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b, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
\(n_P=\dfrac{6,2}{31}=0,2mol\\n_{O_2}=\dfrac{0,2.5}{4}=0,25mol \)
\(S+O_2\underrightarrow{t^o}SO_2\)
\(n_S=\dfrac{3,2}{32}=0,1mol\\ n_{O_2}=0,1mol\)
\(C+O_2\underrightarrow{t^o}CO_2\)
\(n_C=\dfrac{2,4}{12}=0,2mol\\ n_{O_2}=0,2mol\\ n_{O_2}\left(tổng\right)=\)
\(0,25+0,1+0,2=0,55mol\\ m_{O_2}\left(trong.hh.B\right)=0,55.32=17,6g\)
a, \(m_{Fe}=0,25.56=14g\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(\Rightarrow n_{O_2}=\dfrac{0,25.2}{3}=0,16mol\\ m_{O_2}=0,16.32=5,12g\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(n_{O_2}=\dfrac{0,25.3}{4}=0,1875mol\\ m_{O_2}=0,1875.32=6g\)
\(2Zn+O_2\underrightarrow{t^o}2ZnO\)
\(n_{O_2}=\dfrac{0,5.1}{2}=0,25mol\\ m_{O_2}=0,25.32=8g\)
\(\Rightarrow m_{O_2}\left(trong.hỗn.hợp.A\right)=\) \(5,12+6+8=19,12g\)
\(n_{hhkhí}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
Gọi \(n_{SO_2}=a\left(mol\right)\left(0< a< 0,75\right)\)
\(\rightarrow n_{O_2\left(dư\right)}=0,75-b\left(mol\right)\)
Ta có: \(\dfrac{64a+32\left(0,75-a\right)}{0,75}=\dfrac{33,6}{1}=33,6\left(\dfrac{g}{mol}\right)\)
\(\rightarrow a=0,0375\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{SO_2}=\dfrac{0,0375}{0,75}=5\%\\\%V_{O_2\left(dư\right)}=100\%-5\%=95\%\end{matrix}\right.\)
\(a,Đặt:n_{CH_4}=a\left(mol\right);n_{C_4H_{10}}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ 2C_4H_{10}+13O_2\rightarrow\left(t^o\right)8CO_2+10H_2O\\ \Rightarrow\left\{{}\begin{matrix}16a+58b=7,4\\22,4a+22,4.4b=22\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6\left(g\right)\\m_{C_4H_{10}}=0,1.58=5,8\left(g\right)\end{matrix}\right.\\ b,n_{O_2}=2a+\dfrac{13}{2}b=2.0,1+6,5.0,1=0,85\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,85.22,4=19,04\left(l\right)\)
áp dụng định luật bảo toàn khối lượng ta có :
Σmhh + mo2 =ms02 + mco2 <=> 4,4 + 6,4 = mso2 + mco2 <=> mso2 + mco2 = 10,8
Gọi số mol C, S là a, b
=> 12a + 32b = 7,68
PTHH: C + O2 --to--> CO2
_____a--------------->a
S + O2 --to--> SO2
b--------------->b
=> a + b = \(\dfrac{9,856}{22,4}=0,44\)
=> a = 0,32; b = 0,12
=> \(\left\{{}\begin{matrix}\%C=\dfrac{0,32.12}{7,68}.100\%=50\%\\\%S=\dfrac{0,12.32}{7,68}.100\%=50\%\end{matrix}\right.\)
\(a,m_C=10.36\%=3,6\left(kg\right)=3600\left(g\right)\\ n_C=\dfrac{3600}{12}=300\left(mol\right)\\ m_S=10-3,6=6,4\left(kg\right)=6400\left(g\right)\\ n_S=\dfrac{6400}{32}=200\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ S+O_2\rightarrow\left(t^o\right)SO_2\\ n_{O_2\left(tổng\right)}=n_C+n_S=300+200=500\left(mol\right)\\ V_{O_2\left(tổng\right)\left(đktc\right)}=500.22,4=11200\left(l\right)\\ V_{kk}=\dfrac{100}{20}V_{O_2\left(tổng\right)\left(đktc\right)}=5.11200=56000\left(l\right)\\ b,V_{hh\left(CO_2,SO_2\left(đktc\right)\right)}=22,4.\left(n_C+n_S\right)=22,4.\left(300+200\right)=11200\left(l\right)\)
A C4H10+13\2O2--->4CO2+5H2O
nC4H10=10000\58=172 mol
theo pt nO2=1121 mol
mO2=1121.32=35872 g
B C+O2-->CO2
S+O2-->SO2
mO2=32.(1+2)=96 g