=60,38\%\end{matrix}\right.\)
b) mHCl = 0,3.36,5 = 10,95(g)
=> \(m_{ddHCl}=\dfrac{10,95.100}{3,65}.100\%=300\left(g\right)\)
a,\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: x x
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: y y
Ta có: \(\left\{{}\begin{matrix}65x+56y=30,7\\x+y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\%m_{Zn}=\dfrac{0,3.65.100\%}{30,7}=63,52\%;\%m_{Fe}=100\%-63,52\%=36,48\%\)
b,
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,6
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,2 0,4
nHCl = 0,6+0,4 = 1 (mol)
\(V_{ddHCl}=\dfrac{1}{2}=0,5\left(l\right)=500\left(ml\right)\)
nH2 = \(\frac{2,24}{22,4}\) = 0,1 (mol)
Fe + 2HCl \(\rightarrow\) FeCl2 + H2
0,1 <------------- 0,1 <--- 0,1 (mol)
a) mFe = 0,1 . 56 = 5,6 (g)
mCu = 4 (g)
b) mFeCl2 = 0,1 . 127= 12,7 (g)
c) Gọi nZn pư = x (mol)
Zn + FeCl2 \(\rightarrow\) ZnCl2 + Fe
x ----->x --------> x -------> x (mol)
Khối lượng CR giảm là khối lượng của sắt sinh ra.
=> 65x - 56x = 100 - 99,55
\(\Rightarrow\) x = 0,05
Sau pư thể tích ko đổi nên V = 0,1 (l)
CM(ZnCl22) = \(\frac{0,05}{0,1}\) = 0,5 (M)
nFeCl2 dư = 0,1 - 0,05 = 0,05 (mol)
CM(FeCl2) = \(\frac{0,05}{0,1}\) = 0,5 (M)
m dd sau pư = mFe + m dd HCl - mH2 thôi em nhé, Cu không phản ứng nên không cộng thêm vào.
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a) Theo Pt : \(n_{H2}=n_{Fe}=n_{FeCl2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
b) Theo Pt : \(n_{H2}=2n_{HCl}=2.0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}.100\%=100\left(g\right)\)
c) \(m_{ddspu}=10+100-0,1.2=109,8\left(g\right)\)
\(C\%_{FeCl2}=\dfrac{0,1.127}{109,8}.100\%=11,57\%\)
\(n_{HCl}=2.0,4=0,8(mol)\\ n_{Fe}=x(mol);n_{Al}=y(mol)\\ \Rightarrow 56x+27y=11(1)\\ Fe+2HCl\to FeCl_2+H_2\\ 2Al+6HCl\to 2AlCl_3+3H_2\\ \Rightarrow 2x+3y=0,8(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\)
\(a,\Sigma n_{H_2}=x+1,5y=0,4(mol)\\ \Rightarrow V_{H_2}=0,4.22,4=8,96(l)\\ b,m_{Fe}=0,1.56=5,6(g);m_{Al}=0,2.27=5,4(g)\\ c,m_{dd_{HCl}}=400.1,12=448(g)\\ n_{FeCl_2}=0,1(mol);n_{AlCl_3}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,1.127}{5,6+448-0,1.2}.100\%=2,8\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{5,4+448-0,3.2}.100\%=5,9\%\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,1 0,2 0,1 0,1
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(a,\%m_{Zn}=\dfrac{0,1.65}{10}.100\%=65\%\)
\(\%m_{Cu}=100\%-65\%=35\%\)
\(b,V_{HCl}=\dfrac{0,2}{2}=0,1\left(l\right)\)