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2CH3COOH + Mg => (CH3COO)2Mg + H2
nH2 = V/22.4 = 13.44/22.4 = 0.6 (mol)
Theo phương trình ==> nCH3COOH = 1.2 (mol)
==> mCH3COOH = n.M = 1.2 x 60 = 72 (g)
C% = 72 x 100/200 = 36%
Theo phương trình ==> n(CH3COO)2Mg = 0.6 (mol)
==> m(CH3COO)2Mg = n.M = 142x0.6 = 85.2 (g)
viết pthh biểu diễn chuỗi phản ứng sau:rượu etylic ------>axit axetic ------> etyl axetat ----->natri axetat
\(a,m_{Na_2CO_3}=\dfrac{500.20}{100}=100\left(g\right)\\ \rightarrow n_{Na_2CO_3}=\dfrac{100}{106}=\dfrac{50}{53}\left(mol\right)\)
PTHH: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2\uparrow+H_2O\)
\(\dfrac{50}{53}\)------->\(\dfrac{100}{53}\)--------------->\(\dfrac{100}{53}\)-------------->\(\dfrac{50}{53}\)
\(b,m_{axit}=\dfrac{100}{53}.60=\dfrac{6000}{53}\left(g\right)\\ c,m_{dd}=500+400-\dfrac{50}{53}.44=\dfrac{45500}{53}\left(g\right)\\ m_{CH_3COONa}=\dfrac{100}{53}.82=\dfrac{8200}{53}\left(g\right)\\ \rightarrow C\%_{CH_3COONa}=\dfrac{\dfrac{8200}{23}}{\dfrac{45500}{23}}.100\%=18,02\%\)
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{\left(CH_3COO\right)_2Fe}=0,2.174=34,8\left(g\right)\)
Ta có: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\)
m dd sau pư = 11,2 + 200 - 0,2.2 = 210,8 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{34,8}{210,8}.100\%\approx16,51\%\)
Cho kim loại Magie tác dụng vừa đủ với 200 gam dung dịch axit axetic 15%.
a. Tính khối lượng Magie phản ứng ?
b. Tính nồng độ phần trăm dung dịch muối thu được sau phản ứng ?
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mCH3COOH= 200.15%= 30(g) => nCH3COOH= 30/60=0,5(mol)
a) Mg + 2 CH3COOH -> (CH3COO)2Mg + H2
0,25___0,5_______0,25_____________0,25(mol)
mMg= 0,25.24= 6(g)
b) m(CH3COO)2Mg=142.0,25=35,5(g)
mdd(CH3COO)2Mg= 6+200-0,25.2=205,5(g)
=> \(C\%dd\left(CH3COO\right)2Mg=\frac{35,5}{205,5}.100\approx17,275\%\)
a, \(n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\)
PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
Theo PT: \(n_{Mg}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m=m_{Mg}=0,1.24=2,4\left(g\right)\)
\(V=V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH}=n_{CH_3COOH}=0,2\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)
\(\Rightarrow V_{ddC_2H_5OH}=\dfrac{9,2}{0,8}=11,5\left(ml\right)\)
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,3.65=19,5\left(g\right)\)
c, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,1}=6\left(M\right)\)
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