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\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1---->0,1----------------->0,1
=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\end{matrix}\right.\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,25 > 0,1 => CuO dư
Theo pthh: nCu = nH2 = 0,1 (mol)
=> mCu = 0,1.64 = 6,4 (g)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,2
\(V_{H_2}=0,2.22,4=4,48l\\
C_M=\dfrac{0,2}{0,2}=1M\\
n_{CuO}=\dfrac{20}{80}=0,25\left(G\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:0,25>0,1\)
=>CuO dư
\(n_{Cu}=n_{H_2}=0,1\left(mol\right)\\
m_{Cu}=0,1.64=6,4g\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c, \(n_{HCl}=2n_{Zn}=0,2\left(mol\right)\Rightarrow m_{HCl}=0,2.36,5=7,3\left(g\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(1mol\) \(2mol\) \(1mol\)
\(0,1mol\) \(0,2mol\) \(0,1mol\)
\(n_{Zn}=\dfrac{m}{M}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=n.M=0,2.36,5=7,3\left(g\right)\)
\(V_{H_2}=n.22,4=0,1.22,4=2,24\left(l\right)\)
a)
$n_{HCl} = 0,2.2 = 0,4(mol)$
$n_{Zn} = \dfrac{9,75}{65}= 0,15(mol)$
$Zn + 2HCl \to ZnCl_2 + H_2$
Ta thấy :
n Zn / 1 = 0,15 < n HCl / 2 = 0,2 nên HCl dư
n H2 = n Zn = 0,15(mol)
V H2 = 0,15.22,4 = 3,36 lít
b)
n HCl pư = 2n Zn = 0,3(mol)
=> n HCl dư = 0,4 - 0,3 = 0,1(mol)
n ZnCl2 = n Zn = 0,15(mol)
CM HCl = 0,1/0,2 = 0,5M
CM ZnCl2 = 0,15/0,2 = 0,75M
c)
Dung dịch A làm quỳ tím hóa đỏ vì có HCl dư
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\\n_{HCl}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) \(\Rightarrow\) HCl còn dư, Kẽm p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{ZnCl_2}=n_{H_2}=0,15\left(mol\right)\\n_{HCl\left(dư\right)}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\C_{M_{ZnCl_2}}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
Vì HCl còn dư, nên dd sau p/ứ làm quỳ tím hóa đỏ
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
Ta có: \(n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=1\left(mol\right)\\n_{H_2}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{1\cdot36,5}{20\%}=182,5\left(g\right)\\V_{H_2}=0,5\cdot22,4=11,2\left(l\right)\end{matrix}\right.\)
Zn+2HCl->ZnCl2+H2
0,1-------------------0,1
=>VH2=0,1.22,4=2,24l