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nSO2=0.25(mol)
Cu+2H2SO4->CuSo4+SO2+2H2O
CuO+H2SO4->CuSO4+H2O
nCu=nSO2=0.25(mol)
mCu=16(g)
->mCuO=12(g)
nCuO=0.15(mol)
mH2SO4=78.4
nH2SO4=0.8(mol)
tổng nH2SO4 phản ứng:0.5+0.15=0.65(mol)
nH2SO4 dư=0.15(mol)
mH2SO4 dư=14.7(g)
nCuSO4=0.4(mol)
mCuSO4=64(g)
mdd=28+112-64*0.25=124(g)
C%(H2SO4)=14.7:124*100=11.9%
C%(CuSO4)=64:124*100=51.6%
BÀI 2
mdd axit=900(g)
mH2SO4=220.5(g)
gọi mSO2 là x(g)
ta có m chất tan sau khi hòa tan=x+220.5
mdd sau khi hòa tan=x+900
theo bài ra:(x+220.5):(x+900)=49/100
100x+22050=49x+44100
51x=22050
->x=432.4(g)
\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow\%m_{Zn}=\dfrac{0,2.65}{25.8}.100=50,39\%\\ \%m_{Cu}=100-50,39=49,61\%\\ b.m_{ddsaupu}=0,2.65+200-0,2.2=212,6\left(g\right)\\ n_{ZnSO_4}=n_{H_2}=0,2\left(mol\right)\\ C\%_{ZnSO_4}=\dfrac{0,2.161}{212,6}.100=15,15\%\)
a, \(n_{CO_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PT: \(MgO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2O\)
\(MgCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+CO_2+H_2O\)
Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,1.84}{10,4}.100\%\approx80,77\%\\\%m_{MgO}\approx19,23\%\end{matrix}\right.\)
b, \(n_{MgO}=\dfrac{10,4-0,1.84}{40}=0,05\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{MgO}+2n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
\(CuO+H_2SO_{4\left(24,5\%\right)}\rightarrow CuSO_4+H_2O\)
\(Cu+2H_2SO_{4đ}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)
\(n_{SO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(\Rightarrow n_{Cu}=0,05\left(mol\right)\)
\(\Rightarrow m_{CuO}=10-64.0,05=6,8\left(g\right)\)
\(\Rightarrow n_{CuO}=0,085\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(24,5\%\right)}=0,085\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(24,5\%\right)}=8,33\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4\left(24,5\%\right)}=34\left(g\right)\)
a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
b, Theo PT: \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\)
⇒ mMg = 0,1.24 = 2,4 (g) > mA → vô lý
Bạn xem lại xem đề cho bao nhiêu gam hh A nhé.
goi x la so mol cua Cu
y la so mol cua CuO
\(m_{H_2SO_4}=\dfrac{70.112}{100}=78,4g\)
\(n_{H_2SO_4}=\dfrac{78,4}{98}=0,8\left(mol\right)\)
Cu+2H2SO4(d,n)\(\underrightarrow{t^o}\)CuSO2+2H2O+SO2
de: x 2x x 2x x
CuO + H2SO4\(\rightarrow\) CuSO4 +H2O
de: y y y y
Ta co: 64x + 80y = 28
2x + y = 0,8
\(\Rightarrow\left\{{}\begin{matrix}x=0,375\left(mol\right)\\y=0,05\left(mol\right)\end{matrix}\right.\)
\(m_{Cu}=0,375.64=24g\)
\(m_{CuO}=0,05.80=4g\)
\(\%m_{Cu}=\dfrac{24}{28}.100\%\approx85,71\%\)
\(\%m_{CuO}=\dfrac{4}{28}.100\%\approx14,29\%\)
mk chỉ lam ý thu 2 thoi con ý 1 mk k hieu bn muon tinh cai j