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PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
a, Giả sử: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Fe_2O_3}=y\left(mol\right)\end{matrix}\right.\)
Ta có: \(m_{H_2SO_4}=\frac{196.20}{100}=39,2\left(g\right)\Rightarrow n_{H_2SO_4}=\frac{39,2}{98}=0,4\left(mol\right)\)
Theo PT: \(\Sigma n_{H_2SO_4}=x+3y=0,4\left(1\right)\)
Ta có: \(n_{H_2}=\frac{0,4}{2}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\Rightarrow x=0,2\left(2\right)\)
Từ (1) và (2) ⇒ x = 0,2 (mol) ; y = 1/15 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\frac{0,2.56}{0,2.56+\frac{1}{15}.160}.100\%\approx51,2\%\text{ }\\\%m_{Fe_2O_3}\approx48,8\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\\n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=\frac{1}{15}\left(mol\right)\end{matrix}\right.\)
Ta có: m dd sau pư = mFe + mFe2O3 + m dd H2SO4 - mH2
= 0,2.56 + 1/15.160 + 196 - 0,4
≃ 217,467 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\frac{0,2.152}{217,467}.100\%\approx13,98\%\\C\%_{Fe_2\left(SO_4\right)_3}=\frac{\frac{1}{15}.400}{217,467}.100\%\approx12,26\%\end{matrix}\right.\)
Bạn tham khảo nhé!
a)
$Fe +H_2SO_4 \to FeSO_4 + H_2$
$FeSO_4 + 2KOH \to Fe(OH)_2 + K_2SO_4$
$4Fe(OH)_2 + O_2 \xrightarrow{t^o} 2Fe_2O_3 + 4H_2O$
$n_{Fe_2O_3} = \dfrac{20}{160} = 0,125(mol)$
Theo PTHH : $n_{Fe} = 2n_{Fe_2O_3} = 0,25(mol)$
$m_{Fe} = 0,25.56 = 14(gam)$
b)
$n_{H_2} = n_{Fe} = 0,25(mol)$
$V_{H_2} = 0,25.22,4 = 5,6(lít)$
c)
$n_{H_2SO_4} = n_{Fe} = 0,25(mol)$
$V_{dd\ H_2SO_4} = \dfrac{0,25}{1} = 0,25(lít) = 250(ml)$
\(PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ FeSO_4+2KOH\rightarrow Fe\left(OH\right)_2+K_2SO_4\\4 Fe\left(OH\right)_2+O_2\underrightarrow{t^o}2Fe_2O_3+4H_2O\)
\(a.n_{Fe_2O_3}=\dfrac{20}{160}=0,125\left(mol\right)\\ n_{H_2}=n_{H_2SO_4}=n_{Fe}=n_{FeSO_4}=n_{Fe\left(OH\right)_2}=\dfrac{4}{2}.0,125=0,25\left(mol\right)\\ m_{Fe}=0,25.56=14\left(g\right)\\ b.V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ c.V_{ddH_2SO_4}=\dfrac{0,25}{1}=0,25\left(l\right)=250\left(ml\right)\)
nHCl=0,6 mol
FeO+2HCl-->FeCl2+ H2O
x mol x mol
Fe2O3+6HCl-->2FeCl3+3H2O
x mol 2x mol
72x+160x=11,6 =>x=0,05 mol
A/ CFeCl2=0,05/0,3=1/6 M
CFeCl3=0,1/0,3=1/3 M
CHCl du=(0,6-0,4)/0,3=2/3 M
B/
NaOH+ HCl-->NaCl+H2O
0,2 0,2
2NaOH+FeCl2-->2NaCl+Fe(OH)2
0,1 0,05
3NaOH+FeCl3-->3NaCl+Fe(OH)3
0,3 0,1
nNaOH=0,6
CNaOH=0,6/1,5=0,4M
a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b) Gọi x,y là số mol Al, Fe
