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2CH3COOH+CaCO3-to>(CH3COO)2Ca+H2O+CO2
0,4-----------------0,2----------------------------------------0,2
2CH3COOH+CaO->(CH3COO)2Ca+H2O
0,1----------------0,05
n CO2=0,2 mol
=>%m CaCO3=\(\dfrac{0,2.100}{22,8}100=87,72\%\)
=>%m CaO=12,28%
=>n CaO=0,05 mol
=>VCH3COOH=\(\dfrac{0,5}{2}=0,25l\)
a)
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: CaCO3 + 2CH3COOH --> (CH3COO)2Ca + CO2 + H2O
0,2<---------0,4<------------------------------0,2
=> \(m_{CaCO_3}=0,2.100=20\left(g\right)\)
=> \(\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{20}{22,8}=87,72\%\\\%m_{CaO}=100\%-87,72\%=12,28\%\end{matrix}\right.\)
b)
\(n_{CaO}=\dfrac{22,8-20}{56}=0,05\left(mol\right)\)
PTHH: CaO + 2CH3COOH --> (CH3COO)2Ca + H2O
0,05---->0,1
=> \(V_{dd.CH_3COOH}=\dfrac{0,1+0,4}{2}=0,25\left(l\right)\)
c) \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{a}{60}\left(mol\right)\\n_{C_2H_5OH}=\dfrac{1,5a}{46}\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{1,2a}{88}\left(mol\right)\end{matrix}\right.\)
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{\dfrac{a}{60}}{1}< \dfrac{\dfrac{1,5a}{46}}{1}\) => HIệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{1,2a}{88}\left(mol\right)\)
=> \(H=\dfrac{\dfrac{1,2a}{88}}{\dfrac{a}{60}}.100\%=81,82\%\)
\(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\\ a,n_{CH_3COOH}=2.n_{H_2}=2.0,3=0,6\left(mol\right)\\ m_{ddCH_3COOH}=\dfrac{0,6.60.100}{20}=180\left(g\right)\\ b,n_{\left(CH_3COO\right)_2Zn}=n_{Zn}=n_{H_2}=0,3\left(mol\right)\\ C\%_{dd\left(CH_3COO\right)_2Zn}=\dfrac{0,3.183}{180+0,3.65-0,3.2}.100\approx27,602\%\)
\(n_{CaCO_3}=\dfrac{20}{100}=0,2\left(mol\right)\\ a,PTHH:CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\\ b,n_{CO_2}=n_{\left(CH_3COO\right)_2Ca}=n_{CaCO_3}=0,2\left(mol\right)\\ b,V_{CO_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Ca}=0,2.158=31,6\left(g\right)\\ d,C_4H_{10}+\dfrac{5}{2}O_2\rightarrow2CH_3COOH+H_2O\\ n_{C_4H_{10}\left(LT\right)}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ n_{C_4H_{10}\left(TT\right)}=0,2:50\%=0,4\left(mol\right)\\ m_{C_4H_{10}\left(tt\right)}=58.0,4=23,2\left(g\right)\)
Câu 9 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
a) Pt : \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,4 0,2 0,2
→ \(V_{H2\left(dtkc\right)}=0,2.22,4=4,48\left(l\right)\)
b) \(V_{ddCH3COOH}=\dfrac{0,4}{2}=0,2\left(l\right)\)
c) \(m_{\left(CH3COO\right)2Mg}=0,2.101=20,2\left(g\right)\)
d) Pt : \(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,4 0,4
\(C_{MddKOH}=\dfrac{0,4}{0,2}=2\left(M\right)\)
Chúc bạn học tốt
\(a)n_{CH_3COOH} = 0,2.2 = 0,4(mol)\\ Mg + 2CH_3COOH \to (CH_3COO)_2Mg + H_2\\ n_{Mg} = \dfrac{1}{2}n_{CH_3COOH} = 0,2(mol)\\ m_{Mg} = 0,2.24 = 4,8(gam)\\ b)\\ CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\\ n_{CH_3COOH\ pư} = n_{este} = \dfrac{24,64}{88} = 0,28(mol)\\ H = \dfrac{0,28}{0,4}.100\% = 70\%\)
\(n_{BaCO_3}=\dfrac{19,7}{197}=0,1\left(mol\right)\\ a,PTHH:BaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ba+CO_2+H_2O\\ n_{CO_2}=n_{\left(CH_3COO\right)_2Ba}=n_{BaCO_3}=0,1\left(mol\right)\\ b,V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ c,m_{\left(CH_3COO\right)_2Ba}=255.0,1=25,5\left(g\right)\\ d,C_2H_5OH+O_2\rightarrow\left(men.giấm\right)CH_3COOH+H_2O\\ n_{CH_3COOH}=0,1.2=0,2\left(mol\right);n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,2\left(mol\right)\\ n_{C_2H_5OH\left(TT\right)}=0,2.75\%=0,15\left(mol\right)\\ m_{C_2H_5OH\left(TT\right)}=0,15.46=6,9\left(g\right)\)
\(a,n_{C_6H_{12}O_6}=\dfrac{450}{180}=2,5\left(mol\right)\)
PTHH: C6H12O6 --men rượu--> 2C2H5OH + 2CO2
2,5-------------------------->5
C2H5OH + O2 --men giấm--> CH3COOH + H2O
5------------------------------------>5
\(b,m_{C_2H_5OH}=5.46=230\left(g\right)\)
\(c,m_{CH_3COOH}=5.80\%.60=240\left(g\right)\)
a)\(n_{C_6H_{12}O_6}=\dfrac{450}{180}=2,5mol\)
\(C_6H_{12}O_6\underrightarrow{menrượu}2C_2H_5OH+2CO_2\)
2,5 5
b)\(m_{C_2H_5OH}=5\cdot46=230g\)
c)\(C_2H_5OH+O_2\underrightarrow{mengiấm}CH_3COOH+H_2O\)
5 5
Thực tế: \(n_{CH_3COOH}=5\cdot80\%=4mol\)
\(m_{CH_3COOH}=4\cdot60=240g\)
a, \(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
b, \(n_{H_2SO_4}=0,2.1,5=0,3\left(mol\right)\)
Theo PT: nNa2SO4 = nH2SO4 = 0,3 (mol) ⇒ mNa2SO4 = 0,3.142 = 42,6 (g)
nNaOH = 2nH2SO4 = 0,6 (mol) ⇒ mNaOH = 0,6.40 = 24 (g)
c, \(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,6}{0,4}=1,5\) → Pư tạo NaHCO3 và Na2CO3.
PT: \(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)
\(NaOH+CO_2\rightarrow NaHCO_3\)
a,\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: CaCO3 + 2HCl → CaCl2 + CO2 + H2O
Mol: 0,1 0,2 0,1
\(m_{CaCO_3}=0,1.100=10\left(g\right)\)
b,\(C\%_{ddHCl}=\dfrac{0,2.36,5.100\%}{150}=4,87\%\)
c,mdd sau pứ= 10+150-0,1.44 = 151,2 (g)
\(C\%_{ddCaCl_2}=\dfrac{0,1.111.100\%}{151,2}=7,34\%\)
CaCO3+2CH3COOH→Ca(CH3COO)2+H2O+CO2