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a, \(CH_3COOH+Na\rightarrow CH_3COONa+\dfrac{1}{2}H_2\)
\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)
\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
b, Ta có: \(n_{NaOH}=0,2.0,5=0,1\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=n_{NaOH}=0,1\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}+\dfrac{1}{2}n_{C_2H_5OH}=0,3\)
\(\Rightarrow n_{C_2H_5OH}=0,5\left(mol\right)\)
\(\Rightarrow m=m_{CH_3COOH}+m_{C_2H_5OH}=0,1.60+0,5.46=29\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,1.60}{29}.100\%\approx20,69\%\\\%m_{C_2H_5OH}\approx79,31\%\end{matrix}\right.\)
a)
- Xét TN2:
nNaOH = 0,2.0,2 = 0,04 (mol)
PTHH: CH3COOH + NaOH --> CH3COONa + H2O
0,04<-----0,04
- Xét TN1:
\(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)
PTHH: 2CH3COOH + 2Na --> 2CH3COONa + H2
0,04------------------------------>0,02
2C2H5OH + 2Na --> 2C2H5ONa + H2
0,02<--------------------------0,01
=> m = 0,04.60 + 0,02.46 = 3,32 (g)
b) \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,04.60}{3,32}.100\%=72,29\%\\\%m_{C_2H_5OH}=\dfrac{0,02.46}{3,32}.100\%=27,71\%\end{matrix}\right.\)
Phần 2:
nH2 = 0,03 => nAl dư = 0,02
nNaOH = nAl dư + 2nAl2O3 => nAl2O3 = 0,08
Phần 1:
nAl dư = 0,02k; nAl2O3 = 0,08k; nFe = a
=> 0,02k.27 + 0,08k.102 + 56a = 9.39
nH2 = 0.02k.1,5 + a = 0,105
k = 0.5 và a = 0,09
Fe : O = a : (0,08k.3) => Fe3O4
m2 = 9,39 + 9,39/k =28,17g
\(a,n_{NaOH}=1,5.0,2=0,3\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH:
CH3COOH + NaOH ---> CH3COONa + H2O
0,3<-----------0,3
2CH3COOH + 2Na ---> 2CH3COONa + H2
0,3----------------------------------------------->0,15
2C2H5OH + 2Na ---> 2C2H5ONa + H2
0,2<---------------------------------------0,1
=> m = 0,2.46 +0,3.60 = 27,2 (g)
b) \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,3.60}{27,2}.100\%=66,18\%\\\%m_{C_2H_5OH}=100\%-66,18\%=33,82\%\end{matrix}\right.\)
\(a.Mg+2HCl\rightarrow MgCl_2+H_2\\ MgO+2HCl\rightarrow MgCl_2+H_2O\\ b.n_{H_2}=n_{Mg}=0,3\left(mol\right)\\ \Rightarrow\%m_{Mg}=\dfrac{0,3.24}{15,6}.100=48,15\%;\%m_{MgO}=53,85\%\)
2C2H5OH+Na->2C2H5ONa +H2
0,3------------------------------------0,15
2CH3COOH+Na->2CH3COONa+H2
0,1-------------------------------------->0,05
NaOH+CH3COOH->CH3COONa+H2O
0,1-------0,1 mol
n khí =4,48 \22,4=0,2 mol
n NaOH=0,5.0,2=0,1 mol
=>nH2 pt2=0,05
=>n H2 pt1=0,15
=>mC2H5OH=0,3.46=13,8g
=>m CH3COOH=0,1.60=6g