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$a\big)$
$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$
$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$
Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$
$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$
$\to \%m_{ZnO}=100-61,61=38,39\%$
$b\big)$
$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$
Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$
$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,2 ( mol )
\(m_{Zn}=0,2.65=13g\)
\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)
\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,4 ( mol )
\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)
\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)
0,1 0,2 ( mol )
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)
Gọi $n_{Na_2O} = 2a(mol) \Rightarrow n_{K_2O} = a(mol)$
$\Rightarrow 2a.62 + 94a = 21,8 \Rightarrow a = 0,1(mol)$
$Na_2O + H_2O \to 2NaOH$
$K_2O + H_2O \to 2KOH$
$n_{NaOH} = 2n_{Na_2O} = 0,4(mol)$
$n_{KOH} = 2n_{K_2O} = 0,2(mol)$
$C_{M_{NaOH}} = \dfrac{0,4}{0,5} = 0,8M$
$C_{M_{KOH}} = \dfrac{0,2}{0,5} = 0,4M$
$m_{dd} = D.V = 1,04.500 = 520(gam)$
$C\%_{NaOH} = \dfrac{0,4.40}{520}.100\% = 3,1\%$
$C\%_{KOH} = \dfrac{0,2.56}{520}.100\% = 2,15\%$
a, Ta có: 27nAl + 56nFe = 22 (1)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{19,832}{24,79}=0,8\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,4\left(mol\right)\\n_{Fe}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{22}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)
b, \(n_{HCl}=2n_{H_2}=1,6\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{1,6}{0,5}=3,2\left(M\right)\)
Câu 1:
\(n_{CO_2}=\dfrac{11,2}{22,4}=0,5(mol)\\ a,PTHH:CO_2+Ba(OH)_2\to BaCO_3\downarrow+H_2O\\ \Rightarrow n_{Ba(OH)_2}=n_{BaCO_3}=n_{CO_2}=0,5(mol)\\ \Rightarrow C_{M_{Ba(OH)_2}}=\dfrac{0,5}{0,2}=2,5M\\ m_{BaCO_3}=0,5.197=98,5(g)\\ b,PTHH:Ba(OH)_2+2HCl\to BaCL_2+2H_2O\\ \Rightarrow n_{HCl}=2n_{Ba(OH)_2}=1(mol)\\ \Rightarrow m_{CT_{HCl}}=1.36,5=36,5(g)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{36,5}{20\%}=182,5(g)\)
Câu 2:
\(n_{Fe_2O_3}=\dfrac{32}{160}=0,2(mol)\\ m_{HCl}=\dfrac{292.20\%}{100\%}=58,4(g)\\ \Rightarrow n_{HCl}=\dfrac{58,4}{36,5}=1,6(mol)\\ PTHH:Fe_2O_3+6HCl\to 2FeCl_3+3H_2O\)
Vì \(\dfrac{n_{HCl}}{6}>\dfrac{n_{Fe_2O_3}}{1}\) nên \(HCl\) dư
\(\Rightarrow n_{FeCl_3}=2n_{Fe_2O_3}=0,4(mol);n_{H_2O}=3n_{Fe_3O_3}=0,6(mol)\\ \Rightarrow \begin{cases} m_{CT_{FeCl_3}}=0,4.162,5=65(g)\\ m_{H_2O}=0,6.18=10,8(g) \end{cases}\\ \Rightarrow m_{dd_{FeCl_3}}=32+292-10,8=313,2(g)\\ \Rightarrow C\%_{FeCl_3}=\dfrac{65}{313,2}.100\%\approx20,75\%\)
1 , \(n_{Na}=\frac{4,6}{23}=0,2\left(mol\right)\)
\(m_{HCl}=200.2,92\%=5,84\left(mol\right)\) => \(n_{HCl}=\frac{5,84}{36,5}=0,16\left(mol\right)\)
\(2Na+2HCl->2NaCl+H_2\left(1\right)\)
vì \(\frac{0,2}{2}>\frac{0,16}{2}\) => Na dư , HCl hết
dung dịch thu được là dung dịch NaCl
theo (1) \(n_{NaCl}=n_{HCl}=0,16\left(mol\right)\) => \(m_{NaCl}=0,16.58,5=9,36\left(g\right)\)
\(n_{H_2}=\frac{1}{2}n_{HCl}=0,08\left(mol\right)\)
khối lượng dung dịch sau phản ứng là
4,6+200-0,08.2=204,44(g)
\(C_{\%\left(NaCl\right)}=\frac{9,36}{204,44}.100\%\approx4,58\%\)
a, Ta có: 27nAl + 56nFe = 27,8 (1)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{17,353}{24,79}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,2\left(mol\right)\\n_{Fe}=0,4\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{27,8}.100\%\approx19,42\%\\\%m_{Fe}\approx80,58\%\end{matrix}\right.\)
b, \(n_{H_2SO_4}=n_{H_2}=0,7\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,7}{0,5}=1,4\left(M\right)\)
Bài 1:
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{Na}=n_{Na_2O}=0,2.2=0,4\left(mol\right)\\ a.m_{Na}=0,4.23=9,2\left(g\right)\\ b.C_{MddA}=\dfrac{0,4}{0,5}=0,8\left(M\right)\\ C\%_{ddA}=\dfrac{0,4.40}{500.1,2}.100\approx2,667\%\)