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a) \(n_{Al}=\dfrac{8,64}{27}=0,32\left(mol\right)\)
\(n_{HCl}=\dfrac{365.10\%}{36,5}=1\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
Xét tỉ lệ \(\dfrac{0,32}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,32-->0,96---->0,32--->0,48
=> \(V_{H_2}=0,48.22,4=10,752\left(l\right)\)
b) Trong Y chứa AlCl3 và HCl dư
\(m_{AlCl_3}=0,32.133,5=42,72\left(g\right)\)
c) mdd sau pư = 8,64 + 365 - 0,48.2 = 372,68 (g)
\(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{42,72}{372,68}.100\%=11,463\%\\C\%\left(HCldư\right)=\dfrac{\left(1-0,96\right).36,5}{372,68}.100\%=0,392\%\end{matrix}\right.\)
a) Gọi kim loại cần tìm là R
\(n_R=\dfrac{7,56}{M_R}\left(mol\right)\)
PTHH: 2R + 2nHCl --> 2RCln + nH2
\(\dfrac{7,56}{M_R}\)------------>\(\dfrac{7,56}{M_R}\)
=> \(M_{RCl_n}=M_R+35,5n=\dfrac{37,38}{\dfrac{7,56}{M_R}}\)
=> \(M_R=9n\left(g/mol\right)\)
Xét n = 1 => MR = 9(Loại)
Xét n = 2 => MR = 18 (Loại)
Xét n = 3 => MR = 27(g/mol) => R là Al (Nhôm)
b)
\(n_{Al}=\dfrac{7,56}{27}=0,28\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,28-->0,84--->0,28--->0,42
=> \(V_{H_2}=0,42.22,4=9,408\left(l\right)\)
\(m_{HCl}=0,84.36,5=30,66\left(g\right)\)
=> \(m_{ddHCl}=\dfrac{30,66.100}{12}=255,5\left(g\right)\)
c) mdd sau pư = 7,56 + 255,5 - 0,42.2 = 262,22 (g)
=> \(C\%_{AlCl_3}=\dfrac{37,38}{262,22}.100\%=14,255\%\)
a) \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
\(n_{HCl}=\dfrac{146.5\%}{36,5}=0,2\left(mol\right)\)
PTHH: CuO + 2HCl --> CuCl2 + H2O
Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{0,2}{2}\) => CuO hết, HCl dư
=> dd sau phản ứng chứa CuCl2, HCl dư
b)
PTHH: CuO + 2HCl --> CuCl2 + H2O
0,05-->0,1------>0,05
mdd sau pư = 4 + 146 = 150 (g)
\(\left\{{}\begin{matrix}C\%_{CuCl_2}=\dfrac{0,05.135}{150}.100\%=4,5\%\\C\%_{HCldư}=\dfrac{\left(0,2-0,1\right).36,5}{150}.100\%=2,433\%\end{matrix}\right.\)
b)
PTHH: NaOH + HCl --> NaCl + H2O
CuCl2 + 2NaOH --> 2NaCl + Cu(OH)2
0,05--------------------------->0,05
Cu(OH)2 --to--> CuO + H2O
0,05----------->0,05
=> \(a=m_{Cu\left(OH\right)_2}=0,05.98=4,9\left(g\right)\)
=> \(b=m_{CuO}=0,05.80=4\left(g\right)\)
1)
a)
$CaO + 2HCl \to CaCl_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CO_2} = 0,2(mol)$
$n_{CaCl_2} = 0,3(mol)$
Suy ra:
$n_{CaO} = 0,3 - 0,2 = 0,1(mol)$
$\%m_{CaO} = \dfrac{0,1.56}{0,1.56 + 0,2.100}.100\% = 21,875\%$
$\%m_{CaCO_3} = 78,125\%$
b)
$m_{dd} = 0,1.56 + 0,2.100 + 50 - 0,2.44 = 66,8(gam)$
$C\%_{CaCl_2} = \dfrac{33,3}{66,8}.100\% = 49,85\%$
Câu 4 :
a)
Gọi $n_{Fe} = a(mol) ; n_{MgO} = b(mol)$
Suy ra: $56a + 40b = 19,2(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2O$
Theo PTHH : $n_{HCl} = 2a + 2b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,2
$\%m_{Fe} = \dfrac{0,2.56}{19,2}.100\% = 58,33\%$
$\%m_{MgO} = 100\% -58,33\% = 41,67\%$
b)
$n_{FeCl_2} = a = 0,2(mol)$
$n_{MgCl_2} = b = 0,2(mol)$
$m_{muối} = 0,2.127 + 0,2.95 = 44,4(gam)$
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)
0,2_____0,4_____0,2____0,2_____0,2 (mol)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,1_____0,2_____0,1____0,1 (mol)
Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)
Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)
nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol
nCaCl2=\(\dfrac{33,3}{111}=0,3\)
CaCO2 + 2HCl → CaCl2 + CO2 + H2O
0,2 ← 0,2 ← 0,2
CaO + 2HCl → CaCl2 + H2O
0,1 ← 0,1
a) % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)
% CaCO3 =100% - 21,875%= 78,125%
b) a = mCaO+mCaCO3 =0,1.56+0,2.100=25,6g
mdd sau pư= a + mddHCl - mCO2
= 25,6 + 50 - 0,2.44=66,8g
C%CaCl2=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)
Đề chưa nói rõ là : tác dụng với dung dịch axit nào nên có lẽ là HCl hoặc H2SO4 , thứ hai là câu c không đủ dữ kiện đề bài để giải nhé.
\(Đặt:n_{Mg}=x\left(mol\right),n_{Fe}=y\left(mol\right)\)
\(m_{hh}=24x+56y=8\left(g\right)\left(1\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H_2}=x+y=0.2\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):x=y=0.1\)
\(\%Mg=\dfrac{0.1\cdot24}{8}\cdot100\%=30\%\\ \%Fe=70\%\)
\(m_M=m_{MgCl_2}+m_{FeCl_2}=0.1\cdot95+0.1\cdot127=22.2\left(g\right)\)
\(Mg+2H_2SO_{4\left(đ,n\right)}\)\(\rightarrow MgSO_4+SO_2+2H_2O\)
\(Zn+2H_2SO_4\rightarrow ZnSO_4+SO_2+2H_2O\)
Đặt \(n_{Mg}=x\left(mol\right);n_{Zn}=y\left(mol\right)\)
Có hệ:\(\left\{{}\begin{matrix}24x+65y=6,85\\120x+161y=52,1\end{matrix}\right.\) \(\Rightarrow y=-\dfrac{357}{3280}\) (sai đề ?)
a) \(n_{FeCl_3}=\dfrac{16,25}{162,5}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
0,05<----0,3<-----0,1
=> \(m_{Fe_2O_3}=0,05.160=8\left(g\right)\)
b)
\(m_{HCl\left(bd\right)}=91,25.16\%=14,6\left(g\right)\)
mdd sau pư = 8 + 91,25 = 99,25 (g)
\(\left\{{}\begin{matrix}C\%\left(FeCl_3\right)=\dfrac{16,25}{99,25}.100\%=16,373\%\\C\%\left(HCldư\right)=\dfrac{14,6-0,3.36,5}{99,25}.100\%=3,678\%\end{matrix}\right.\)