\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Ta có hệ : \(\left\{{}\begin{matrix}27x+56y=0,83\\\dfrac{3}{2}x+y=0,02\end{matrix}\right.\)
=> \(x=\dfrac{29}{5700};y=\dfrac{47}{3800}\)
\(\%m_{Al}=\dfrac{\dfrac{27}{5700}.27}{0,83}.100=16,55\%\); \(\%m_{Fe}=100-16,55=83,45\%\)
c)Bảo toàn nguyên tố H: \(n_{H_2SO_4}=n_{H_2}=0,02\left(mol\right)\)
=> \(C\%_{H_2SO_4}=\dfrac{0,02.98}{200}.100=0,98\%\)
\(a.Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\\ n_{NaCl}=n_{HCl}=2.n_{CO_2}=2.\dfrac{448:1000}{22,4}=0,04\left(mol\right)\\ C_{MddHCl}=\dfrac{0,04}{0,02}=2\left(M\right)\\ b.m_{NaCl}=58,5.0,04=2,34\left(g\right)\\ c.m_{Na_2CO_3}=106.0,02=2,12\left(g\right)\\ \%m_{Na_2CO_3}=\dfrac{2,12}{5}.100=42,4\%\\ \%m_{NaCl}=100\%-42,4\%=57,6\%\)
Bài 16 :
\(n_{CO2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)
Pt : \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O|\)
1 2 2 1 1
0,02 0,04 0,04 0,02
a) \(n_{HCl}=\dfrac{0,02.2}{1}=0,04\left(mol\right)\)
20ml = 0,02l
\(C_{M_{HCl}}=\dfrac{0,04}{0,02}=2\left(M\right)\)
b) \(n_{NaCl}=\dfrac{0,02.2}{1}=0,04\left(mol\right)\)
⇒ \(m_{NaCl}=0,04.58,5=2,34\left(g\right)\)
c) \(n_{Na2CO3}=\dfrac{0,04.1}{2}=0,02\left(mol\right)\)
⇒ \(m_{Na2CO3}=0,02.106=2,12\left(g\right)\)
\(m_{NaCl}=5-2,12=2,88\left(g\right)\)
0/0Na2CO3 = \(\dfrac{2,12.100}{5}=42,4\)0/0
0/0NaCl = \(\dfrac{2,88.100}{5}=57,6\)0/0
Chúc bạn học tốt
\(a,n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Ba + 2H2O ---> Ba(OH)2 + H2
0,3<-------------0,3<---------0,3
=> mBa = 0,3.137 = 41,1 (g)
=> mK2O = 59,9 - 41,1 = 18,8 (g)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{41,1}{59,9}.100\%=68,61\%\\\%m_{K_2O}=100\%-68,61\%=31,39\%\end{matrix}\right.\)
\(b,n_{K_2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\)
PTHH: K2O + H2O ---> 2KOH
0,2----------------->0,4
Các chất tan trong dd sau phản ứng: KOH, Ba(OH)2
\(\rightarrow\left\{{}\begin{matrix}m_{KOH}=0,4.56=22,4\left(g\right)\\m_{Ba\left(OH\right)_2}=0,3.171=51,3\left(g\right)\end{matrix}\right.\)
Bài 1:
\(n_{Na_2SO_3}=\frac{100,8}{126}=0,8\left(mol\right)\)
\(m_{HCl}=\frac{120.14,6}{100}=17,52\left(g\right)=>n_{HCl}=\frac{17,52}{36,5}=0,48\left(mol\right)\)
PTHH: \(Na_2SO_3+2HCl\rightarrow2NaCl+SO_2+H_2O\)
________0,24<-------0,48------->0,48---->0,24____________(mol)
=> \(m_{dd}=100,8+120-0,24.64=205,44\left(g\right)\)
\(C\%\left(Na_2SO_3\right)=\frac{\left(0,8-0,24\right).126}{205,44}.100\%=34,35\%\)
\(C\%\left(NaCl\right)=\frac{0,48.58,5}{205,44}.100\%=13,67\%\)