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b) Tính khối lượng H2SO4 dư sau pư, biết H2SO4 đã lấy dư so với lượng pư là 10%
a, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
b, \(n_{Fe_2O_3}=\dfrac{24}{160}=0,15\left(mol\right)\)
Theo PT: \(n_{H_2}=3n_{Fe_2O_3}=0,45\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,45.22,4=10,08\left(l\right)\)
c, n\(n_{Fe}=2n_{Fe_2O_3}=0,3\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{HCl}=2n_{Fe}=0,6\left(mol\right)\Rightarrow V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(M\right)\)
\(n_{Fe_3O_4}=\dfrac{24}{232}=\dfrac{3}{29}\left(mol\right)\)
PTHH :
\(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
3/29 9/29
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
9/29 18/29
\(c,V_{HCl}=\dfrac{\dfrac{18}{29}}{1,5}=\dfrac{12}{29}\left(l\right)\)
Bài 1:
a) PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+2H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}m_{Fe_2O_3}=20\cdot80\%=16\left(g\right)\\m_{CuO}=20-16=4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=3n_{Fe_2O_3}+n_{CuO}=0,35\left(mol\right)\) \(\Rightarrow V_{H_2}=0,35\cdot22,4=7,84\left(l\right)\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe}=2n_{Fe_2O_3}=0,2\left(mol\right)\\n_{Cu}=n_{CuO}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{hhB}=m_{Fe}+m_{Cu}=0,2\cdot56+0,05\cdot64=14,4\left(g\right)\)
Bài 2:
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a) Vì khối lượng Cu bằng \(\dfrac{6}{5}\) khối lượng Fe
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=\dfrac{26,4}{6+5}\cdot6=14,4\left(g\right)\\m_{Fe}=26,4-14,4=12\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu}=\dfrac{14,4}{64}=0,225\left(mol\right)\\n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{3}{2}n_{Fe}+n_{Cu}=\dfrac{9}{28}+0,225=\dfrac{153}{280}\left(mol\right)\) \(\Rightarrow V_{H_2}=\dfrac{153}{280}\cdot22,4=12,24\left(l\right)\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=\dfrac{3}{28}\left(mol\right)\\n_{CuO}=n_{Cu}=0,225\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=\dfrac{3}{28}\cdot160\approx17,14\left(g\right)\\m_{CuO}=0,225\cdot80=18\left(g\right)\end{matrix}\right.\) \(\Rightarrow m_{hh}=35,14\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{17,14}{35,14}\cdot100\%\approx48,78\%\\\%m_{CuO}=51,22\%\end{matrix}\right.\)
\(1) Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\\ Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O \text{Theo PTHH }\\ n_{H_2O} = n_{H_2} = \dfrac{20,16}{22,4}=0,9(mol)\\ \text{Bảo toàn khối lượng : }\\ a = m_{hh} + m_{H_2} - m_{H_2O} = 65,4 + 0,9.2 - 0,9.18 = 51(gam)\)
2)
\(n_{Mg} = a ; n_{Al} = b ; n_{Fe} = c\\ \Rightarrow 24a + 27b + 56c = 18,6(1)\\ Mg + 2HCl \to MgCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = a + 1,5b + c = \dfrac{14,56}{22,4}=0,65(2)\\ 2Mg + O_2 \xrightarrow{t^o} 2MgO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ n_{O_2} = \dfrac{7,84}{22,4} = 0,35\)
Ta có :
\(\dfrac{a + b + c}{0,5a + 0,75b + \dfrac{2}{3}c} = \dfrac{0,55}{0,35}(3)\\ (1)(2)(3) \Rightarrow a = 0,2 ; b = 0,2 ; c= 0,15\\ \%m_{Mg} = \dfrac{0,2.24}{18,6}.100\% = 25,81\%\\ \%m_{Al} = \dfrac{0,2.27}{18,6}.100\% = 29,03\%\\ \%m_{Fe} = 100\% - 25,81\% -29,03\% = 45,16\%\)
a) \(n_O=n_{H_2}=\dfrac{3,316}{22,4}=0,14\left(mol\right)\)
\(m_{kl}=m_A-m_O=8,48-0,14.16=6,24\left(g\right)\)
b) Gọi \(n_{CuO}=x\)
Suy ra: \(n_{FeO}=2x\);
Gọi \(n_{Fe_2O_3}=y\)
Suy ra: \(n_{Fe_3O_4}=2y\)
\(m_{hhoxit}=80x+72.2x+160y+232.2y=8,48\)
\(n_O=x+2x+3y+4.2y=0,14\)
Ta có hệ phương trình:
\(\left\{{}\begin{matrix}80x+72.2x+160y+232.2y=8,48\\x+2x+3.y+4.2y=0,14\end{matrix}\right.\)
Dùng casio giải tìm ra được x,y. Dựa vào đó mà tính tp %.
nZn=\(\dfrac{19.5}{65}\)=0.3(mol)
nH2SO4=\(\dfrac{39.2}{98}\)=0.4(mol)
PTHH:
Zn + H2SO4 --> ZnSO4 + H2
B/đ`:0.3 0.4 0 0
P/ứ: 0.3-->0.3--->0.3-->0.3
SauP/ứ:0 0.1 0.3 0.3
=> PTHH => khí thu đc sau p/ứ là : H2
=> VH2(đktc)=0.3*22.4=6.72(l)
Đặt nCuO=a (mol) ; nFe3O4= b (mol)
PTHH:
CuO + H2 --> Cu + H2O (1)
P/ứ: a --------->a (mol)
Fe3O4 + 4H2 --> 3Fe + 4H2O (2)
P/ứ: b ------------> b (mol)
Vì sau khi nung hỗn hợp thì H2O thoát ra và chất còn lại là Fe và Cu
=> m hh A giảm = m H2O
Từ PTHH: (1);(2)
=> nH2O=nH2= 0.3(mol)
=> mH2O=0.3*18=5.4(g)
=> m = 5.4 (g)
a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Cu}=24-m_{Fe}=12,8\left(g\right)\) \(\Rightarrow n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{CuO}=n_{Cu}=0,2\left(mol\right)\\n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ m = mCuO + mFe2O3 = 0,2.80 + 0,1.160 = 32 (g)
b, \(\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,2.80}{32}.100\%=50\%\\\%m_{Fe_2O_3}=50\%\end{matrix}\right.\)
c, Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,5.22,4=11,2\left(l\right)\)