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SO3 + H2O --------> H2SO4
m/80...m/80...............m/80 (mol)
mct của dd mới = 500.1,2.0,245 + 49m/40 =147 + 49m/40 (g)
mdd mới = 1,2.500 + m = 600 + m (g)
=> (147 + 49m/40 )/(600 + m) = 0,49
=> m= 200(g)
\(SO_3+H_2O->H_2SO_4\\ m_{SO_3}=a;m_{ddH_2SO_4\left(9,8\%\right)}=b\\ C\%_{sau}=\dfrac{54,88}{100}=\dfrac{\dfrac{a}{80}.96+0,098b}{500}\left(I\right)\\ a+b=500\left(II\right)\\ a=204,5;b=295,5\)
Vậy cần thêm 204,5 g khí sulfur trioxide.
\(M+H_2SO_4\rightarrow MSO_4+H_2\uparrow\\ n_{ASO_4}=n_A=n_{H_2}=n_{H_2SO_4}=a\left(mol\right)\\ 1.m_{ddH_2SO_4}=\dfrac{98a.100}{20}=490a\left(g\right)\\ 2.m_{ddsau}=M_M.a+490a-2a=\left(M_M+488\right).a\left(g\right)\\ C\%_{ddsau}=22,64\%\\ \Leftrightarrow\dfrac{\left(M_M+96\right)a}{\left(M_M+488\right)a}.100\%=22,64\%\\ \Leftrightarrow M_M=18,72\left(loại\right)\)
Khả năng cao sai đề nhưng làm tốt a,b nha
\(n_{NaOH}=\dfrac{0,8}{40}=0,02mol\\ 2NaOH+H_2SO_4->Na_2SO_4+2H_2O\\ m_{Na_2SO_4}=142\cdot0,01=1,42g\\ n_{H_2SO_4pư}=0,01mol\\ m_{H_2SO_4}=98\cdot1,15\cdot0,01=1,127g\)
\(a.n_{NaOH}=\dfrac{0,8}{40}=0,02\left(mol\right)\\2 NaOH+H_2SO_4\xrightarrow[]{}Na_2SO_4+2H_2O\\ \Rightarrow n_{Na_2SO_4}=\dfrac{1}{2}0,02=0,01\left(mol\right)\\ m_{Na_2SO_4}=0,01.142=1,42\left(g\right)\\ b.n_{H_2SO_4\left(pư\right)}=\dfrac{1}{2}0,02=0,01\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,01.15\%=0,0015\left(mol\right)\\ m_{H_2SO_4\left(dùng\right)}=\left(0,01+0,0015\right).98=1,127\left(g\right)\)
BaO+H2O -> Ba(OH)2
0,02 0,02
a) CM = n/V = 0,02/0,02 = 1M
b) Ba(OH)2 + H2SO4 -> BaSO4 +2H2O
0,02 0,02
=> m = 0,392 g
D = m/V = 1,14
=> 0,392/V = 1,14 => V = 0,34l
a.Mg + H2SO4 -> MgSO4 + H2
b.\(nH2=\dfrac{4.704}{22.4}=0.21mol\) = nMg
mMg = 0.21\(\times24=5.04g\)
\(\%mMg=\dfrac{5.04\times100}{25}=20.16\%\)
\(\%mAg=100-20.16=79.84\%\)
c.MgSO4 + 2KOH -> K2SO4 + Mg(OH)2
0.21 0.42
H2SO4 + 2KOH -> K2SO4 + H2O
0.04 0.08
\(nH2SO4=\dfrac{9.8\times250}{100\times98}=0.25mol\)
Mà nH2SO4 phản ứng = nH2 = 0.21 mol
\(\Rightarrow nH2SO4dư=0.25-0.21=0.04mol\)
=> nKOH = 0.42 + 0.08 = 0.5mol
\(\Rightarrow CM_{KOH}=\dfrac{0.5}{0.625}=0.8M\)
\(n_{H_2SO_4}=\dfrac{400.24,5\%}{98}=1\left(mol\right)\)
2l dung dịch A có 1 mol H2SO4
=> 400ml dung dịch A có \(\dfrac{400.1}{2000}=0,2\)mol H2SO4
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,2..............0,4
Ta có : \(n_{NaOH}=2n_{H_2SO_4}\)
=> \(V_{NaOH}=\dfrac{0,4}{3,2}=0,125\left(l\right)=125ml\)
Câu 3: Gọi lượng SO3 cần lấy là x g ( 0 < x < 450)
\(m_{ddH_2SO_449\%}=450-x\left(g\right)\)
\(\Rightarrow m_{H_2SO_449\%}=220,5-0,49x\left(g\right)\)
\(m_{H_2SO_483,3\%}=\dfrac{83,3.450}{100}=374,85\left(g\right)\)
PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)
______80g___________98g
______x(g)___________y(g)
\(\Rightarrow m_{H_2SO_4tt}=1,225x\left(g\right)\)
Vì \(m_{H_2SO_4bđ}+m_{H_2SO_4tt}=m_{H_2SO_483,3\%}\)
\(\Rightarrow220,5-0,49x+1,225x=374,85\)
\(\Rightarrow x=210\) (nhận)
\(\Rightarrow m_{ddH_2SO_449\%}=450-210=240\left(g\right)\)
Câu 2: Gọi \(m_{ddH_2SO_460\%}=x\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_480\%}=x+16\left(g\right)\)
\(\Rightarrow m_{H_2SO_480\%}=\dfrac{80\left(x+16\right)}{100}=0,8x+12,8\left(g\right)\)
\(m_{H_2SO_460\%}=\dfrac{60x}{100}=0,6x\left(g\right)\)
PTHH: SO3 + H2O -> H2SO4
______80g__________98g
______16g__________y(g)
\(\Rightarrow y=m_{H_2SO_4tt}=19,6\left(g\right)\)
Ta có pt: 0,6x + 19,6 = 0,8x + 12,8
\(\Leftrightarrow x=34\)